Perovskite-based p-n type heterojunction Decorated with Reduced Graphene Oxide for Improved Liquified Petroleum Gas Sensing
Journal of Alloys and Compounds,
Год журнала:
2025,
Номер
unknown, С. 178905 - 178905
Опубликована: Янв. 1, 2025
Язык: Английский
Engineering an Ultrafast Ambient NO2 Gas Sensor Using Cotton-Modified LaFeO3/MXene Composites
ACS Sensors,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 3, 2024
This
work
presents
a
room-temperature
(RT)
NO2
gas
sensor
based
on
cotton-modified
LaFeO3
(CLFO)
combined
with
MXene.
(LFO),
CLFO,
and
CLFO/MXene
composites
were
synthesized
via
hydrothermal
method.
The
fabricated
sensor,
utilizing
MXene/CLFO,
exhibits
p-type
behavior
fully
recoverable
sensing
capabilities
for
low
concentrations
of
NO2,
achieving
higher
response
14.2
times
at
5
ppm.
demonstrates
excellent
performance
time
2.7
s
recovery
6.2
s,
along
notable
stability.
sensor's
sensitivity
is
attributed
to
interactions
the
material's
surface,
adsorption
energy,
charge-transfer
mechanisms.
Techniques
such
as
in
situ
FTIR
(Fourier
transform
infrared)
spectroscopy,
GC–MS
(gas
chromatography–mass
spectroscopy),
near-ambient
pressure
X-ray
photoelectron
spectroscopy
employed
verify
their
byproducts.
Additionally,
finite-difference
time-domain
simulations
used
model
electromagnetic
field
distribution
provide
insight
into
interaction
between
molecules
surface
nanoscale.
A
prototype
wireless
IoT
(Internet
Things)-based
leakage
detection
system
was
also
developed,
showcasing
practical
application.
study
offers
valuable
development
sensors
limit.
Язык: Английский
Vitalizing Perovskite Oxide-Based Acetone Sensors with Metal–Organic Framework-Derived Heterogeneous Oxide Catalysts
ACS Sensors,
Год журнала:
2024,
Номер
9(12), С. 6492 - 6501
Опубликована: Ноя. 1, 2024
Perovskite
oxides
are
promising
candidates
for
chemiresistive-type
gas
sensors
owing
to
their
exceptional
thermal
and
chemical
stability
during
solid–gas
reactions.
However,
perovskites
suffer
from
critical
issues
such
as
low
surface
area
poor
activity,
which
negatively
influence
the
sensing
characteristics.
While
metal
nanoparticles
can
be
incorporated
in
improve
reactivity,
fundamental
incompatibility
between
catalytic
metals
perovskite
often
leads
substantial
structural
degradation
well
phase
instability.
Herein,
we
overcome
this
challenge
through
introduction
of
an
intermediary
that
forms
coherent
interfaces
with
both
catalyst
metals.
Specifically,
present
case
study
p-type
La0.8Ca0.2Fe0.98Pt0.02O3
perovskite,
whose
hole
accumulation
layer
was
modulated
by
incorporation
metal–organic
framework
(MOF)-derived
n-type
α-Fe2O3
decorated
highly
dispersed
Pt
catalysts.
The
resulting
composite
exhibited
significantly
improved
activity
over
nonmodified
La0.8Ca0.2FeO3
leading
chemiresistive
performance
toward
acetone
(Rg/Ra
=
39.8
10
ppm
at
250
°C)
high
cross-sensitivity
against
interfering
gases.
Importantly,
our
findings
reaffirm
interfacial
engineering
facilitating
reactions
on
and,
doing
so,
effectively
provide
a
general
synthetic
guideline
design
perovskite-based
chemiresistors.
Язык: Английский
Reduced graphene oxide/urea-modified LaFeO₃ composite films for humidity sensing/supercapacitor applications
Materials Chemistry and Physics,
Год журнала:
2025,
Номер
unknown, С. 130456 - 130456
Опубликована: Янв. 1, 2025
Язык: Английский
Sucrose auto-combustion synthesis of Al3+ and Cr3+ substituted LaFeO3 ceramic perovskite: Structural, magnetic, and electrical characterizations
Results in Chemistry,
Год журнала:
2025,
Номер
unknown, С. 102126 - 102126
Опубликована: Фев. 1, 2025
Язык: Английский
Recent Advances on the Gas-Sensing Properties and Mechanism of Perovskite Oxide Materials - A Review
ACS Omega,
Год журнала:
2025,
Номер
10(14), С. 13780 - 13796
Опубликована: Апрель 1, 2025
Perovskite
oxide-based
materials
(ABO3)
have
gained
much
attention
as
promising
candidates
for
advanced
gas-sensing
applications
due
to
their
versatile
structures,
tunable
properties,
and
excellent
stability.
This
review
discusses
recent
developments
in
the
synthesis,
structural
optimization,
functionalization
of
perovskites
enhance
performance.
Strategies
such
doping,
creating
oxygen
vacancies,
tuning
morphology,
forming
heterojunctions
significantly
improved
sensitivity,
selectivity,
response,
recovery
times.
Specific
advances
include
incorporation
nanostructures,
porous
morphologies,
catalytic
elements,
which
optimized
adsorption
desorption
processes
various
target
gases,
including
volatile
organic
compounds,
NO2,
CO2.
Mechanistic
insights
into
role
surface
defects,
charge
carrier
dynamics
are
also
addressed.
These
position
perovskite
important
components
next-generation
gas
sensors
environmental
monitoring
industrial
applications.
Язык: Английский
Design and development of a novel device to identify the individual concentration of NO and NO2 in a gas mixture
Md Abu Sayeed Sujan,
Suman Chatterjee
Review of Scientific Instruments,
Год журнала:
2025,
Номер
96(4)
Опубликована: Апрель 1, 2025
This
study
investigates
the
performance
of
advanced
potentiometric
sensors
utilizing
yttria-stabilized
zirconia
(YSZ)
substrates
coated
with
lanthanum
copper
oxide
(La2CuO4)
or
tungsten
(WO3)
for
selective
detection
nitrogen
oxides
(NO
and
NO2).
The
were
systematically
evaluated
at
operating
temperatures
550,
600,
650
°C.
results
indicate
that
sensitivity
to
NO2
significantly
increases
higher
temperatures,
while
response
NO
is
more
pronounced
lower
temperatures.
behavior
attributed
catalytic
conversion
vice
versa,
enhanced
by
a
porous
platinum
(Pt)
layer
applied
sensing
elements.
A
robust
linear
relationship
between
generated
potential
gas
concentrations
was
established,
allowing
accurate
estimation
unknown
in
mixed
environments.
In
addition,
highlights
importance
temperature
optimizing
sensor
demonstrates
application
these
environmental
monitoring
regulatory
compliance.
findings
contribute
insights
into
designing
efficient
technologies
aimed
improving
air
quality
management
strategies
globally.
Язык: Английский
Enhanced n-butanol sensing performance of Co3O4/LaFeO3 nanocomposites
Materials Letters,
Год журнала:
2024,
Номер
unknown, С. 137574 - 137574
Опубликована: Окт. 1, 2024
Язык: Английский
Recent Advances in Perovskite Nanomaterials for Sensing Applications
Journal of The Electrochemical Society,
Год журнала:
2024,
Номер
171(11), С. 117529 - 117529
Опубликована: Ноя. 1, 2024
Perovskite-structured
materials
have
been
extensively
studied
for
sensing
applications
on
account
of
their
good
thermal
stability
and
3–4
eV
bandgap.
They
utilized
to
detect
traces
O
2
,
NO,
CO,
NO
CO
H
O,
CH
4
similar
smaller
gas
molecules
such
as
C
5
OH
etc.
In
addition,
other
are
optical
sensing,
I-V
fluctuations,
strain
sensors,
electromechanical
metal
ions,
halides
reported
toxic
gases,
Volatile
Organic
Compounds
(VOCs),
detection
fungicides,
pesticides,
explosives,
cellular
imaging,
radiation
humidity
temperature
sensing.
Язык: Английский