Chemical Papers, Год журнала: 2025, Номер unknown
Опубликована: Май 26, 2025
Язык: Английский
Chemical Papers, Год журнала: 2025, Номер unknown
Опубликована: Май 26, 2025
Язык: Английский
Microchimica Acta, Год журнала: 2025, Номер 192(5)
Опубликована: Апрель 24, 2025
Язык: Английский
Процитировано
0Microchemical Journal, Год журнала: 2025, Номер 214, С. 113990 - 113990
Опубликована: Май 15, 2025
Язык: Английский
Процитировано
0ACS Applied Materials & Interfaces, Год журнала: 2025, Номер unknown
Опубликована: Май 18, 2025
This study introduces a novel method for synthesizing Fe-based metal-organic framework (MOF), leveraging Fe wire as substrate and an iron precursor source with which to grow MIL-88B(Fe) MIL-88B(Fe)-NH2. simple in situ approach requires only the addition of ligand MOF formation, eliminating need additional metal precursor. The adsorption performance developed on is evaluated using polar formaldehyde gas nonpolar cyclohexane vapor hazardous model gas/vapor (GV). key discovery highlights pivotal role functional compatibility between GV governing diffusivity through mesopores (<20 nm) within MOF, validated experimental analysis theoretical calculations. In contrast, interparticle larger pores (>20 remains unaffected, demonstrating unique influence nanoscale interactions. Semiempirical atomic simulations support results, revealing stronger interactions more sites compatible GV-MOF pairs. establishes sustainable pathway designing advanced adsorbents, emphasizing importance micro-/meso-diffusivity hierarchical porous structure maximize overall capacity. A proof-of-concept multipurpose adsorbent conceived by weaving wires different functionalities achieve simultaneous removal GVs.
Язык: Английский
Процитировано
0Chemical Papers, Год журнала: 2025, Номер unknown
Опубликована: Май 26, 2025
Язык: Английский
Процитировано
0