Sustainable synthesis of iron-doped manganese oxide nanoparticles for effective photo-accelerated detoxification of tetracycline DOI Creative Commons

Sanjay S. Majani,

M. A. Veena,

Chetan Kumar

и другие.

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Май 24, 2025

The widespread use of antibiotics has severely impacted water bodies and ecosystems, necessitating well-designed photocatalysts for effective degradation. In this regard, present work reports the synthesis MnO2:xFe3+ (MF-x, x = 0, 2, 4, 6, 8, 10) nanoparticles via bio-mediated process using Tridax procumbens as reducing stabilizing agents. Various physicochemical approaches confirmed structural, optical, morphological properties MF-x nanoparticles, revealing a reduced optical bandgap (2.06-0.97 eV) visible-light photocatalysis. PXRD analysis reveals cubic crystalline nature belonging to space group number 206 (I a-3) with crystallite sizes ranging 39-70 nm, which was further refined Rietveld method acceptable χ2 value 2.3 doped sample. Raman spectra existence Fg Eg + active modes from bixbyite structure corresponding I a-3. Furthermore, FESEM TEM analyses showed highly uniform porous morphology evaluated particle in agreement results. Additionally, quantitative aspects precursor elements were through XPS studies. photocatalytic activity MF-10 degrading Tetracycline hydrochloride (TC-HCl) under optimized pH, catalyst dosage, TC-HCl concentration visible light. Results show that weight (100 mg) as-synthesized exhibit high performance 94.23% degradation against 20 ppm 90 min. On other hand, pH variation reusability test indicated efficiency significant at neutral 5th cycle (64.28) authenticated by pHPZC evaluation (7.55). Thus, showcased potential application MnO2: Fe3+ low-cost environmentally friendly material treatment applications.

Язык: Английский

Advances of Metal‐Based Nanomaterials in the Prevention and Treatment of Oral Infections DOI
Junnan Qi,

Chao Si,

Haofeng Liu

и другие.

Advanced Healthcare Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 17, 2025

The complicated environment of the oral cavity presents significant challenges to traditional antibacterial approaches, which has driven exploration novel therapeutic strategies. Metal-based nanomaterials (MNMs), with diverse mechanisms (e.g., membrane disruption, oxidative stress) and evolution from empirical theory-guided design, exhibit immense potential. This review introduces pioneering Hierarchical Response Strategy Framework, systematically classifying MNM systems into three progressive levels: Primary category, comprising MNMs that exert spontaneous effects based on inherent physicochemical properties ion release); Secondary including precisely controlled actions by microenvironmental or stimulus-responsive light-induced ROS); Tertiary encompassing integrate regenerative functions for multidimensional therapy remineralization). Through this framework, authors elucidate MNMs' transition single-function precision-controlled, multifunctional synergy, analyze impact metal elements structural design efficacy, summarize their applications in dental caries, endodontic infections, periodontal disease, etc. framework offers a perspective existing research theoretical foundation rational next-generation precise, smart, comprehensive anti-infective materials.

Язык: Английский

Процитировано

0

Gelatin Assisted Green Synthesis of Silver Ferrite Nanoparticles Using Capparis Cartilaginea Extract for Enhanced Antimicrobial Activity DOI
Naif A. R. Almalki, Musab Aldhahri, Saleh M. Al‐Maaqar

и другие.

ChemistrySelect, Год журнала: 2025, Номер 10(17)

Опубликована: Апрель 29, 2025

Abstract In this study, Capparis cartilaginea extract was used as a reducing and stabilizing agent to perform an eco‐friendly synthesis of gelatin‐coated silver ferrite nanoparticles (GAgFeO 2 ). The had crystallite size approximately 25 nm were characterized via X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field‐emission scanning electron microscopy (FESEM), Brunauer–Emmett–Teller (BET) surface area analysis. BET analysis revealed that the gelatin coating results in GAgFeO having slightly lower specific (22.87 m /g), than AgFeO had. exhibited moderate stability with zeta potential −17.5 mV, while showed higher −23.8 indicating stronger electrostatic repulsion enhanced colloidal stability. Antimicrobial tests 26 mm inhibition zone against MRSA, 14 Pseudomonas aeruginosa , 16 Salmonella Typhimurium outperforming uncoated nanoparticles. minimum inhibitory concentration (MIC) Candida albicans 0.062 mg/mL antifungal potential. These demonstrate superior antimicrobial efficacy well their application medical environmental fields.

Язык: Английский

Процитировано

0

Sustainable synthesis of iron-doped manganese oxide nanoparticles for effective photo-accelerated detoxification of tetracycline DOI Creative Commons

Sanjay S. Majani,

M. A. Veena,

Chetan Kumar

и другие.

Scientific Reports, Год журнала: 2025, Номер 15(1)

Опубликована: Май 24, 2025

The widespread use of antibiotics has severely impacted water bodies and ecosystems, necessitating well-designed photocatalysts for effective degradation. In this regard, present work reports the synthesis MnO2:xFe3+ (MF-x, x = 0, 2, 4, 6, 8, 10) nanoparticles via bio-mediated process using Tridax procumbens as reducing stabilizing agents. Various physicochemical approaches confirmed structural, optical, morphological properties MF-x nanoparticles, revealing a reduced optical bandgap (2.06-0.97 eV) visible-light photocatalysis. PXRD analysis reveals cubic crystalline nature belonging to space group number 206 (I a-3) with crystallite sizes ranging 39-70 nm, which was further refined Rietveld method acceptable χ2 value 2.3 doped sample. Raman spectra existence Fg Eg + active modes from bixbyite structure corresponding I a-3. Furthermore, FESEM TEM analyses showed highly uniform porous morphology evaluated particle in agreement results. Additionally, quantitative aspects precursor elements were through XPS studies. photocatalytic activity MF-10 degrading Tetracycline hydrochloride (TC-HCl) under optimized pH, catalyst dosage, TC-HCl concentration visible light. Results show that weight (100 mg) as-synthesized exhibit high performance 94.23% degradation against 20 ppm 90 min. On other hand, pH variation reusability test indicated efficiency significant at neutral 5th cycle (64.28) authenticated by pHPZC evaluation (7.55). Thus, showcased potential application MnO2: Fe3+ low-cost environmentally friendly material treatment applications.

Язык: Английский

Процитировано

0