Journal of Organometallic Chemistry, Год журнала: 2025, Номер unknown, С. 123572 - 123572
Опубликована: Фев. 1, 2025
Язык: Английский
Journal of Organometallic Chemistry, Год журнала: 2025, Номер unknown, С. 123572 - 123572
Опубликована: Фев. 1, 2025
Язык: Английский
Journal of Materials Chemistry A, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
The need to minimize carbon emissions and improve sustainable energy systems has stimulated significant research into multifunctional materials.
Язык: Английский
Процитировано
7Fuel, Год журнала: 2025, Номер 387, С. 134416 - 134416
Опубликована: Янв. 21, 2025
Язык: Английский
Процитировано
3Chemical Society Reviews, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
This review examines the strategies of symmetry breaking (charge/coordination/geometric) in single-atom catalysts to regulate active site electronic structures, greatly enhancing catalytic performance.
Язык: Английский
Процитировано
3ACS Sustainable Chemistry & Engineering, Год журнала: 2025, Номер unknown
Опубликована: Янв. 16, 2025
Electrocatalytically converting nitrates in sewage to ammonia, which can not only achieve the purpose of eliminating but also obtaining valuable is an effective supplement traditional Haber–Bosch process. Although significant progress has been made cathodic catalyst design, overall ammonia electrolysis from nitrate reduction still restricted by anodic oxygen evolution heavily relying on noble-based catalysts. Herein, a bimetallic NiFe-MOF nanosheet array electrode fabricated and serves as efficient bifunctional for reactions. The introduction Fe Ni-MOF facilitates formation structure with higher electrochemical active surface area, well provides synergetic NiFe sites. reaches greatly enhanced yield rate 0.94 mmol cm–2 h–1 Faradaic efficiency 90.8% at cathode −0.6 V versus reversible hydrogen electrode, reaction declined overpotential 424 mV 50 mA cm–2. As electrocatalysis, performance comparable that using Pt mesh counter electrode.
Язык: Английский
Процитировано
2Fuel, Год журнала: 2025, Номер 390, С. 134595 - 134595
Опубликована: Фев. 16, 2025
Язык: Английский
Процитировано
2Ionics, Год журнала: 2025, Номер 31(3), С. 2909 - 2918
Опубликована: Янв. 15, 2025
Язык: Английский
Процитировано
1Journal of Sol-Gel Science and Technology, Год журнала: 2025, Номер unknown
Опубликована: Янв. 26, 2025
Язык: Английский
Процитировано
1International Journal of Environmental & Analytical Chemistry, Год журнала: 2025, Номер unknown, С. 1 - 17
Опубликована: Янв. 30, 2025
Язык: Английский
Процитировано
1International Journal of Hydrogen Energy, Год журнала: 2025, Номер 106, С. 411 - 422
Опубликована: Фев. 4, 2025
Язык: Английский
Процитировано
1Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown
Опубликована: Фев. 4, 2025
Abstract The effective use of metal‐organic framework (MOF)‐based materials in the electrocatalytic hydrogen evolution reaction (HER) relies on understanding their structural and electronic properties. While structure morphology MOF‐derived catalysts significantly impact HER activity, tuning d‐band through modulation has emerged as a key factor optimizing catalytic performance. Techniques such composition tuning, heteroatom doping, surface modification, interface engineering were found to be methods for manipulating configuration and, turn, modulating d‐band. This review systematically explores design strategies by focusing modulation. It provides detailed discussion various – used modulate structure. Furthermore, establishes relationship between Gibbs free energy, modulation, supported both spectroscopic theoretical evidences.
Язык: Английский
Процитировано
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