The imperative for sensing innovations toward lab on cell in battery technology: a holistic survey of the emerging trend of embedding sensor technologies in electrochemical cells DOI Creative Commons
Guillaume Thenaisie, Luis D. Couto

Deleted Journal, Год журнала: 2024, Номер 1(1)

Опубликована: Ноя. 25, 2024

Abstract The rapid evolution of battery technology has sparked an urgent need for advanced monitoring and diagnostic capabilities. This comprehensive review explores the emerging concept Lab-on-Cell (LoC), a paradigm shift in management that integrates sophisticated sensing technologies directly into electrochemical cells. Through meticulous analysis, study examines cutting-edge sensor technologies, including resistive thermoelectric sensors, piezoelectric devices, impedance spectroscopy, optical fiber sensors. It delves their principles, applications, limitations within context diagnostics. Uniquely, this intertwines technological assessment with geopolitical economic context, charting LoC against backdrop global events policy shifts. sheds light on complex drivers innovation field, drawing connections between research trends, industrial needs, regulatory changes. introduces novel dual-reference system, separating general LoC-specific sources to cater diverse readership. culminates forward-looking analysis technologies’ potential impact systems, cell design, manufacturing processes. By weaving together advancements, market forces, future projections, in-depth examination provides holistic view landscape. stands as vital resource researchers, industry professionals, policymakers navigating intricate energy storage technologies.

Язык: Английский

Development of Polymer-based Artificial Solid Electrolyte Interphase for Safer Li-Metal Batteries: Challenges, Strategies and Prospects DOI
Tianyi Wang, Xin Liu, Shifei Huang

и другие.

Nano Energy, Год журнала: 2024, Номер 129, С. 109970 - 109970

Опубликована: Июль 8, 2024

Язык: Английский

Процитировано

18

In Situ TEM Characterization of Battery Materials DOI
Diyi Cheng, Jinseok Hong, Daewon Lee

и другие.

Chemical Reviews, Год журнала: 2025, Номер unknown

Опубликована: Фев. 4, 2025

Transmission electron microscopy (TEM) is an indispensable analytical technique in materials research as it probes material information down to the atomic level and can be utilized examine dynamic phenomena during transformations. In situ TEM resolves transient metastable states via direct observation of dynamics under external stimuli. With innovative sample designs developed over past decades, advanced has enabled emulation battery operation conditions unveil nanoscale changes within electrodes, at interfaces, electrolytes, rendering a unique tool offer unequivocal insights that are beam-sensitive, air-sensitive, or contain light elements, etc. this review, we first briefly outline history along with research, followed by introduction various cell configurations. We provide comprehensive review on studies for lithium batteries beyond (e.g., sodium other chemistries) open-cell closed-cell approaches. At end, raise several unresolved points regarding preparation protocol, imaging conditions, etc., experiments. also outlook next-stage development study, aiming foster closer collaboration between communities mutual progress.

Язык: Английский

Процитировано

5

The mystic role of high-entropy designs in rechargeable metal-ion batteries: A review DOI
Yi‐Cheng Lin, Shaohua Luo, Wei Zhao

и другие.

Journal of Energy Chemistry, Год журнала: 2024, Номер 98, С. 441 - 471

Опубликована: Июль 4, 2024

Язык: Английский

Процитировано

16

Nucleation, growth and dissolution of Li metal dendrites and the formation of dead Li in Li-ion batteries investigated by operando electrochemical liquid cell scanning transmission electron microscopy DOI Creative Commons
Walid Dachraoui, Ruben‐Simon Kühnel, Corsin Battaglia

и другие.

Nano Energy, Год журнала: 2024, Номер 130, С. 110086 - 110086

Опубликована: Авг. 3, 2024

Li metal dendrites, which can form on the anode of Li-ion batteries during charging, not only accelerate their aging but may also pose a safety hazard when causing short-circuit within battery. Therefore, fundamental understanding mechanisms governing early stages plating, progression into and formation dead Li, is imperative. Here, we employ operando electrochemical liquid cell scanning transmission electron microscopy (ec-LC-STEM) to monitor, in real-time, nanoscale processes occurring at anode-electrolyte interface battery charge/discharge. Our results indicate that dendrites nucleate as spherical nanoparticles beneath solid electrolyte interphase (SEI) subsequently grow until dendritic formed. During discharge, undergo incomplete dissolution, leading Li. Interestingly, SEI layers play pivotal role both growth dissolution processes. findings reveal multi-step process: (i) nucleation, (ii) root growth, (iii) tip growth. We elucidate associated with morphology initially developed structure layer. The thinning inhomogeneously thick whiskers leads contraction before tip, ultimately resulting creation electrically isolated metal. This work sheds light well provides significant insights for future electrode designs.

Язык: Английский

Процитировано

14

An Unexpected Low‐Temperature Battery Formation Technology Enabling Fast‐Charging Graphite Anodes DOI Open Access

Ruilin Hou,

Linlin Zheng,

Tianze Shi

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 16, 2025

Abstract The battery formation process is pivotal for constructing a solid electrolyte interphase (SEI) on graphite anodes, generally conducted at high temperatures. However, the resulting excessive SEI film causes significant lithium loss and an inferior charging rate. Herein, unconventional low‐temperature technology based innovative temperature‐responsive with anion‐dominated solvation structure low temperature validated. During cycling 5 °C, enhanced anion–cation interaction, coupled suppressed solvent decomposition, facilitates generation of thin fluoride‐rich film. Consequently, anodes exhibit 5C fast‐charging performance (198.89 mAh g −1 , 53.39% theoretical capacity), successfully overcoming rate bottleneck 2C commonly encountered in commercial realize 95.88% capacity retention after 400 cycles 0.5C. Moreover, compared to traditional high‐temperature formation, saves 52.73% (from 22.02 10.42 h) time reduces from 16.76% 7.21%. This work highlights importance opportunities utilizing as “driving force” regulating interfacial chemistry.

Язык: Английский

Процитировано

2

Electrolyte design to regulate the electrode–electrolyte interface on the electrochemical performance for K0.5MnO2||graphite-based potassium-ion batteries DOI
Yi‐Cheng Lin, Shaohua Luo, Pengwei Li

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 490, С. 151540 - 151540

Опубликована: Апрель 22, 2024

Язык: Английский

Процитировано

8

Advances in Electrochemical Liquid-Phase Transmission Electron Microscopy for Visualizing Rechargeable Battery Reactions DOI
Honglu Hu, Ruijie Yang, Zhiyuan Zeng

и другие.

ACS Nano, Год журнала: 2024, Номер 18(20), С. 12598 - 12609

Опубликована: Май 9, 2024

This review presents an overview of the application electrochemical liquid-phase transmission electron microscopy (ELP-TEM) in visualizing rechargeable battery reactions. The technique provides atomic-scale spatial resolution and real-time temporal resolution, enabling direct observation analysis materials processes under realistic working conditions. highlights key findings insights obtained by ELP-TEM on reaction mechanisms discusses current limitations future prospects ELP-TEM, including improvements expansion scope systems that can be studied. Furthermore, underscores critical role understanding optimizing design fabrication high-performance, long-lasting batteries.

Язык: Английский

Процитировано

8

Titanium Nitride Microelectrode: A New Candidate for In Situ Electrochemical Transmission Electron Microscopy Study DOI Creative Commons
Junbeom Park, Ningyan Cheng, Binghui Ge

и другие.

Advanced Engineering Materials, Год журнала: 2024, Номер 26(10)

Опубликована: Март 11, 2024

In situ transmission electron microscopy (TEM) is increasingly utilized by researchers to explore various electrochemical applications in the quest address climate change, aiming comprehend underlying mechanisms and enhance performance. However, conventional Pt microelectrode commonly used TEM poses limitations due its low transparency high catalytic activity. this study, titanium nitride (TiN x ) introduced as a novel material that can be fabricated following typical cleanroom processes. Through Zn Cu electrodeposition studies, it shown how activity higher of TiN enable obtaining stable cycling quantify deposition on top mode, highlighting benefit microelectrodes for different studies.

Язык: Английский

Процитировано

4

Recent progress about transmission electron microscopy characterizations on lithium-ion batteries DOI
Yihang Liu,

Qiuyun Li,

Ziqiang Wang

и другие.

Journal of Energy Chemistry, Год журнала: 2024, Номер 95, С. 39 - 56

Опубликована: Март 27, 2024

Язык: Английский

Процитировано

4

In‐situ polymerized solid/quasi‐solid polymer electrolyte for lithium‐metal batteries: recent progress and perspectives DOI Open Access
Hangyu Zhang, Xijun Xu,

Weizhen Fan

и другие.

Chemistry - A European Journal, Год журнала: 2024, Номер unknown

Опубликована: Окт. 11, 2024

Abstract In pursuit of high energy density, lithium metal batteries (LMBs) are undoubtedly the best choice. However, leakage and inevitable dendrite growth in liquid electrolytes seriously hinder its practical application. Solid/quasi‐solid state have emerged as an answer to solve above issues. Especially, polymer with excellent interface compatibility, flexibility, ease machining become a research hotspot for LMBs. Nevertheless, contact between electrolyte inorganic electrode materials low ionic conductivity restrict development. On account these, situ polymerized is proposed. Polymer solid produced through polymerization promote robust while simplifying preparation steps. This review summarized latest progress These were divided into three parts according their methods: thermally induced polymerization, chemical initiator ionizing radiation so on. Furthermore, we concluded major challenges future trends It's hoped that this will provide meaningful guidance on designing high‐performance

Язык: Английский

Процитировано

4