The Journal of Organic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Май 22, 2025

An external reductant-free and acid-free synthesis of phosphonothioates from odorless sodium sulfinates induced by CCl4 (1.0 equiv) under mild conditions has been achieved. This transformation provides an efficient synthetic approach to in up 98% yield with good functional group compatibility. In addition, unexpected CCl4-induced sulfoxides sulfones using DMSO as the solvent developed.

Язык: Английский