Halide Perovskite Photocatalysts for Clean Fuel Production and Organic Synthesis: Opportunities and Challenges DOI Creative Commons

Siddharth Singh,

Zeinab Hamid, Ramavath Babu

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 9, 2025

Abstract The need to constrain the use of fossil fuels causing global warming is motivating development a variety photocatalysts for solar‐to‐fuel generation and chemical synthesis. In particular, semiconductor‐based have been extensively exploited in solar‐driven organic synthesis, carbon dioxide (CO 2 ) conversion into value‐added products, hydrogen (H from water O) splitting. Recently, metal halide perovskites (MHPs) emerged as an important class semiconductors heterogeneous photocatalysis owing their interesting properties. Despite key issues with long‐term stability degradation polar solvents due ionic character, there has significant progress perovskite‐based improving performance gas liquid phases. This review discusses state‐of‐the‐art using photoelectrocatalysis production halogen acid solutions, CO reduction chemicals, various transformations. different types used, design strategies overcome instability solvents, efficiencies achieved are discussed. Furthermore, outstanding challenges associated electrolytes how can be improved

Язык: Английский

Tuning Dimensions of CsPbBr3 Nanocrystals through Pb(II) Counter Anions: A Dance of Dimensions and Product Selectivity in Visible-Light Photocatalysis DOI

Anupam Manna,

Pravat Nayek,

Prasenjit Mal

и другие.

ACS Energy Letters, Год журнала: 2025, Номер unknown, С. 1499 - 1507

Опубликована: Март 4, 2025

Язык: Английский

Процитировано

0
Application of Lead-Free Metal Halide Perovskite Heterojunctions for the Carbohalogenation of C–C Multiple Bonds DOI Creative Commons
Camilla Callegari,

Costanza Tedesco,

Alessia Corbo

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Апрель 1, 2025

A graphitic carbon nitride/lead-free double perovskite heterojunction (g-C3N4/Cs2AgBiCl6) has been adopted as a heterogeneous photocatalyst under visible light irradiation. The employed material enabled the atom transfer radical addition-type carbohalogenation of multiple C-C bonds, including (internal) alkenes and alkynes, with alkyl halides. protocol showed remarkable functional group tolerance, compatible late-stage functionalization natural pharmaceutical derivatives, could be easily scaled up, delivering >1 g desired products.

Язык: Английский

Процитировано

0
Dynamic Self-Assembled Systems of Photoinert N-Propargyl Amides Enable Red-Light Supramolecular Photocatalysis DOI
Sathi Sahoo, Tarun Kumar Dinda, Prasenjit Mal

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown

Опубликована: Апрель 18, 2025

Язык: Английский

Процитировано

0
Halide Perovskite Photocatalysts for Clean Fuel Production and Organic Synthesis: Opportunities and Challenges DOI Creative Commons

Siddharth Singh,

Zeinab Hamid, Ramavath Babu

и другие.

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Май 9, 2025

Abstract The need to constrain the use of fossil fuels causing global warming is motivating development a variety photocatalysts for solar‐to‐fuel generation and chemical synthesis. In particular, semiconductor‐based have been extensively exploited in solar‐driven organic synthesis, carbon dioxide (CO 2 ) conversion into value‐added products, hydrogen (H from water O) splitting. Recently, metal halide perovskites (MHPs) emerged as an important class semiconductors heterogeneous photocatalysis owing their interesting properties. Despite key issues with long‐term stability degradation polar solvents due ionic character, there has significant progress perovskite‐based improving performance gas liquid phases. This review discusses state‐of‐the‐art using photoelectrocatalysis production halogen acid solutions, CO reduction chemicals, various transformations. different types used, design strategies overcome instability solvents, efficiencies achieved are discussed. Furthermore, outstanding challenges associated electrolytes how can be improved

Язык: Английский

Процитировано

0