Journal of Drug Delivery Science and Technology, Год журнала: 2023, Номер 90, С. 105123 - 105123
Опубликована: Ноя. 7, 2023
Язык: Английский
Coordination Chemistry Reviews, Год журнала: 2024, Номер 519, С. 216090 - 216090
Опубликована: Июль 30, 2024
Язык: Английский
Процитировано
32
Heliyon, Год журнала: 2023, Номер 10(1), С. e23840 - e23840
Опубликована: Дек. 16, 2023
Metal-organic frameworks (MOFs) are promising materials offering exceptional performance across a myriad of applications, attributable to their remarkable physicochemical properties such as regular porosity, crystalline structure, and tailored functional groups. Despite potential, there is lack dedicated reviews that focus on key characterizations MOFs for the beginners new researchers in field. This review written based our expertise synthesis characterization MOFs, specifically provide right direction researcher who beginner this area. In way, experimental errors can be reduced, wastage time chemicals avoided when conduct study. article, topic critically analyzed, findings conclusions presented. We reviewed three well-known XRD techniques, including PXRD, single crystal XRD, SAXS, which were used analysis depending size quality morphology. The TGA profile was an effective factor evaluating activation process ensuring successful investigation other characterizations. BET pore significantly affected by selective benzene chain cross-linkers. FTIR prominent method investigate groups surfaces, successfully evaluate process, characterize functionalized estimate applications. most significant methods include X-ray diffraction, utilized structural identification, thermogravimetric (TGA), exploring thermal decomposition. It important note stability influenced two main factors: metal-ligand interaction type attached organic ligand. textural hand, scrutinized through nitrogen adsorption-desorption isotherms experiments at 77 K. However, smaller size, Argon isotherm 87.3 K preferred. Furthermore, CO2 adsorption 273 measure ultra-micropore sizes lower than these, cannot measured using N2 highest observed high-valence constructed metal-oxo cluster, has excellent ability control properties. found procedure (including choice solvent, cross-linker, secondary metal, surface groups, temperature), method, pressure impact area MOF and, extension, its integrity. Additionally, Fourier-transform infrared spectroscopy plays crucial role identifying active Understanding these utilizing relevant techniques will enable more precise selection specific
Язык: Английский
Процитировано
32
Molecular Catalysis, Год журнала: 2024, Номер 560, С. 114127 - 114127
Опубликована: Апрель 11, 2024
Язык: Английский
Процитировано
10
Coordination Chemistry Reviews, Год журнала: 2024, Номер 523, С. 216229 - 216229
Опубликована: Окт. 11, 2024
Язык: Английский
Процитировано
8
Journal of Material Science and Technology, Год журнала: 2025, Номер unknown
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1
Coatings, Год журнала: 2024, Номер 14(3), С. 366 - 366
Опубликована: Март 20, 2024
Fossil fuels play a powerful role in the global economy and are therefore referred to as strategic raw materials. However, their massive use around world is associated with concerns about sufficiency of energy sources for future generations. Currently, fossil fuel resources heavily depleted, limited supplies. According forecasts, demand will constantly increase, so it necessary find solution that reconciles ever-increasing need protect environment. The main this problem acquire from renewable resources, especially direction obtaining alternative substitutes transportation fuels. One can replace existing hydrogen. An efficient way obtain compound through modern photocatalysts. Hence, purpose paper review recent literature on effective catalysts photocatalytic processes (e.g., glycerol conversion) enable synthesis
Язык: Английский
Процитировано
7
Energy & Fuels, Год журнала: 2024, Номер 38(10), С. 8481 - 8515
Опубликована: Апрель 24, 2024
CO2 is an important component of the atmosphere that helps in balancing Earth's atmospheric temperature and channelizes food cycles. However, increase or decrease concentration will severely affect climate. Particularly, rise levels has immensely contributed to global warming, resulting elevated temperature, altered precipitation patterns, glacier melting, subsequent rises sea levels, impacting human well-being. In response, researchers are exploring strategies capture convert into valuable products, such as methanol, formic acid, organic compounds. synthesis compounds using CO2, like benzimidazole quinazolines, a high impact. Benzimidazole, widely used medicinal chemistry for treating cancer stomach ulcers, also exhibits antiviral antifungal properties. Quinazoline derivatives, essential drugs prazosin doxazosin, have applications post-traumatic stress disorder Alzheimer's disease. These were synthesized mainly environmentally harmful synthons phosgene potassium cyanide. To address both environmental health concerns, delving chemical fixation sustainable green production. Catalysis emerges key principle chemistry, with catalysts reducing activation energy facilitating processes. This review discusses recent state art on development various conversion quinazoline benzimidazole, through homogeneous heterogeneous catalysts. Notably, while lack industrial recyclability, show promise large-scale implementation. comprehensive mechanistic aspects DFT studies understanding better. Toward end, it gives future scope this subject.
Язык: Английский
Процитировано
4
Journal of Alloys and Compounds, Год журнала: 2024, Номер 995, С. 174622 - 174622
Опубликована: Май 3, 2024
Язык: Английский
Процитировано
4
Surfaces and Interfaces, Год журнала: 2025, Номер 58, С. 105833 - 105833
Опубликована: Янв. 15, 2025
Язык: Английский
Процитировано
0
Journal of Energy Storage, Год журнала: 2025, Номер 114, С. 115746 - 115746
Опубликована: Фев. 10, 2025
Язык: Английский
Процитировано
0