Palladium-catalysed asymmetric cascade transformations of 4-alken-2-ynyl carbonates to construct complex frameworks DOI Creative Commons

Ze-Liang He,

Li Li, Zhichao Chen

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 27, 2024

A palladium-catalysed asymmetric auto-tandem reaction between 4-alken-2-ynyl carbonates and diverse ortho-functionalized activated alkenes is reported, giving complex frameworks in moderate yields with excellent chemo-, regio- stereoselectivity.

Язык: Английский

Assembly of Diverse Allenes via Activator-Free Palladium-Catalyzed Regioselective γ-Arylation of Propargylamines with Boronic Acids DOI
Yan Sun,

Ya Pan,

Tao Zhao

и другие.

The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Фев. 7, 2025

Controlling the reaction selectivity to achieve a precision synthesis is constant concern for chemists. Here, we report palladium-catalyzed deaminative coupling of propargylamines with arylboronic acids generate allene skeletons. Importantly, this approach allows regioselective γ-arylation unactivated propargyl tertiary amines access various allenes in absence amino-activating reagents. We present wide range and boronic demonstrate synthetic application target products construct valuable compounds.

Язык: Английский

Процитировано

0
Palladium-Catalyzed Intermolecular 1,3-Dienylation of Propargyl Esters Involving the Insertion of SO2 DOI

Haohao Jiang,

Mengzhao Yu,

Shuoshuo Zhang

и другие.

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Фев. 20, 2025

A palladium-catalyzed three-component 1,3-dienylation of propargylic esters with DABSO and aryl iodides has been developed. This novel reductive cross-coupling reaction produces 2-sufonylated 1,3-dienes as single products in the presence metal Mn high regio- chemoselectivities. Control experiments demonstrated that transformation may undergo a radical process.

Язык: Английский

Процитировано

0
Palladium(ii)-catalyzed 1,3-heteroaryl acyloxylation of propargylic electrophiles DOI
Shenghan Teng,

Peiyao Liang,

Lin Hu

и другие.

Organic Chemistry Frontiers, Год журнала: 2024, Номер 11(15), С. 4077 - 4083

Опубликована: Янв. 1, 2024

Here, we report a regio- and stereo-defined 1,3-heteroaryl acyloxylation of 3-substituted propargylic esters with readily available heteroarenes including indoles, pyrroles, furans thiophenes under palladium catalysis.

Язык: Английский

Процитировано

0
Thiophene and benzo[b]thiophene DOI

Sean Chin Chan,

Andrii Monastyrskyi

Progress in heterocyclic chemistry, Год журнала: 2024, Номер unknown, С. 89 - 122

Опубликована: Янв. 1, 2024

Язык: Английский

Процитировано

0
Palladium-catalysed asymmetric cascade transformations of 4-alken-2-ynyl carbonates to construct complex frameworks DOI Creative Commons

Ze-Liang He,

Li Li, Zhichao Chen

и другие.

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 27, 2024

A palladium-catalysed asymmetric auto-tandem reaction between 4-alken-2-ynyl carbonates and diverse ortho-functionalized activated alkenes is reported, giving complex frameworks in moderate yields with excellent chemo-, regio- stereoselectivity.

Язык: Английский

Процитировано

0