Far-From-Equilibrium Processing Opens Kinetic Paths for Engineering Novel Materials by Breaking Thermodynamic Limits

ACS Materials Letters, Год журнала: 2024, Номер 7(1), С. 319 - 332

Опубликована: Дек. 20, 2024

Thermodynamic metastable nanomaterials display attractive properties due to their unique atom configuration and microstructure, distinct from counterparts found in equilibrium phase diagrams. However, fabrication remains a grand challenge because conventional methods are generally operated under near-equilibrium conditions. To break the thermodynamic limits for discovering novel materials, numerous by adopting extreme strategies have been developed, including ultrafast synthesis, Joule heating, carbon thermal shock, pulse temperature gradients, rapid solidification. A common feature of these is that target material processed far-from-equilibrium (FFE) state, where new kinetic route created evolution an unprecedented composition/structure. In this review, we provide unifying view guiding engineering FFE environments during materials categorized within both temporal spatial dimensions landscape. Furthermore, highlight potential not only as platforms deeper understanding nonequilibrium behaviors, but also framework designing innovative advanced technologies.

Язык: Английский

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Transforming energy storage with unitized regenerative fuel cells: Challenges and future potential

Journal of Energy Storage, Год журнала: 2025, Номер 114, С. 115773 - 115773

Опубликована: Фев. 13, 2025

Язык: Английский

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Hybrid effect of Sm and B4C on grain size stability and hardness of nanocrystalline CoCrFeNi high entropy alloy after isothermal annealing

Journal of Alloys and Compounds, Год журнала: 2025, Номер unknown, С. 179807 - 179807

Опубликована: Март 1, 2025

Язык: Английский

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Remarkable thermal stability of nanocrystalline CoCrFeNi high entropy alloy achieved through the incorporation of rare-earth element samarium

Intermetallics, Год журнала: 2024, Номер 178, С. 108608 - 108608

Опубликована: Дек. 21, 2024

Язык: Английский

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Poly(ionic liquid) Nanocone Arrays as Light-Harvesting Antenna Enables Hot-Electron Mediated Chemistry under Natural Sunlight

ACS Applied Polymer Materials, Год журнала: 2025, Номер unknown

Опубликована: Янв. 27, 2025

Язык: Английский

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Photothermal high-entropy materials: A review

Sustainable materials and technologies, Год журнала: 2025, Номер unknown, С. e01316 - e01316

Опубликована: Фев. 1, 2025

Язык: Английский

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Enhancement of electrocatalytic efficiency by rapid bubble detachment at electrodeposited feather-like FeCoNiCuMn high-entropy alloy porous structure

International Journal of Hydrogen Energy, Год журнала: 2025, Номер 113, С. 385 - 394

Опубликована: Март 1, 2025

Язык: Английский

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Lattice Distortion and Synergistic Crystal Field: A Path to Broad-Spectrum Absorption in High-Entropy Sulfides for Solar Water Evaporation

Nano Energy, Год журнала: 2025, Номер unknown, С. 110902 - 110902

Опубликована: Март 1, 2025

Язык: Английский

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A lanthanide MOF with nanostructured node disorder

Nature Communications, Год журнала: 2025, Номер 16(1)

Опубликована: Апрель 3, 2025

Язык: Английский

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Achieving mechanical-magnetic (FeCoNi)86Al4Cu3Ti7 HEAs

Materials Research Bulletin, Год журнала: 2025, Номер unknown, С. 113476 - 113476

Опубликована: Апрель 1, 2025

Язык: Английский

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