[Ga(C2H6OS)6](SbBr6): A Highly Luminescent Organic–Inorganic Hybrid Bimetallic Bromide Synthesized via a Cation Hybridization Strategy DOI
Xiang Xu, Yifan Ding, Ying Ding

и другие.

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Июнь 4, 2025

In this report, a new organic-inorganic hybrid bimetallic halide with excellent luminescent properties, namely, [Ga(C2H6OS)6](SbBr6), has been synthesized and characterized. This compound crystallizes in the trigonal space group R3̅ = b 13.83069(14) Å, c 15.7632(3) V 2611.34(7) Å3, Z 3, features zero-dimensional structure composed of isolated [Ga(C2H6OS)6]3+ cation clusters (SbBr6)3- inorganic anion octahedra. [Ga(C2H6OS)6](SbBr6) crystals exhibit bright yellowish-green photoluminescent broadband emission centered at 540 nm full width half-maximum 115 nm, large Stokes shift 175 high photoluminescence quantum yield 43.1%. Moreover, displays impressive radioluminescence performance when excited by X-rays, light 13 500 photons MeV-1 radiation resistance. Flexible films incorporating polydimethylsiloxane illustrate X-ray imaging ability spatial resolution approximately 10 lp mm-1 low detection limit 161.2 nGyair s-1. These preliminary investigations demonstrate considerable potential for applications radiography.

Язык: Английский

[Ga(C2H6OS)6](SbBr6): A Highly Luminescent Organic–Inorganic Hybrid Bimetallic Bromide Synthesized via a Cation Hybridization Strategy DOI
Xiang Xu, Yifan Ding, Ying Ding

и другие.

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Июнь 4, 2025

In this report, a new organic-inorganic hybrid bimetallic halide with excellent luminescent properties, namely, [Ga(C2H6OS)6](SbBr6), has been synthesized and characterized. This compound crystallizes in the trigonal space group R3̅ = b 13.83069(14) Å, c 15.7632(3) V 2611.34(7) Å3, Z 3, features zero-dimensional structure composed of isolated [Ga(C2H6OS)6]3+ cation clusters (SbBr6)3- inorganic anion octahedra. [Ga(C2H6OS)6](SbBr6) crystals exhibit bright yellowish-green photoluminescent broadband emission centered at 540 nm full width half-maximum 115 nm, large Stokes shift 175 high photoluminescence quantum yield 43.1%. Moreover, displays impressive radioluminescence performance when excited by X-rays, light 13 500 photons MeV-1 radiation resistance. Flexible films incorporating polydimethylsiloxane illustrate X-ray imaging ability spatial resolution approximately 10 lp mm-1 low detection limit 161.2 nGyair s-1. These preliminary investigations demonstrate considerable potential for applications radiography.

Язык: Английский

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