Cited by Inorganic–Organic Bi4Nb1–xTaxO8Cl/rGO/SA-PTA Z-Scheme Heterojunction with a Third-Order Polarized Electric Field and a Fast Electron Transfer Channel for Photocatalytic Overall Water Splitting

Enabling Unconventional “Alternating‐Distal” N₂ Reduction Pathway for Efficient Ammonia Electrosynthesis DOI

Chu Zhang, Qing Wang, Zeyu Li

и другие.

Angewandte Chemie International Edition, Год журнала: 2025, Номер unknown

Опубликована: Март 10, 2025

The general understanding on the reaction path is that electrocatalytic N2 reduction follows either individual associative alternating or distal pathways, where efficient activation and selective NH3 production are very challenging. Herein, an unconventional "alternating-distal" pathway was achieved by shifting "*NHNH2→*NH2NH2" to "*NHNH2→*NH + NH3" step boost synthesis with amorphous CeMnOx electrocatalyst. In this process, realized through π back donation Mn site, while Mn/Ce dual active sites could regulate intermediate configurations avoid nitrogen-containing by-product formation. Such affirmed in situ spectroscopic analyses theoretical calculations. a neutral media, average ammonia rate of 82.8 µg h-1 mg-1 outstanding Faradaic efficiency 37.3% were attained. This work validated mechanism synthesis, which might be extended other catalytic process multiple possible paths.

Язык: Английский

Процитировано

Hollow structured photocatalysts DOI

Fangxuan Liu,

Ziyan Liu,

Guowei Zhou

и другие.

Acta Physico-Chimica Sinica, Год журнала: 2025, Номер unknown, С. 100071 - 100071

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

Boosting ammonia electrosynthesis via interfacial tandem nitrate reduction enabled by an amorphous@crystalline electrocatalyst DOI

Zeyu Li, Qing Wang, Lixiang Zhong

и другие.

Materials Today, Год журнала: 2025, Номер unknown

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

Regulating the electronic structure of BiOBr by Cu-doping to promote efficient photocatalytic nitrogen fixation reaction DOI

Yongchong Yu,

Ping Zhang,

Reyila Tuerhong

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132501 - 132501

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

Inorganic–Organic Bi₄Nb_1–xTa_xO₈Cl/rGO/SA-PTA Z-Scheme Heterojunction with a Third-Order Polarized Electric Field and a Fast Electron Transfer Channel for Photocatalytic Overall Water Splitting DOI

Kailong Gao,

Qi He,

Liuna Zhang

и другие.

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 5155 - 5170

Опубликована: Март 12, 2025

Язык: Английский

Процитировано