Electroreduction of CO2 to Methanol Using a Coordination-Moiety-Anchored Carbon-Based Electrode DOI

Ann Mariella Babu,

Anitha Varghese

Langmuir, Год журнала: 2025, Номер unknown

Опубликована: Май 22, 2025

Electrochemical reduction of carbon dioxide (CO2ER) has gained wide attention lately because its potential to create a closed loop, offering sustainable solution toward environmental as well energy crisis. However, the key challenge lies in selective conversion CO2 into electrofuels, such methanol, which necessitates six proton-coupled electron transfers. In this work, we report first instance an electrochemically prepared Cu-coordinated 2,5-dimercapto-1,3,4-thiadiazole-modified fiber paper electrode (CDM@CFP). The hence-engineered novel was applied for CO2ER reaction produce methanol exclusively with F.E. 59.6% at low -0.73 V versus RHE. Unlike most copper-based electrocatalysts, result multiple hydrocarbons, here, have optimized potential-dependent selectivity maximum efficiency, is significant milestone field.

Язык: Английский

Electrochemical biosensing methods for analysis of trace biomarkers: a review DOI
Baorong Zhang, Zhuomin Zhang, Gongke Li

и другие.

Critical Reviews in Analytical Chemistry, Год журнала: 2025, Номер unknown, С. 1 - 18

Опубликована: Апрель 7, 2025

Electrochemical biosensing methods have many advantages such as high sensitivity, portable instruments, fast response, low cost, etc. In recent years, electrochemical been widely used for the analysis of biomarkers and demonstrated rapid progress. This review systematically covers progress in trace biomarker analysis, with a primary focus on developments over past decade. The article discusses advancements probe preparation using metal coordination materials, nanomaterials, organic redox polymer nanocomposites, highlights construction DNA strategy, aptamer immune-biosensing strategy. Typical applications ions, virus biomarkers, short non-protein coding RNAs are further summarized. Challenges future perspectives also discussed to guide research bioanalysis electrochemistry.

Язык: Английский

Процитировано

0
Wearable devices for monitoring sweat glucose: an integrated strategy for efficient electrochemical sensors DOI Creative Commons
Ruiyu Luo, Yi Yang, Senlin Huang

и другие.

Sensors and Actuators Reports, Год журнала: 2025, Номер unknown, С. 100339 - 100339

Опубликована: Май 1, 2025

Язык: Английский

Процитировано

0
Electroreduction of CO2 to Methanol Using a Coordination-Moiety-Anchored Carbon-Based Electrode DOI

Ann Mariella Babu,

Anitha Varghese

Langmuir, Год журнала: 2025, Номер unknown

Опубликована: Май 22, 2025

Electrochemical reduction of carbon dioxide (CO2ER) has gained wide attention lately because its potential to create a closed loop, offering sustainable solution toward environmental as well energy crisis. However, the key challenge lies in selective conversion CO2 into electrofuels, such methanol, which necessitates six proton-coupled electron transfers. In this work, we report first instance an electrochemically prepared Cu-coordinated 2,5-dimercapto-1,3,4-thiadiazole-modified fiber paper electrode (CDM@CFP). The hence-engineered novel was applied for CO2ER reaction produce methanol exclusively with F.E. 59.6% at low -0.73 V versus RHE. Unlike most copper-based electrocatalysts, result multiple hydrocarbons, here, have optimized potential-dependent selectivity maximum efficiency, is significant milestone field.

Язык: Английский

Процитировано

0