Formation of Ni‐MOF Derived Nickel Sulfides as Efficient Electrocatalysts for Oxygen Evolution Reaction Through Optimizing the Sulfur Sources Selection DOI
Fang Wu, Yuhong Jiao, Jinlong Ge

и другие.

ChemistrySelect, Год журнала: 2024, Номер 9(37)

Опубликована: Окт. 2, 2024

Abstract Developing low‐cost and exceedingly efficient electrocatalysts for oxygen evolution reaction (OER) is vital application of hydrogen production from water splitting. Herein, three different nickel sulfides on foam were fabricated via a simple sulfuring the as‐formed Ni‐MOF with sulfide as sulfur source. The effect source OER performance, morphology structure as‐prepared product are well discussed. optimized Ni‐MOF/NF‐SS deliver overpotentials 253 330 mV to reach current densities 10 100 mA cm −2 small Tafel slope 70.9 mVdec −1 , stability over 50 h. This work provides insights into relationship between activity structures sulfides, but also affords new route fabricate sulfides‐based OER.

Язык: Английский

Iron phthalocyanine coupled with Co-Nx sites in carbon nanostraws for Zn-Air batteries DOI
Yi Wu, Junliang Chen, Jie Liu

и другие.

Chemical Engineering Journal, Год журнала: 2024, Номер 503, С. 158343 - 158343

Опубликована: Дек. 9, 2024

Язык: Английский

Процитировано

10
Tailoring the d-band electronic structure of FePc by direct oxygen bridge on ZIF-8 derived ultrathin carbon shell to improve the oxygen reduction performance DOI Creative Commons
Xilin Zhang, Shun Wang,

Zhiyi Sun

и другие.

Nano Research, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

1
Enhancing Optoelectronic Properties in Phthalocyanine‐Based SURMOFs: Synthesis of ABAB Linkers by Avoiding Statistical Condensation with Tailored Building Blocks DOI Creative Commons

Lukas Langer,

Mareen Stahlberger, Xiaojing Liu

и другие.

Advanced Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 25, 2025

Abstract Phthalocyanine (PC)‐based metal–organic frameworks (MOFs) hold substantial promise for applications in energy storage, sensing, and catalysis due to their robust stability enhanced electron transfer capabilities. However, synthesizing phthalocyanine linkers with precise geometries presents a significant challenge, which limits prevalence the field. Traditional methods typically employ readily synthesized tetratopic PC realizing PC‐based MOFs. In response, study an innovative approach using ditopic ABAB‐phthalocyanine MOF linkers. The A B building blocks synthesis are deliberately designed circumvent issues of statistical condensation. These then utilized fabrication zinc‐based surface‐anchored (SURMOF) thin films. structural electronic properties these SURMOFs explored through series detailed experimental computational methods, including X‐ray diffraction, scanning microscopy (SEM), density functional theory (DFT) calculations. UV–Vis spectroscopy reveals improvements absorption, thereby enhancing material's performance light harvesting conversion. Furthermore, photodetector built this novel linker demonstrates high efficacy long‐wavelength region (780 nm), highlighting its potential cutting‐edge sensing technologies.

Язык: Английский

Процитировано

0
Molecular iron phthalocyanines anchoring onto ZIF-67-derived cobalt-carbon nanomaterials as bifunctional oxygen catalysts DOI

Xiaoyu Lin,

Danna Lin,

Weiwu Zhang

и другие.

Frontiers in Energy, Год журнала: 2025, Номер unknown

Опубликована: Март 30, 2025

Язык: Английский

Процитировано

0
Topology Engineering Promoting Electron Transfer in Phthalocyanine-Based Polymer Electrocatalysts for Oxygen Reduction DOI

Qiming Ye,

Yu Han, Shaoze Wang

и другие.

ACS Applied Polymer Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 23, 2025

Язык: Английский

Процитировано

0
Enhancing electrocatalytic N2 reduction to NH3 by introducing Ni heteroatoms into NiCuOx electrocatalyst DOI
Xinxin Han,

Weizhen Zhou,

Xin Huang

и другие.

Catalysis Science & Technology, Год журнала: 2024, Номер 14(13), С. 3691 - 3698

Опубликована: Янв. 1, 2024

The Ni dopant enhances the local electronic density surrounding Cu sites, which is favorable for reducing energy barrier of rate-determining (*N 2 to *NNH) step NRR as well depressing competing HER.

Язык: Английский

Процитировано

2
Built-In Positive Valence Space Shifting the Chemical Equilibrium Forward for Nitrate Reduction to Ammonia DOI
Yuzhuo Jiang, Sisi Liu,

Qiyang Cheng

и другие.

Inorganic Chemistry, Год журнала: 2024, Номер 63(26), С. 12146 - 12155

Опубликована: Июнь 19, 2024

The electrochemical conversion of nitrate pollutants into value-added ammonia (NH

Язык: Английский

Процитировано

2
Hierarchical Nitrogen-Doped Carbon: A Versatile Catalyst for Oxygen Reduction and Evolution Reactions DOI Creative Commons
Anand Parkash,

Adeel Mukhtar Arain,

Masroor Abro

и другие.

ECS Journal of Solid State Science and Technology, Год журнала: 2024, Номер 13(8), С. 081003 - 081003

Опубликована: Авг. 1, 2024

This study presents the synthesis and characterization of hierarchical nitrogen-doped carbon (HCN-900), demonstrating remarkable electrocatalytic performance for both oxygen reduction reaction (ORR) evolution (OER), outperforming traditional catalysts like RuO₂ Pt/C. HCN-900 exhibits an onset potential 0.98 V a half-wave 0.85 ORR, closely matching Pt/C while achieving electron transfer number 4.0, indicative four-electron pathway. For OER, achieves current density 10 mA cm⁻ 2 at overpotential 223 mV, significantly lower than (288 mV) (363 mV). The material also shows Tafel slope 87 mV dec⁻¹, indicating rapid kinetics efficient transfer. impressive is attributed to optimized structural electronic properties HCN-900, including its high surface area, porosity, nitrogen doping, which enhance active site promote transport. Furthermore, retains approximately 96.72% initial after h continuous operation, excellent long-term stability. comprehensive analysis highlights as promising bifunctional catalyst advanced energy applications, providing cost-effective sustainable alternative conventional catalysts. Its superior make candidate integration into next-generation conversion storage systems.

Язык: Английский

Процитировано

0
Tailoring Iron hexadecafluorophthalocyanine/GO nanocomposite separators for polysulfide adsorption and enabling fast electrochemical kinetics of Li-S batteries DOI
Zhanwei Xu, Liang Li, Siyu Chen

и другие.

Journal of Alloys and Compounds, Год журнала: 2024, Номер unknown, С. 176687 - 176687

Опубликована: Сен. 1, 2024

Язык: Английский

Процитировано

0
Formation of Ni‐MOF Derived Nickel Sulfides as Efficient Electrocatalysts for Oxygen Evolution Reaction Through Optimizing the Sulfur Sources Selection DOI
Fang Wu, Yuhong Jiao, Jinlong Ge

и другие.

ChemistrySelect, Год журнала: 2024, Номер 9(37)

Опубликована: Окт. 2, 2024

Abstract Developing low‐cost and exceedingly efficient electrocatalysts for oxygen evolution reaction (OER) is vital application of hydrogen production from water splitting. Herein, three different nickel sulfides on foam were fabricated via a simple sulfuring the as‐formed Ni‐MOF with sulfide as sulfur source. The effect source OER performance, morphology structure as‐prepared product are well discussed. optimized Ni‐MOF/NF‐SS deliver overpotentials 253 330 mV to reach current densities 10 100 mA cm −2 small Tafel slope 70.9 mVdec −1 , stability over 50 h. This work provides insights into relationship between activity structures sulfides, but also affords new route fabricate sulfides‐based OER.

Язык: Английский

Процитировано

0