Triptycene based microporous hypercrosslinked polymer with amino functionality for selective CO2 capture DOI Open Access
Mosim Ansari, Aasif Helal,

Mahmoud Mohamed Abdelnaby

и другие.

Journal of Applied Polymer Science, Год журнала: 2024, Номер unknown

Опубликована: Окт. 9, 2024

Abstract The increasing CO 2 concentration in the atmosphere contributes significantly to global warming, necessitating effective capture techniques. Though amine‐based solvents are commonly used, they have drawbacks like high energy consumption and corrosion. Physical adsorption using microporous sorbents with polar groups emerges as a promising alternative, offering efficiency selectivity for capture. This work presents design of new hypercrosslinked polymer amino derived from 3D molecular building block triptycene (TBMP‐NH ), applications. unit backbone provides surface area, thermal stability, microporosity. TBMP‐NH demonstrates excellent stability ( T d > 350°C), considerable microporosity, BET‐specific area 866 m /g, making it adsorbent. It exhibits capacity 1.86 mmol/g at 273 K 1.23 298 K, Q st value 33.95 kJ/mol, indicating physisorption mechanism where micropore volume V mic = 0.359 cm 3 /g) plays crucial role. displays good /N /CH 4 selectivity, outperforming several reported porous polymers. Owing its physiochemical properties, efficient selective ability, can be considered material environmental remediation application.

Язык: Английский

Hydroxyl-Incorporated Microporous Polymer Comprising 3D Triptycene for Selective Capture of CO2 over N2 and CH4 DOI Creative Commons
Mosim Ansari, Aamir Hanif, Mahmoud M. Abdelnaby

и другие.

ACS Omega, Год журнала: 2025, Номер unknown

Опубликована: Янв. 15, 2025

The rising CO2 concentration in the atmosphere contributes significantly to global warming, necessitating effective carbon capture techniques. Amine-based solvents are widely employed for chemisorption of CO2, although they have drawbacks, such as degradation, corrosion, and high regeneration energy requirements. Physical adsorption utilizing microporous adsorbents is a viable alternative that offers excellent efficiency selectivity capture. This work presents facile one-pot synthesis 3D-triptycene-containing hyper-cross-linked polymer (TBPP-OH) possessing hydroxyl groups. presence triptycene units TBPP-OH polymeric structure gives several desirable features, inherent microporosity, larger surface area, improved thermal stability. showed considerable microporosity (%Vmic = 70%), BET-specific area (SABET) 838 m2 g–1, good stability (Td 372 °C char yield > 60%) which makes it promising adsorbent A strong affinity was shown by with Qst 32.9 kJ/mol demonstrating superior capacity 2.77 mmol/g at 273 K 1 bar pressure where volume micropore plays significant role. values over N2 CH4 were also estimated be reasonably indicating potential separation different applications. mechanism investigated using Langmuir dual-site models.

Язык: Английский

Процитировано

3
Facile synthesis of inherently nitrogen-doped PAN-derived microporous carbons activated with NaNH2 for selective CO2 adsorption and separation DOI

Ghazanfar Nazir,

Adeela Rehman, Muhammad Ikram

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 497, С. 154704 - 154704

Опубликована: Авг. 14, 2024

Язык: Английский

Процитировано

7
Mitigating CO2 Emissions: A Review on Emerging Technologies/Strategies for CO2 Capture DOI

A.E. Geweda,

Mohamed E. Zayed, Mohd Yusuf Khan

и другие.

Journal of the Energy Institute, Год журнала: 2024, Номер unknown, С. 101911 - 101911

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

6
Preparation of N, S co-doped carbon nanotubes composites by coal pyrolysis for the CO2 capture DOI
Ying Wang,

Chuanfang Zhang,

Mengfei Tang

и другие.

Journal of environmental chemical engineering, Год журнала: 2024, Номер unknown, С. 114452 - 114452

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

5
Recent advances of hyper-crosslinked porous polymers in environment related fields: synthesis, functionalization, and applications DOI
Hui Zhang,

Ruitong Yin,

Chengdong Wang

и другие.

Environmental Technology Reviews, Год журнала: 2025, Номер 14(1), С. 427 - 457

Опубликована: Апрель 5, 2025

Язык: Английский

Процитировано

0
Sulfur- and Nitrogen-Incorporated Phenothiazine-Based Porous Organic Polymer: Selective and Efficient CO2 Capture and Evaluation for Vacuum Swing Adsorption DOI
Mosim Ansari, Aasif Helal, Abuzar Khan

и другие.

ACS Applied Polymer Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 7, 2025

Язык: Английский

Процитировано

0
Triptycene based microporous hypercrosslinked polymer with amino functionality for selective CO2 capture DOI Open Access
Mosim Ansari, Aasif Helal,

Mahmoud Mohamed Abdelnaby

и другие.

Journal of Applied Polymer Science, Год журнала: 2024, Номер unknown

Опубликована: Окт. 9, 2024

Abstract The increasing CO 2 concentration in the atmosphere contributes significantly to global warming, necessitating effective capture techniques. Though amine‐based solvents are commonly used, they have drawbacks like high energy consumption and corrosion. Physical adsorption using microporous sorbents with polar groups emerges as a promising alternative, offering efficiency selectivity for capture. This work presents design of new hypercrosslinked polymer amino derived from 3D molecular building block triptycene (TBMP‐NH ), applications. unit backbone provides surface area, thermal stability, microporosity. TBMP‐NH demonstrates excellent stability ( T d > 350°C), considerable microporosity, BET‐specific area 866 m /g, making it adsorbent. It exhibits capacity 1.86 mmol/g at 273 K 1.23 298 K, Q st value 33.95 kJ/mol, indicating physisorption mechanism where micropore volume V mic = 0.359 cm 3 /g) plays crucial role. displays good /N /CH 4 selectivity, outperforming several reported porous polymers. Owing its physiochemical properties, efficient selective ability, can be considered material environmental remediation application.

Язык: Английский

Процитировано

1