Catalyzed carbon-based materials for CO₂-battery utilization

Energy Materials, Год журнала: 2025, Номер 5(4)

Опубликована: Янв. 23, 2025

Increasing atmospheric CO2 levels and global carbon neutrality goals have driven interest in technologies that both mitigate emissions provide sustainable energy storage solutions. Metal-carbon dioxide (M-CO2) batteries offer significant promise due to their high density potential utilize CO2. A key challenge advancing M-CO2 lies optimizing CO2-breathing cathodes, which are essential for adsorption, diffusion, conversion. Carbon-based cathodes play a critical role facilitating redox batteries, owing cost-effectiveness, conductivity, tunable microstructure, porosity. However, there is lack of current systematic understanding the relationship between structure, composition, catalytic properties carbon-based as well impact on overall efficiency, stability, durability batteries. In this review, we will give an insightful review analysis recent advances various materials, including commercial carbons, single-atom catalysts, transition metal/carbon composites, metal-organic frameworks, etc. , focusing structure-function-property relationships. comprehensive pivotal played by materials optimization strategies be provided. Moreover, future perspectives research suggestions presented advance development innovation

Язык: Английский

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Electrocatalytic nitrite reduction to ammonia on isolated bismuth alloyed ruthenium

Journal of Energy Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Сен. 1, 2024

Язык: Английский

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Nanoconfinement and tandem catalysis over yolk-shell catalysts towards electrochemical reduction of CO2 to multi-carbon products

Journal of Colloid and Interface Science, Год журнала: 2025, Номер 687, С. 733 - 741

Опубликована: Фев. 15, 2025

Язык: Английский

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Multiple active site metal-based catalysts for C-N coupling reactions and the beyond

Next Materials, Год журнала: 2025, Номер 8, С. 100555 - 100555

Опубликована: Фев. 21, 2025

Язык: Английский

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Electrosynthesis of Urea on High‐Density Ga─Y Dual‐Atom Catalyst via Cross‐Tuning

Advanced Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 25, 2025

Abstract Electrochemically converting carbon dioxide (CO 2 ) and nitrate (NO 3 − into urea via the C─N coupling route offers a sustainable alternative to traditional industrial production technology, but it is still limited by poor yield rate, low Faradaic efficiency, insufficient kinetics. Herein, high‐density Ga─Y dual‐atom catalyst developed with loading up 14.1 wt.% of Ga Y supported on N, P‐co‐doped substrate (Ga/Y‐CNP) for electrosynthesis. The facilitates efficient through co‐reduction CO NO , resulting in high rate 41.9 mmol h −1 g efficiency 22.1% at −1.4 V versus reversible hydrogen electrode. In situ spectroscopy theoretical calculations reveal that superior performance attributed cross‐tuning between adjacent pair sites, which can mutually optimize their electronic states facilitating reduction *CO sites promoting conversion hydroxylamine (*NH OH) followed spontaneous *NH OH intermediates form bonds. This work pioneering strategy manipulate pathways active produce high‐value‐added chemicals.

Язык: Английский

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Recent progress in electrocatalytic C-N coupling of CO2 and inorganic N-containing small molecules

Science China Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 5, 2025

Язык: Английский

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Efficient urea synthesis by coupling catalyst of nickel-single-atom and copper-cluster

Journal of Material Science and Technology, Год журнала: 2025, Номер unknown

Опубликована: Март 1, 2025

Язык: Английский

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Oxygen-Vacancy-Engineered Cr₂CO₂ Electrocatalysts for Efficient Urea Synthesis from Nitrite and Carbon Monoxide

Applied Catalysis B Environment and Energy, Год журнала: 2025, Номер unknown, С. 125327 - 125327

Опубликована: Март 1, 2025

Язык: Английский

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Electrode–Electrolyte Engineering and In Situ Spectroscopy for Urea Electrosynthesis from Carbon Dioxide and Nitrate Co-Reduction

JACS Au, Год журнала: 2025, Номер unknown

Опубликована: Апрель 3, 2025

Язык: Английский

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Catalyst and gas diffusion electrode design toward C–N coupling for urea electrosynthesis

eScience, Год журнала: 2025, Номер unknown, С. 100425 - 100425

Опубликована: Апрель 1, 2025

Язык: Английский

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