Chemistry - An Asian Journal,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 4, 2024
Abstract
Herein,
the
Cu‐UiO‐66
catalyst
was
developed
for
acceptorless
dehydrogenative
coupling
(ADC)
between
alcohols
and
amines
to
produce
imines.
The
synthesized
by
installing
Cu
2+
onto
Zr‐oxo
clusters
in
UiO‐66,
efficiently
catalyzes
ADC
reaction
under
mild
environmentally
friendly
conditions
with
excellent
selectivity.
Mechanistic
studies
reveal
that
O
2
⋅
−
radicals
porosity
of
formed
participate
cooperatively
during
catalytic
cycle.
Meanwhile,
only
by‐product
system
is
benign
water.
Cycling
tests
hot
filtration
showed
exhibited
stability
activity
reaction.
Importantly,
might
provide
a
promising
strategy
Advances in Colloid and Interface Science,
Год журнала:
2024,
Номер
333, С. 103281 - 103281
Опубликована: Авг. 24, 2024
Growing
concerns
about
environmental
pollution
have
highlighted
the
need
for
efficient
and
sustainable
methods
to
remove
dye
contamination
from
various
ecosystems.
In
this
context,
computational
such
as
molecular
dynamics
(MD),
Monte
Carlo
(MC)
simulations,
quantum
mechanics
(QM)
calculations,
machine
learning
(ML)
are
powerful
tools
used
study
predict
adsorption
processes
of
dyes
on
adsorbents.
These
provide
detailed
insights
into
interactions
mechanisms
involved,
which
can
be
crucial
designing
systems.
MD
detailing
arrangements,
dyes'
behaviour
interaction
energies
with
They
simulate
entire
process,
including
surface
diffusion,
solvent
layer
penetration,
physisorption.
QM
especially
density
functional
theory
(DFT),
determine
structures
reactivity
descriptors,
aiding
in
understanding
mechanisms.
identify
stable
configurations
like
hydrogen
bonding
electrostatic
forces.
MC
simulations
equilibrium
properties
by
sampling
configurations.
ML
proven
highly
effective
predicting
optimizing
processes.
models
offer
significant
advantages
over
traditional
methods,
higher
accuracy
ability
handle
complex
datasets.
optimize
conditions,
clarify
adsorbent
functionalization
roles,
removal
efficiency
under
conditions.
This
research
explores
MD,
MC,
QM,
approaches
connect
macroscopic
phenomena.
Probing
these
techniques
provides
energetics
pollutants
surfaces.
The
findings
will
aid
developing
new
materials
removal.
review
has
implications
remediation,
offering
a
comprehensive
at
scales.
Merging
microscopic
data
observations
enhances
knowledge
pollutant
adsorption,
laying
groundwork
efficient,
technologies.
Addressing
growing
challenges
ecosystem
protection,
contributes
cleaner,
more
future.
•
Enviro
concern
drives
eco-friendly
Computation
unveils
Study
bridges
dynamics,
Carlo,
mechanics.
Insights
inform
novel
adsorbents
Integration
shapes
greener
solutions.
Reviews in Inorganic Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 16, 2025
Abstract
Water
is
a
basic
unit
for
survival
of
living
creature
and
over
the
past
few
years,
increased
industrialization
urbanization
caused
huge
contamination
natural
water
resources.
Major
contaminants
are
pharmacological-wastes,
especially
antibiotics
from
hospitals
pharmaceutical
industries
which
causes
pollution.
Pharmacological
elimination
ecosystem
very
critical
environmental
challenge
because
they
persistent
cause
potential
health
hazards.
Owing
to
high
surface
area,
tunable-porosity,
versatile
functionality
Metal-Organic
Frameworks
(MOFs),
their
composites
have
emerged
as
promising
materials
purification.
Various
including
amoxicillin,
doxycycline,
levofloxacin,
ciprofloxacin
successfully
removed
wastewater
using
MOFs
composites,
purifies
by
adsorption-mechanism.
This
study
reviews
advanced
progressions
in
application
MOF-based
adsorption
pollutants.
Additionally,
plant-based
been
explored
eco-friendly
cost-effective
pollutant
removal.
Despite
these
advancements,
challenges
such
scalability
MOF
synthesis,
stability
under
operational
conditions,
toxicity
need
be
addressed
commercial
application.
Future
research
should
focus
on
optimizing
synthesis
processes,
enhancing
recyclability
MOFs,
conducting
long-term
environmental-impact
assessments
ensure
sustainable
effective
treatment
solutions.
Advanced Energy and Sustainability Research,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 22, 2024
In
this
review,
the
transformative
role
of
polymer
nanocomposites
in
hydrogen
production
from
challenging
water
sources
is
explored.
Their
catalytic
efficiency
and
unique
properties
are
highlighted,
making
them
vital
for
overcoming
complexities
generation.
Polymer
demonstrate
exceptional
adaptability
to
various
compositions,
including
wastewater
saline
water,
enhancing
efficiency,
stability,
compatibility.
significance
these
nanomaterials
sustainable
energy
landscape
underscored,
showcasing
their
ability
outperform
conventional
methods.
Key
breakthroughs
emphasized,
illustrating
crucial
clean
production.
Looking
forward,
potential
applications
diverse
fields,
industrial
processes
sector
advancements,
identified.
This
synthesis
findings
not
only
enhances
understanding
but
also
sets
stage
widespread
adoption
meeting
global
demand
