Unveiling the reaction pathway on Cu/CeO2 catalyst for electrocatalytic CO2 reduction to CH4

Applied Catalysis B Environment and Energy, Год журнала: 2021, Номер 304, С. 120951 - 120951

Опубликована: Ноя. 23, 2021

Язык: Английский

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Atomic Pd-promoted ZnZrO solid solution catalyst for CO2 hydrogenation to methanol

Applied Catalysis B Environment and Energy, Год журнала: 2021, Номер 304, С. 120994 - 120994

Опубликована: Дек. 9, 2021

Язык: Английский

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CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts: Effects of ZnO morphology and oxygen vacancy

Fuel, Год журнала: 2022, Номер 314, С. 123035 - 123035

Опубликована: Янв. 5, 2022

Язык: Английский

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CeO2 nanosheets with anion-induced oxygen vacancies for promoting photocatalytic toluene mineralization: Toluene adsorption and reactive oxygen species

Applied Catalysis B Environment and Energy, Год журнала: 2022, Номер 317, С. 121694 - 121694

Опубликована: Июль 2, 2022

Язык: Английский

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Tunable and improved microwave absorption of flower-like core@shell MFe2O4@MoS2 (M = Mn, Ni and Zn) nanocomposites by defect and interface engineering

Journal of Material Science and Technology, Год журнала: 2022, Номер 139, С. 137 - 146

Опубликована: Сен. 29, 2022

Язык: Английский

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Synergistic Pt-CeO2 interface boosting low temperature dry reforming of methane

Applied Catalysis B Environment and Energy, Год журнала: 2022, Номер 318, С. 121809 - 121809

Опубликована: Июль 30, 2022

Язык: Английский

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Ni nanoparticles enclosed in highly mesoporous nanofibers with oxygen vacancies for efficient CO2 methanation

Applied Catalysis B Environment and Energy, Год журнала: 2022, Номер 317, С. 121715 - 121715

Опубликована: Июль 6, 2022

Язык: Английский

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Boosting toluene deep oxidation by tuning metal-support interaction in MOF-derived Pd@ZrO2 catalysts: The role of interfacial interaction between Pd and ZrO2

Fuel, Год журнала: 2023, Номер 357, С. 129833 - 129833

Опубликована: Сен. 20, 2023

Язык: Английский

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Modulating the Electronic Metal‐Support Interactions in Single‐Atom Pt₁−CuO Catalyst for Boosting Acetone Oxidation

Angewandte Chemie International Edition, Год журнала: 2022, Номер 61(28)

Опубликована: Март 29, 2022

The development of highly active single-atom catalysts (SACs) and identifying their intrinsic sites in oxidizing industrial hazardous hydrocarbons are challenging prospects. Tuning the electronic metal-support interactions (EMSIs) is valid for modulating catalytic performance SACs. We propose that modulation EMSIs a Pt1 -CuO SAC significantly promotes activity catalyst acetone oxidation. promote charge redistribution through unified Pt-O-Cu moieties, which modulates d-band structure atomic Pt sites, strengthens adsorption activation reactants. positively charged atoms superior activating at low temperatures, stretched Cu-O bonds facilitate lattice oxygen to participate subsequent believe this work will guide researchers engineer efficient SACs application hydrocarbon oxidation reactions.

Язык: Английский

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Facet Engineering of a Metal–Organic Framework Support Modulates the Microenvironment of Palladium Nanoparticles for Selective Hydrogenation

Angewandte Chemie International Edition, Год журнала: 2022, Номер 61(47)

Опубликована: Сен. 27, 2022

The exposed facets of supported catalysts play a crucial role in catalysis; however, they are usually ignored and related studies remain rare. Herein, we have fabricated series sandwich-structured metal-organic framework composites, denoted ZIF-8X @Pd@ZIF-8 (x represents the morphology ZIF-8 core, i.e., ZIF-8C exposing (100) facet, ZIF-8RD (110) ZIF-8TRD mixed facets), featuring Pd nanoparticles deposited on specific crystal for hydrogenation p-chloronitrobenzene. electronic state is tailored by where more electron-deficient found than that @Pd@ZIF-8, leading to discriminative adsorption -NO2 -Cl groups Consequently, exhibits excellent activity (97.6 %) selectivity (98.1 p-chloroaniline. This work highlights facet engineering supports modulate microenvironment metal nanoparticles, offering promising avenue enhanced catalysis.

Язык: Английский

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