Research on Chemical Intermediates, Год журнала: 2024, Номер 50(10), С. 4597 - 4617
Опубликована: Авг. 28, 2024
Язык: Английский
Research on Chemical Intermediates, Год журнала: 2024, Номер 50(10), С. 4597 - 4617
Опубликована: Авг. 28, 2024
Язык: Английский
Journal of Catalysis, Год журнала: 2025, Номер unknown, С. 116197 - 116197
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0Small, Год журнала: 2025, Номер unknown
Опубликована: Май 10, 2025
Abstract Photocatalytic acetylene (C 2 H ) semi‐hydrogenation reaction is an environmentally friendly process for ethylene 4 production. However, all attempts to enhance the C yield have faced kinetic limitations. Electronic metal‐support interaction (EMSI) effective approach constants by regulating adsorption and desorption capabilities of intermediates reactive species, promoting in forward direction. Herein, Pd/TiO catalysts are constructed a hydrothermal‐calculation method, forming EMSI effect between Pd TiO . Spectroscopy characterizations theoretical calculations demonstrate that promotes photo‐generated charge carriers from Pd. The control local electron density on nanoparticles directly influenced Gibbs free energy * This ultimately enhances consumption kinetics , while simultaneously suppressing facilitating Consequently, it modulates preferential order evolution semi‐hydrogenation, expediting production Therefore, achieves 99.7% conversion, 77.3% selectivity, TON C2H4 = 5960 within 3 h. work provides reference guidance subsequent construction efficient photocatalytic catalysts.
Язык: Английский
Процитировано
0Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 163950 - 163950
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0Research on Chemical Intermediates, Год журнала: 2024, Номер 50(10), С. 4597 - 4617
Опубликована: Авг. 28, 2024
Язык: Английский
Процитировано
2