Photocatalytic β-O-4 bond cleavage in lignin models and native lignin through CdS integration on titanium oxide photocatalyst under visible light irradiation

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 359, С. 124494 - 124494

Опубликована: Авг. 14, 2024

Язык: Английский

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Value-Added Conversion of Lignin Based on Inorganic−Organic Dual-Ligand-Regulated CdSe@CdS Nanorods

Surfaces and Interfaces, Год журнала: 2025, Номер 61, С. 106123 - 106123

Опубликована: Март 1, 2025

Язык: Английский

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Concurrent Photocatalytic CO₂ Reduction and 1‐Phenylethanol Oxidation Regulated by Chloride Ion‐Capped CdS@Zn_xCd_1‐xS@ZnS QDs

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Март 5, 2025

Abstract Solar‐driven photocatalytic CO 2 reduction coupled with the oxidation of organic compounds to value‐added chemicals is a promising strategy, which can utilize both photogenerated electrons and holes. Here, gradient alloyed CdS@Zn x Cd 1‐x S@ZnS quantum dots (quasi‐Type II band structure) capped Cl − ligands demonstrate great potential in simultaneous conversion 1‐phenylethanol into syngas pinacol. The passivation maximizes exposure surface‐active sites improves their electronic structure, providing prerequisite for efficient execution redox reactions. More importantly, p–π conjugation between chloride‐ion benzene ring provides bridge ultrafast transfer holes, greatly promotes activation Cα─H bond release mass reactive free hydrogen. This process effectively lowers thermodynamic energy barrier reduction, even as excessively high kinetic barriers arising from accumulation excess protons also enable them self‐couple, leading generation (CO ≈ 75 mmol g −1 h ; selectivity 69.86%). work insights future artificial photosynthesis achieve activity cost‐effective storable renewable resources co‐production substances through synergistic oxidation.

Язык: Английский

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Synergizing photothermal and pyroelectric effects: Coal gangue assisted simultaneous ZnS/CuS for degradation of mineral processing wastewater

Journal of Water Process Engineering, Год журнала: 2024, Номер 68, С. 106393 - 106393

Опубликована: Окт. 30, 2024

Язык: Английский

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Green and Eco-Friendly Egg White–TiO2 Hydrogel with Enhanced Antimicrobial, Adsorptive, and Photocatalytic Properties

Catalysts, Год журнала: 2024, Номер 14(12), С. 899 - 899

Опубликована: Дек. 8, 2024

The design of multi-purpose decontaminants with environmentally friendly characteristics, low cost, and high efficiency in removing pollutants from the environment is an effective economic strategy for maintaining long-term development ecosystem. Based on killing two birds one stone, egg white (EW)/TiO2 hydrogel a porous structure devised as bio-adsorbent using waste eggs nearing their expiration date simultaneously achieving efficient removal organic dyes inactivation microorganisms industrial wastewater. characterizations its morphology composition scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) theory, energy-dispersive spectrometry (EDS), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analyzer (TGA) validate successful synthesis EW/TiO2. maximum adsorption capacity EW/TiO2 333.172 mg∙mL−1 according to Langmuir model. photodegradation methyl blue (MB) solution under irradiation via xenon lamp used assess photocatalytic behavior Among different samples, 5 wt% TiO2-doped shows 99% 120 min irradiation. Finally, antibacterial properties are evaluated by calculating bacterial survival rate against Escherichia coli (E. coli). photocatalyst exhibits 90.4%, indicating that possesses positive activity effectively inhibiting growth bacteria, which suitable wastewater treatment over long period time.

Язык: Английский

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A High Responsivity Photodetector Based on Pf6-Cspbbr3 Quantum Dots Modified Mote2 Ultrathin Film

Опубликована: Янв. 1, 2024

Язык: Английский

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