A DMSO-assisted iridium(iii) complex as a luminescent “turn-on” sensor for selective detection of l-histidine and bacterial imaging DOI
Xiaojuan Li,

Tianqian Jia,

Yueyan Wang

и другие.

Analytical Methods, Год журнала: 2024, Номер 16(40), С. 6839 - 6844

Опубликована: Янв. 1, 2024

Histidine (His) is a semi-essential amino acid and unique key neurotransmitter involved in numerous physiological processes. An excessive or deficient amount of His the body can lead to various related diseases. However, since chemical structures L-His its metabolites (such as histamine (Ha), imidazole-4-acetate (ImA), etc.) are very similar, simple efficient selective detection great importance but remains challenge. Herein, we successfully designed synthesized DMSO-assisted iridium(III) complex (Ir1-DMSO), which be applied "turn-on" photoluminescence (PL) probe for quantification L-His/Ha. More importantly, Ir1-DMSO exhibited good sensitivity, high selectivity, anti-interference capability L-His/Ha/His-containing proteins, advantageous due fabrication low technical demands. This was attributed reaction with imidazole groups Furthermore, show utility PL imaging agent cultures E. coli S. aureus. Considering diversity composition structural flexibility, it extended other solvents Ir-ligand complexes analyses based on specific molecular recognition sensing platforms.

Язык: Английский

Applications of Aggregation-Induced Emission Materials in Immunology: From Diagnostics to Immunotherapy DOI Creative Commons

Langyi Yang,

Ling‐Hong Xiong, Xuewen He

и другие.

Chemical & Biomedical Imaging, Год журнала: 2025, Номер unknown

Опубликована: Апрель 1, 2025

Aggregation-induced emission (AIE) materials, due to their unique ability significantly enhance optical in aggregated states, have demonstrated vast potential immunology, particularly early disease diagnosis and immunotherapy. AIE materials can serve as highly efficient fluorescent probes for biomarker detection, providing critical insights diagnosis. Additionally, they act cancer vaccines, enhancing the effectiveness of immunotherapy through photodynamic therapy, photothermal or activation immune cells. This review highlights applications focusing on recent advancements diagnostics while also discussing challenges face directions future development.

Язык: Английский

Процитировано

0

808 nm Light-Triggered Cyanine-Decorated Iridium(III) Complexes for Antibacterial Photodynamic Therapy in Deep-Tissue DOI

Baraka Joseph Butuyuyu,

Jiqiang Liu, Qihang Ding

и другие.

Inorganic Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Апрель 11, 2025

Acute bacterial skin and structure infections (ABSSSIs) pose significant global health challenges, exacerbated by rising antibiotic resistance. Antibacterial photodynamic therapy (APDT) has emerged as a promising strategy to combat these utilizing photosensitizer (PS) that generates reactive oxygen species (ROS) upon light activation. However, the limited tissue penetration of conventional organic PSs, which primarily absorb in UV-vis spectra, hindered their therapeutic potential for deeper infections. Herein, we introduce novel iridium(III)-cyanine complex (Ir-cy) with strong near-infrared (NIR) absorption at 814 nm (up 101 red-shifted from previous reports), specifically designed enhance APDT. Under 808 laser irradiation, Ir-cy demonstrated substantial ROS generation capacity, achieving approximately 70% reduction Staphylococcus aureus (S. aureus) colonies depth 7.2 mm within simulated model. Comprehensive vitro vivo evaluations further confirmed its potent antibacterial efficacy against S. while maintaining excellent biocompatibility. These findings highlight highly effective NIR-active PS, paving way advanced strategies targeting deep-tissue ABSSSIs through optimized

Язык: Английский

Процитировано

0

A Biocompatible Phosphorescence Probe Based on Iridium(III) Solvent Complex for Monitoring Integrin Expression in Living Cells DOI

Yaoyao Gao,

Meng Li, Xiaofei Wang

и другие.

Talanta, Год журнала: 2025, Номер 293, С. 128158 - 128158

Опубликована: Апрель 15, 2025

Язык: Английский

Процитировано

0

Screening Anti-Parkinson’s Disease Drugs in Living Mouse Brains via a Peroxynitrite-Activated Fluorescent Probe DOI Creative Commons
Jiao Wu, Xiaoyu Wang, Jingwen Zou

и другие.

Chemical & Biomedical Imaging, Год журнала: 2024, Номер unknown

Опубликована: Дек. 20, 2024

Screening anti-Parkinson's disease (PD) drugs at in vivo brain level is imperative for managing PD yet currently remains unaccomplished. Peroxynitrite (ONOO–) has been implicated progression. Thus, developing ONOO–-based imaging tools anti-PD drug screening holds promise early prognosis and treatment of PD. Consequently, a near-infrared (NIR) fluorescence probe, BOB-Cl-PN, with high specificity, good sensitivity (LOD = 24 nM), rapid response (<60 s), was devised to investigate ONOO– relationships. Utilizing NIR imaging, BOB-Cl-PN effectively monitored fluctuations 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP)-induced cell models, establishing cellular throughput (cHTS) system drugs. In live animal BOB-Cl-PN's ability penetrate the blood–brain barrier enabled flux mouse brains. Moreover, served as an contrast potential traditional Chinese medicines therapy, identifying fisetin having best therapeutic index among 10 medicines. This study constructs sensitive, efficient monitoring dynamics brains provides valuable platform

Язык: Английский

Процитировано

1

A DMSO-assisted iridium(iii) complex as a luminescent “turn-on” sensor for selective detection of l-histidine and bacterial imaging DOI
Xiaojuan Li,

Tianqian Jia,

Yueyan Wang

и другие.

Analytical Methods, Год журнала: 2024, Номер 16(40), С. 6839 - 6844

Опубликована: Янв. 1, 2024

Histidine (His) is a semi-essential amino acid and unique key neurotransmitter involved in numerous physiological processes. An excessive or deficient amount of His the body can lead to various related diseases. However, since chemical structures L-His its metabolites (such as histamine (Ha), imidazole-4-acetate (ImA), etc.) are very similar, simple efficient selective detection great importance but remains challenge. Herein, we successfully designed synthesized DMSO-assisted iridium(III) complex (Ir1-DMSO), which be applied "turn-on" photoluminescence (PL) probe for quantification L-His/Ha. More importantly, Ir1-DMSO exhibited good sensitivity, high selectivity, anti-interference capability L-His/Ha/His-containing proteins, advantageous due fabrication low technical demands. This was attributed reaction with imidazole groups Furthermore, show utility PL imaging agent cultures E. coli S. aureus. Considering diversity composition structural flexibility, it extended other solvents Ir-ligand complexes analyses based on specific molecular recognition sensing platforms.

Язык: Английский

Процитировано

0