Sustainable Energy & Fuels,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 6, 2024
Sodium
acetate
trihydrate
(SAT)
is
an
extremely
potential
low-temperature
phase
change
material
(PCM)
in
the
solar
power
absorption,
residual
heat
recovery,
and
other
fields.
Abstract
The
efficient
capture,
conversion,
and
storage
of
solar
energy
present
significant
promise
for
advancing
green
utilization.
However,
pristine
phase
change
materials
(PCMs)
are
inherently
inadequate
optical
capture
absorption.
To
improve
photothermal
conversion
properties,
PCMs
metal‐organic
frameworks
derived
Co
nanoparticle‐anchored
carbonized
hollow
fiber
advantageously
integrated.
robust
carbon
tubular
structure
promises
thermal
storage,
fast
phonon
transfer,
excellent
durability
structural
stability
after
long
heating‐cooling
cycles.
Plasmonic
nanoparticles
broadband‐absorbing
high
graphitized
synergistically
enhance
light
harvesting
in
composite
PCMs,
achieving
94.38%
efficiency
(100
mW
cm
−2
).
This
integration
enables
the
simultaneous
generation
electrical
under
randomly
incident
radiation.
Attractively,
designed
photothermoelectric
system
steadily
realizes
a
continuous
output
voltage
309.8
mV
current
70.0
mA
advantageous
integrated
design
strategy
provides
constructive
insights
developing
next‐generation
toward
systems.
Journal of Material Science and Technology,
Год журнала:
2024,
Номер
214, С. 313 - 321
Опубликована: Июль 20, 2024
Solar-driven
thermo-electric
generation
(STEG)
emerges
as
a
promising
solution
to
mitigate
the
global
energy
shortage.
However,
practical
application
of
conventional
photothermal
materials
equipped
with
STEG
is
limited
due
low
solar
thermal
conversion
efficiency.
Herein,
we
fabricated
an
epoxy
resin
(EP)
nanocomposite,
EP/CCA80,
excellent
photo-thermal-electric
properties
by
embedding
vertically
aligned
aerogel
consisting
cellulose
nanofibers
(CNF)
and
carboxylated
multi-walled
carbon
nanotubes
(CMWCNTs)
into
transparent
EP
matrix.
EP/CCA80
composites
possessed
broad
light
absorption
range
from
200
nm
2500
properties.
Under
illumination
1.0
kW
m–2,
achieved
notable
stable
temperature
93.2°C
efficiency
up
54.35%
only
0.65
wt%
CMWCNTs
inclusion.
Additionally,
coupled
thermoelectric
(TE)
devices,
composite
facilitated
significant
difference
voltage
output
25.3°C
160.29
mV
(1.0
m–2),
respectively,
which
could
power
small
fan
rotate
at
speed
193
min–1.
Such
are
poised
offer
viable
solutions
for
enhancing
accessibility
in
remote
regions,
thereby
contributing
reduction
shortages
environmental
degradation.
Biomacromolecules,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 13, 2024
As
a
renewable
alternative
heat
source,
the
inherently
intermittent
feature
of
solar
energy
needs
to
be
coordinated
by
reliable
conversion
and
storage
systems
for
utilizing
most
abundant
energy.
Phase
change
materials
(PCMs)
are
supposed
advanced
mediums
storing
great
deal
generated
light.
However,
PCMs
cannot
effectively
absorb
utilize
due
leakage,
low
photothermal
efficiency,
poor
thermal
conductivity.
Herein,
we
developed
collagen-based
aerogel
modified
dialdehyde
carboxymethyl
cellulose
polydopamine-modified
two-dimensional
transition-metal
carbide/nitride
(MXene@PDA)
through
bidirectional
freeze-drying
technology
supporting
PCMs,
which
exhibited
anisotropy
in
structure
properties.
In
particular,
conductivity
was
0.0871
W/(m·K)
axial
direction
0.0504
radial
direction,
demonstrating
its
anisotropic
insulation
performance.
Moreover,
final
composite
had
been
obtained
via
impregnating
matrix
into
polyethylene
glycol
(PEG)
hydrophobic
treatment
polydimethylsiloxane,
outstanding
solar-thermal
ability,
good
capacity,
leakage-proof
property,
antifouling
The
loading
rate
PEG
as
high
92.2%,
melting
enthalpy
132.6
J/g.
Most
importantly,
water
contact
angle
evaluated
156.8°,
indicating
superior
This
material
has
intensive
application
prospects
fields
collection,
conversion,
storage.