Abstract
In
this
study,
Fe
3
O
4
nanoparticles
were
deposited
on
graphitic
carbon
nitride
(g‐C
N
),
which
was
subsequently
functionalized
with
sulfonic
acid
groups,
resulting
in
a
magnetically
separable
solid
catalyst.
The
synthesized
catalyst
comprehensively
characterized
using
FT‐IR,
EDX,
XRD,
TEM,
VSM,
elemental
analysis,
and
acid–base
titration
to
assess
its
structural
properties,
surface
morphology,
acidity.
Its
catalytic
performance
evaluated
the
ring‐opening
reaction
of
epoxides
alcohols,
demonstrating
excellent
substrate
versatility
efficiency
for
alcoholysis
various
epoxides.
inclusion
enabled
facile
recovery
an
external
magnet.
Furthermore,
exhibited
remarkable
reusability,
maintaining
consistent
activity
over
four
successive
cycles
negligible
decline.
Coordination Chemistry Reviews,
Год журнала:
2024,
Номер
514, С. 215900 - 215900
Опубликована: Май 8, 2024
Catalysis
stands
as
a
cornerstone
in
chemical
synthesis,
pivotal
advancing
sustainable
manufacturing
pathways.
The
evolution
from
energy-intensive
to
catalytic
processes
has
marked
transformative
shift,
notably
exemplified
by
low-energy
methods.
These
processes,
operating
under
milder
conditions
and
emphasizing
selectivity
recyclability,
represent
the
forefront
of
chemistry.
This
review
navigates
through
an
array
reactions,
highlighting
their
diverse
applications
culminating
exploration
recent
strides
within
processes.
For
example,
explores
uses
such
enzyme
mimicking,
biodiesel
production,
carbon
dioxide
capture,
organic
synthesis.
Additionally,
it
covers
enzymatic
catalysis
photocatalysis
for
transformations,
energy
applications,
water
treatment.
Notably,
emphasizes
capabilities
single-atom
(SAC)
diatomic
catalysts
(DACs),
recognizing
exceptional
performance
catalyzing
reactions
at
minimal
activation
energies
while
maintaining
high
efficiency
mild
conditions.
By
elucidating
modulation
electronic
structure
offering
microelectronic
perspective,
aims
elucidate
mechanisms
underlying
activity
SAC
DACs.
Emphasizing
interplay
between
coordination
chemistry
principles
efficacy,
elucidates
indispensable
role
complexes
fortifying
sustainability
these
spotlighting
fusion
with
catalysis,
this
underscore
collective
influence
shaping
landscape
production.
Sustainable Energy & Fuels,
Год журнала:
2024,
Номер
8(17), С. 3775 - 3800
Опубликована: Янв. 1, 2024
The
in
situ
hydrogenation
of
lignocellulosic
biomass
and
its
derivatives
using
liquid
hydrogen
carriers
heterogeneous
catalysts
provides
greener
sustainable
methodologies
for
producing
biofuels
chemicals.
Abstract
The
methodology
of
nanoarchitectonics
is
to
construct
functional
materials
using
nanounits
such
as
atoms,
molecules,
and
nanoobjects,
just
like
architecting
buildings.
Nanoarchitectonics
pursues
the
ultimate
concept
science
through
integration
related
fields.
In
this
review
paper,
under
title
interface‐interactive
nanoarchitectonics,
several
examples
structure
fabrication
function
development
at
interfaces
will
be
discussed,
highlighting
importance
with
nanoscale
considerations.
Two
sections
provide
some
solid
liquid
surfaces.
interfacial
environments,
molecular
structures
can
precisely
observed
analyzed
theoretical
calculations.
Solid
surfaces
are
a
prime
site
for
level.
has
potential
pave
way
cutting‐edge
functionality
based
on
advanced
observation
analysis.
Liquid
more
kinetic
dynamic
than
interfaces,
their
high
fluidity
offers
many
possibilities
fabrications
by
nanoarchitectonics.
latter
feature
advantages
in
terms
freedom
interaction
diversity
components,
therefore,
may
suitable
environments
functionalities.
final
section
then
discusses
what
needed
future
material
creation
Molecules,
Год журнала:
2024,
Номер
29(18), С. 4353 - 4353
Опубликована: Сен. 13, 2024
Phenylhydroxylamine
and
its
derivates
(PHAs)
are
important
chemical
intermediates.
Phenylhydroxylamines
mainly
produced
via
the
catalytic
reduction
of
aromatic
nitro
compounds.
However,
this
method
prefers
to
generate
thermodynamically
stable
amine.
Thus,
designing
suitable
systems,
especially
catalysts
selectively
convert
compounds
PHAs,
has
received
increasing
attention
but
remains
challenging.
In
review,
we
initially
provide
a
brief
overview
various
strategies
employed
for
synthesis
focusing
on
reducing
Subsequently,
an
in-depth
analysis
is
presented
process,
encompassing
discussions
catalysts,
reductants,
hydrogen
sources,
comprehensive
assessment
merits
drawbacks
systems.
Furthermore,
concise
provided
regarding
progress
made
in
comprehending
mechanisms
involved
process
Finally,
main
challenges
prospects
PHAs'
production
outlined.
Journal of Physics Condensed Matter,
Год журнала:
2024,
Номер
37(5), С. 053001 - 053001
Опубликована: Ноя. 8, 2024
Abstract
Nanotechnology
has
elucidated
scientific
phenomena
of
various
materials
at
the
nano-level.
The
next
step
in
developments
is
to
build
up
materials,
especially
condensed
matter,
based
on
such
nanotechnology-based
knowledge.
Nanoarchitectonics
can
be
regarded
as
a
post-nanotechnology
concept.
In
nanoarchitectonics,
functional
material
systems
are
architected
from
nanounits.
Here,
this
review
would
like
focus
layered
structures
terms
structure
formation.
unit
mostly
two-dimensional
or
thin-film
materials.
They
attractive
that
have
attracted
much
attention
modern
matter
science.
By
organizing
them
into
structures,
we
expect
develop
functions
communication
between
layers.
Building
by
assembling
nano-layers
units
typical
approach
nanoarchitectonics.
discussion
will
divided
following
categories:
hard
hybrid,
soft
and
living
object.
For
each
target,
several
recent
research
examples
given
illustrate
discussion.
This
paper
extract
what
aspects
considered
important
creation
component.
Layering
strategies
need
adapted
characteristics
components.
type
structural
precision
functionality
required
highly
dependent
flexibility
mobility
Furthermore,
needed
nanoarchitectonics
discussedas
future
perspectives.
