Nanoscale, Год журнала: 2023, Номер 16(2), С. 691 - 700
Опубликована: Дек. 6, 2023
2D MOF nanosheets prepared using a high-gravity reactive precipitation method exhibit high catalytic activities toward Knoevenagel condensation and the glycolysis of poly(ethylene terephthalate).
Язык: Английский
RSC Sustainability, Год журнала: 2023, Номер 1(9), С. 2135 - 2147
Опубликована: Янв. 1, 2023
This review has focused on the concept of upcycling, which involves utilizing PET waste as a raw material for production value-added products such monomers, fine chemicals, hydrogen, or carbon materials.
Язык: Английский
Процитировано
27
Polymer Chemistry, Год журнала: 2024, Номер 15(7), С. 585 - 608
Опубликована: Янв. 1, 2024
This review discusses the physical-, chemical recycling and biodegradation processes mechanisms of PET, proposing effecting compromise between its overall properties conferred intrinsic biodegradability by modified monomer polymerisation.
Язык: Английский
Процитировано
10
Green Chemistry, Год журнала: 2023, Номер 25(18), С. 7243 - 7252
Опубликована: Янв. 1, 2023
The Ti 0.5 Si O 2 solid acid catalyst is extremely active and stable for methanol alcoholysis of polyethylene terephthalate to dimethyl under mild conditions.
Язык: Английский
Процитировано
19
Green Chemistry, Год журнала: 2023, Номер 25(20), С. 8160 - 8171
Опубликована: Янв. 1, 2023
Polyethylene terephthalate (PET) can be recovered as high-purity bis(2-hydroxyethyl terephthalate) (BHET) monomer by glycolysis in the presence of Fe 3 O 4 nanoparticles (NPs). After removing metallic impurities, BHET used to producing r -PET.
Язык: Английский
Процитировано
19
ACS Applied Polymer Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 29, 2025
Язык: Английский
Процитировано
1
ACS Sustainable Chemistry & Engineering, Год журнала: 2023, Номер 11(43), С. 15544 - 15555
Опубликована: Окт. 18, 2023
The development of efficient catalysts for the chemical recycling poly(ethylene terephthalate) (PET) is essential to tackling global issue plastic waste. There has been intense interest in heterogeneous as a sustainable catalyst system PET depolymerization, having advantage easy separation and reuse after reaction. In this work, we explore design by comparing metal-ion (Fe3+) metal-oxide nanoparticle (Fe2O3 NP) immobilized on mesoporous silica (SiO2) functionalized with different N-containing amine ligands. Quantitative solid-state nuclear magnetic resonance (NMR) spectroscopy confirms successful grafting elucidates bonding mode organic ligands SiO2 surface. surface act organocatalysts, enhancing catalytic activity active metal species. Fe2O3 NP presence outperform bare NPs, Fe3+-ion-immobilized homogeneous FeCl3 salts, equivalent Fe loading. X-ray photoelectron analysis indicates charge transfer between NPs electron-donating ability N groups hydrogen may also play role higher performance amine-ligand-assisted catalysts. Density functional theory (DFT) calculations reveal that reactivity ion-immobilized strongly correlated ligand–metal binding energy products glycolysis reaction catalyzed are stabilized, showing significant exergonic character compared single Fe3+ ions.
Язык: Английский
Процитировано
14
Catalysis Science & Technology, Год журнала: 2023, Номер 13(22), С. 6561 - 6569
Опубликована: Янв. 1, 2023
The glycolysis of polyethylene terephthalate (PET) is considered as the most promising PET recycling strategy due to its mild reaction conditions and circularity.
Язык: Английский
Процитировано
14
European Polymer Journal, Год журнала: 2023, Номер 201, С. 112578 - 112578
Опубликована: Ноя. 7, 2023
Язык: Английский
Процитировано
14
Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 157249 - 157249
Опубликована: Окт. 1, 2024
Язык: Английский
Процитировано
5
Waste Management, Год журнала: 2023, Номер 170, С. 308 - 316
Опубликована: Сен. 20, 2023
Язык: Английский
Процитировано
10