Classification and Analysis of Halide Mixtures in Li10P3S12M (M = Cl, Br, I) Solid Electrolytes for Superionic Conductors DOI
Radian Febi Indrawan, Kazuhiro Hikima, Atsunori Matsuda

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 20, 2024

The lithium thiophosphate group of solid electrolytes (SEs) is considered one the best lithium-ion conductors that could be compatible with liquid electrolytes. However, interface stability SEs against anode and oxide cathode a challenge due to severe degradation over charge–discharge cycles. In this study, we aim analyze introduce addition halides into molar ratio 3Li3PS4 1LiM (M = Cl, Br, I) in order not only improve ion conductivity but also increase SEs. Li10P3S12Br (LPSBr) Li10P3S12I (LPSI) results high ionic at 1.7 2.9 mS cm–1, respectively, room temperature. Although LPSBr has lower conductivity, it shows better electrochemical compared LPSI. By combining advantages both LiI LiBr form Li10P3S12Br1–xIx, have observed improvements SEs, which important for extending lifetime cycle all-solid-state batteries (ASSLBs).

Язык: Английский

In situ formation of Li3N interlayer enhancing interfacial stability of solid-state lithium batteries DOI
Yuezhen Mao, Tianyuan Wang,

Fusheng Yin

и другие.

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 685, С. 595 - 603

Опубликована: Янв. 20, 2025

Язык: Английский

Процитировано

2
Fluorinated SO2-based inorganic electrolytes for enhanced electrochemical performance in Li-metal anodes DOI

Jiwhan Lee,

Seong Hoon Choi,

Seung Do Mun

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161438 - 161438

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Dual in-situ curing gel polymer electrolyte for solid-state lithium battery DOI
Lun Yu,

Sibin Zhu,

Zilan Jiang

и другие.

Materials Today Communications, Год журнала: 2025, Номер unknown, С. 112414 - 112414

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
Research Advances in Rare‐Earth‐Based Solid Electrolytes for All‐Solid‐State Batteries DOI
Shanshan Song, Fei He, Qing Xia

и другие.

Small, Год журнала: 2025, Номер unknown

Опубликована: Апрель 24, 2025

Abstract All‐solid‐state batteries (ASSBs) and solid‐state electrolytes (SSE) have emerged as promising alternative energy storage devices for traditional lithium‐ion batteries, drawing significant attention from researchers. Notably, SSE materials incorporating rare earth elements demonstrated remarkable advancements in terms of ionic conductivity, electrochemical stability, cycle‐reversible performance. The unique electron layer structures facilitate diverse level transitions. Meanwhile, their relatively large radius contributes to excellent mechanical strength, properties the electrolyte. This paper offers a comprehensive review rare‐earth‐based oxide solid electrolytes, sulfide halide composite polymer enriched with elements. characteristics, applications, modification methods, underlying mechanisms these are investigated, offering valuable insights inspiration design future materials. Additionally, this systematically presents solutions improving performance ASSBs explores ion transmission batteries. Finally, research direction, optimization development prospects analyzed forecasted.

Язык: Английский

Процитировано

0
Inorganic solid electrolytes for all-solid-state sodium/lithium-ion batteries: recent development and applications DOI Creative Commons
Muhammad Muzakir, M. Karnan, Eric Jianfeng Cheng

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 14, 2024

This review provides a comprehensive overview of recent advancements in preparation techniques and electrolyte engineering. It also discusses the integration both single- multi-phase electrolytes ASSBs future research potentials.

Язык: Английский

Процитировано

3
Incorporation of halogen (Cl, Br, I) in Li-P-S-O system for exploring new sulfide solid electrolytes with high conductivity and superior electrochemical performance in solid-state batteries DOI
Hari Raj, Audric Neveu,

Christian Jordy

и другие.

Journal of Materials Chemistry A, Год журнала: 2024, Номер 12(45), С. 31405 - 31423

Опубликована: Янв. 1, 2024

Doping halogen elements into LGPS-structured sulfide solid electrolytes could address the instability in ambient atmosphere and incompatibility with lithium metal, paving way for successful commercialization of solid-state batteries.

Язык: Английский

Процитировано

0
Urchin-like γ-MnO2/Carbon Nanotubes as an Efficient Cathode Catalyst for Durable Solid-State Lithium and Sodium-CO2 Batteries DOI
Jilong Liu,

Zhi Li,

Chen Chen

и другие.

ACS Applied Energy Materials, Год журнала: 2024, Номер 7(22), С. 10730 - 10737

Опубликована: Ноя. 13, 2024

Metal-CO2 batteries integrate the benefits of carbon dioxide capture and efficient energy storage, representing a prospective innovation in storage systems. In particular, most research attention has been concentrated on Li-CO2 Na-CO2 due to their high density discharge potential. However, excessive accumulation products volatilization liquid electrolyte restrict further advancements these batteries. Herein, we synthesized an urchin-like γ-MnO2 cathode catalyst that enables rapid reversible CO2 reduction reaction (CO2RR) evolution (CO2ER). The assembled solid-state Li/Na-CO2 with Li7La3Zr2O12- Na3Zr2Si2PO12-based composite solid electrolytes facilitate uniform stripping/deposition metallic anodes, thereby ensuring long-term cycling stability exhibit for 240 100 cycles, respectively, at current 200 mA g–1 cutting-off capacity 500 mAh g–1. Even g–1, still possess excellent rate capability. This work provides promising solution reduce costs catalysts enhance safety

Язык: Английский

Процитировано

0
Classification and Analysis of Halide Mixtures in Li10P3S12M (M = Cl, Br, I) Solid Electrolytes for Superionic Conductors DOI
Radian Febi Indrawan, Kazuhiro Hikima, Atsunori Matsuda

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 20, 2024

The lithium thiophosphate group of solid electrolytes (SEs) is considered one the best lithium-ion conductors that could be compatible with liquid electrolytes. However, interface stability SEs against anode and oxide cathode a challenge due to severe degradation over charge–discharge cycles. In this study, we aim analyze introduce addition halides into molar ratio 3Li3PS4 1LiM (M = Cl, Br, I) in order not only improve ion conductivity but also increase SEs. Li10P3S12Br (LPSBr) Li10P3S12I (LPSI) results high ionic at 1.7 2.9 mS cm–1, respectively, room temperature. Although LPSBr has lower conductivity, it shows better electrochemical compared LPSI. By combining advantages both LiI LiBr form Li10P3S12Br1–xIx, have observed improvements SEs, which important for extending lifetime cycle all-solid-state batteries (ASSLBs).

Язык: Английский

Процитировано

0