Interface Engineering, Charge Carrier Dynamics, and Solar-Driven Applications of Halide Perovskite/2D Material Heterostructured Photocatalysts DOI Creative Commons

Haihang Tong,

Fangfang Li, Minshu Du

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Апрель 10, 2025

Halide perovskites (HPs), renowned for their intriguing optoelectronic properties, such as robust light absorption coefficient, long charge transfer distance, and tunable band structure, have emerged a focal point in the field of photocatalysis. However, photocatalytic performance HPs is still inhibited by rapid recombination, insufficient potential energy, limited number surface active sites. To overcome these limitations, integration two-dimensional (2D) materials, characterized shortened pathways expansive areas, into HP/2D heterostructures presents promising avenue to achieve exceptional interfacial including extensive absorption, efficient separation transfer, energetic redox capacity, adjustable characteristics. Herein, comprehensive review delving fundamentals, engineering, carrier dynamics material presented. Numerous photocatalysts fabricated through diverse strategies architectures are systematically described categorized. More importantly, enhanced properties thoroughly investigated discussed. Finally, an analysis challenges faced development photocatalysts, alongside insightful recommendations barriers, provided.

Язык: Английский

The Future of Catalysis: Applying Graph Neural Networks for Intelligent Catalyst Design DOI

Zhihao Wang,

Wentao Li, Siying Wang

и другие.

Wiley Interdisciplinary Reviews Computational Molecular Science, Год журнала: 2025, Номер 15(2)

Опубликована: Март 1, 2025

ABSTRACT With the increasing global demand for energy transition and environmental sustainability, catalysts play a vital role in mitigating climate change, as they facilitate over 90% of chemical material conversions. It is important to investigate complex structures properties enhanced performance, which artificial intelligence (AI) methods, especially graph neural networks (GNNs) could be useful. In this article, we explore cutting‐edge applications future potential GNNs intelligent catalyst design. The fundamental theories their practical catalytic simulation inverse design are first reviewed. We analyze critical roles accelerating screening, performance prediction, reaction pathway analysis, mechanism modeling. By leveraging convolution techniques accurately represent molecular structures, integrating symmetry constraints ensure physical consistency, applying generative models efficiently space, these approaches work synergistically enhance efficiency accuracy Furthermore, highlight high‐quality databases crucial catalysis research innovative application thermocatalysis, electrocatalysis, photocatalysis, biocatalysis. end, key directions advancing catalysis: dynamic frameworks real‐time conditions, hierarchical linking atomic details features, multi‐task interpretability mechanisms reveal pathways. believe advancements will significantly broaden science, paving way more efficient, accurate, sustainable methodologies.

Язык: Английский

Процитировано

0

Interface Engineering, Charge Carrier Dynamics, and Solar-Driven Applications of Halide Perovskite/2D Material Heterostructured Photocatalysts DOI Creative Commons

Haihang Tong,

Fangfang Li, Minshu Du

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown

Опубликована: Апрель 10, 2025

Halide perovskites (HPs), renowned for their intriguing optoelectronic properties, such as robust light absorption coefficient, long charge transfer distance, and tunable band structure, have emerged a focal point in the field of photocatalysis. However, photocatalytic performance HPs is still inhibited by rapid recombination, insufficient potential energy, limited number surface active sites. To overcome these limitations, integration two-dimensional (2D) materials, characterized shortened pathways expansive areas, into HP/2D heterostructures presents promising avenue to achieve exceptional interfacial including extensive absorption, efficient separation transfer, energetic redox capacity, adjustable characteristics. Herein, comprehensive review delving fundamentals, engineering, carrier dynamics material presented. Numerous photocatalysts fabricated through diverse strategies architectures are systematically described categorized. More importantly, enhanced properties thoroughly investigated discussed. Finally, an analysis challenges faced development photocatalysts, alongside insightful recommendations barriers, provided.

Язык: Английский

Процитировано

0