Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications
Chemical Society Reviews,
Год журнала:
2024,
Номер
53(12), С. 6244 - 6294
Опубликована: Янв. 1, 2024
This
review
highlights
the
promising
prospects
of
defective
zirconium-based
MOFs
in
addressing
challenging
energy-
and
environment-related
problems,
positioning
them
as
versatile
tools
toward
a
cleaner
more
sustainable
future.
Язык: Английский
Benefits and complexity of defects in metal-organic frameworks
Communications Materials,
Год журнала:
2024,
Номер
5(1)
Опубликована: Ноя. 8, 2024
Defect
engineering
has
developed
over
the
last
decade
to
become
an
inimitable
tool
with
which
shape
Metal-Organic
Framework
(MOF)
chemistry;
part
of
evolution
in
perception
MOFs
from
perfect,
rigid
matrices
dynamic
materials
whose
chemistry
is
shaped
as
much
by
imperfections
it
their
molecular
components.
However,
challenges
defect
characterisation
and
reproducibility
persist
and,
coupled
as-yet
opaque
role
for
synthetic
parameters
formation,
deny
chemists
full
potential
reticular
synthesis.
Herein
we
map
broad
implications
defects
have
on
MOF
properties,
highlight
key
explore
remarkable
ways
imperfection
enriches
chemistry.
Engineering
into
metal-organic
frameworks
a
strategy
grant
additional
properties
but
there
are
still
reproducibility.
Here,
this
Perspective
presents
benefits
framework
field.
Язык: Английский
Enhancing Biocatalysis: Metal–Organic Frameworks as Multifunctional Enzyme Hosts
Accounts of Chemical Research,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 28, 2024
ConspectusEnzymes
are
highly
efficient
and
selective
catalysts
that
operate
under
mild
conditions,
making
them
invaluable
for
various
chemical
transformations.
However,
their
limitations,
such
as
instability
high
cost,
call
advancements
in
enzyme
immobilization
the
development
of
suitable
host
materials.
Metal-organic
frameworks
(MOFs),
characterized
by
porosity,
crystallinity,
tunability,
promising
candidates
encapsulation.
Among
these,
zirconium-based
MOFs
(Zr-MOFs)
stand
out
due
to
exceptional
structural
diversity
stability.
The
physical
properties
Zr-MOFs
can
be
tuned
with
atomic
precision,
interactions
enzymes
analyzed
through
a
range
techniques
spanning
from
chemistry
materials
science
biochemistry.
This
tunable
platform
provides
opportunities
systematically
investigate
impact
encapsulation
on
stability
activity
order
develop
design
rules
hosts.In
this
Account,
we
discuss
experimentally
validated
concepts
designing
MOF
hosts
based
mechanisms.
We
present
methods
enhance
catalytic
performance
strategies
creating
multifunctional
enzyme@MOF
systems
via
modifications.
start
highlighting
importance
maximizes
substrate
diffusion
availability,
particular
focus
containing
hierarchical
mesoporous
structures
those
Язык: Английский
Defective UiO-66-NH2 enrichment medium for effective extraction and sensitive analysis of haloacetic acid disinfection by-products in tea drinks
Talanta,
Год журнала:
2025,
Номер
unknown, С. 128424 - 128424
Опубликована: Июнь 1, 2025
Язык: Английский
Two Cobaltous PCPs: Rapid Catalytic Degradation of POPs Coupled with Remarkable Antibacterial and Antifungal Properties
Dalton Transactions,
Год журнала:
2024,
Номер
53(43), С. 17694 - 17701
Опубликована: Янв. 1, 2024
Two
cobalt-based
porous
coordination
polymers
(PCPs):
[Co
3
(BTC)
2
(H
O)
12
]
n
(1)
and
(DMP)
8
(2)
exhibit
rapid
catalytic
degradation
of
POPs
viz.
dyes
nitroaromatics
along
with
remarkable
antimicrobial
activities.
Язык: Английский
A Fluorescent Nanoplatform Based on Tb3+@tartric Acid-Functionalized UiO-67-bpy: A New Strategy of Synergistic Sensitization and its Highly Sensitive Performance toward the Detection of Nitenpyram
Journal of Inorganic and Organometallic Polymers and Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 15, 2024
Язык: Английский