Advances and Prospects of Selective Electrocatalytic Upgrading of 5‐Hydroxymethylfurfural to Furan‐2,5‐Dicarboxylic Acid
The Chemical Record,
Год журнала:
2025,
Номер
unknown
Опубликована: Март 3, 2025
Abstract
The
electrocatalytic
upgrading
of
5‐hydroxymethylfurfural
(HMF,
5‐(Hydroxymethyl)
furan‐2‐carbaldehyde)
has
emerged
as
a
renewable
and
environmentally
friendly
means
for
the
production
high‐value
chemicals,
with
oxidation
product
furan‐2,5‐dicarboxylic
acid
(FDCA,
2,5‐furandicarboxylic
acid)
possessing
economic
viability
in
substituting
terephthalic
polymer
synthesis.
This
article
reviews
recent
advancements
selective
HMF
to
FDCA,
including
reaction
pathways,
mechanisms,
well
activity
descriptors
(HMFOR),
alongside
advanced
operando
characterization
techniques.
Subsequently,
representative
HMFOR
catalysts,
encompassing
noble
metal,
non‐noble
transition
metal‐based
catalysts
metal
free‐based
are
presented.
Then
strategies
regulating
longevity
were
introduced,
followed
by
an
exploration
future
prospects
development
catalysts.
Язык: Английский
Anionic regulation Fe/NiOOH electrocatalysts to boost electrooxidation performance of biomass derived 5-hydroxymethylfurfural
Journal of Colloid and Interface Science,
Год журнала:
2025,
Номер
unknown, С. 137510 - 137510
Опубликована: Апрель 1, 2025
Язык: Английский
A Review of Ni-Based Electrode Materials for Electrocatalytic Oxygen Evolution Reaction
Shuwei Guo,
Qi Lu,
Xiwen Zhou
и другие.
Energy & Fuels,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 17, 2025
Язык: Английский
Refining Electrocatalyst Design for 5-Hydroxymethylfurfural Oxidation: Insights into Electrooxidation Mechanisms, Structure–Property Correlations, and Optimization Strategies
ACS Catalysis,
Год журнала:
2025,
Номер
unknown, С. 7308 - 7339
Опубликована: Апрель 18, 2025
Язык: Английский
Ni‐Based Catalysts for 5‐Hydroxymethylfurfural Electrooxidation Coupled with Hydrogen Production
ChemElectroChem,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 21, 2025
This
review
presents
a
comprehensive
analysis
of
Ni‐based
catalysts
for
the
co‐electrolysis
H
2
O
and
5‐hydroxymethylfurfural
(HMF)
under
alkaline
conditions,
enabling
co‐production
low‐carbon
hydrogen
2,5‐furandicarboxylic
acid
(FDCA),
key
biobased
platform
chemical.
First,
recent
advances
in
elucidating
mechanism
HMF
electrooxidation
(HMFOR)
to
FDCA
on
Ni
are
examined.
Next,
an
in‐depth
evaluation
HMFOR
performance
various
is
provided,
highlighting
effects
doping
or
combining
with
transition
metals
such
as
Fe,
Co,
Cu,
Mn,
well
multimetallic
compositions.
Finally,
activity
compared
across
studies
identify
trends
propose
research
directions
scaling
this
technology
industrial
level.
Язык: Английский