Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

Chemical Reviews, Год журнала: 2015, Номер 115(22), С. 12138 - 12204

Опубликована: Ноя. 11, 2015

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTOxidative Coupling between Two Hydrocarbons: An Update of Recent C–H FunctionalizationsChao Liu†, Jiwen Yuan†, Meng Gao‡, Shan Tang†, Wu Li†, Renyi Shi†, and Aiwen Lei*†‡View Author Information† College Chemistry Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, 430072, People's Republic China‡ National Research Center Carbohydrate Synthesis, Jiangxi Normal Nanchang, 330022, China*E-mail: [email protected]Cite this: Chem. Rev. 2015, 115, 22, 12138–12204Publication Date (Web):November 11, 2015Publication History Received7 August 2014Published online11 November 2015Published inissue 25 2015https://pubs.acs.org/doi/10.1021/cr500431shttps://doi.org/10.1021/cr500431sreview-articleACS PublicationsCopyright © 2015 American Chemical SocietyRequest reuse permissionsArticle Views24367Altmetric-Citations933LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Catalysts,Cross coupling reaction,Hydrocarbons,Organic compounds,Oxidative Get e-Alerts

Язык: Английский

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Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

Chemical Society Reviews, Год журнала: 2012, Номер 41(9), С. 3464 - 3464

Опубликована: Янв. 1, 2012

Copper salts have been developed as versatile catalysts for oxidative coupling reactions in organic synthesis. During these processes, Cu-catalysts are often proposed to serve a one-electron oxidant promote the single-electron transfer process. Recently, transition-metal catalyzed direct dehydrogenative transformation has attracted considerable attention. This tutorial review summarizes recent advances copper-catalyzed functionalization via single electron (SET) process achieving C–C, C–N, C–O, C–halogen atoms, C–P, and N–N bond formation.

Язык: Английский

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Transition-Metal-Free Coupling Reactions

Chemical Reviews, Год журнала: 2014, Номер 114(18), С. 9219 - 9280

Опубликована: Сен. 3, 2014

ADVERTISEMENT RETURN TO ISSUEPREVReviewTransition-Metal-Free Coupling ReactionsChang-Liang Sun and Zhang-Jie Shi*View Author Information Beijing National Laboratory of Molecular Sciences (BNLMS) Key Bioorganic Chemistry Engineering Ministry Education, College Green Center, Peking University, 202 Chengfu Road, 098#, 100871, China State Organometallic Chemistry, Chinese Academy Sciences, 345 Lingling Shanghai 200032, Elemento-Organic Nankai Tianjin 200060, China*E-mail: [email protected]Cite this: Chem. Rev. 2014, 114, 18, 9219–9280Publication Date (Web):September 3, 2014Publication History Received18 May 2013Published online3 September 2014Published inissue 24 2014https://pubs.acs.org/doi/10.1021/cr400274jhttps://doi.org/10.1021/cr400274jreview-articleACS PublicationsCopyright © 2014 American Chemical SocietyRequest reuse permissionsArticle Views34901Altmetric-Citations908LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Aromatic compounds,Cross coupling reaction,Hydrocarbons,Reagents,Substitution reactions Get e-Alerts

Язык: Английский

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Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

Accounts of Chemical Research, Год журнала: 2015, Номер 48(4), С. 1007 - 1020

Опубликована: Апрель 6, 2015

The possibility of developing new methods for the efficient construction organic molecules via disconnections other than traditional functional group transformations has driven interest in direct functionalization C-H bonds. ubiquity bonds makes such attractive, but they also pose several challenges. first is reactivity and selectivity To achieve this, directing groups (DGs) are often installed that can enhance effective concentration catalyst, leading to thermodynamically stable metallacyclic intermediates. However, presence a pendant product undesirable unnecessary. This may account limitation applications reactions more common general uses. Thus, development removable or functionalizable desirable. Another key problem resulting M-C bond be low, which limit scope coupling partners hence reaction patterns activation reactions. While Cp*Rh(III)-catalyzed arenes was reported only 7 years ago, significant progress been made this area past few years. We began our studies 2010, we others have demonstrated diversified catalytic realized using Cp*Rh(III) complexes with high reactivity, stability, compatibility. Account describes efforts solve some these challenges Rh(III) catalysis. fulfilled design arene substrates by taking advantage nucleophilicity, electrophilicity, oxidizing potential, properties participating ligand when coupled relatively reactive unsaturated as alkenes alkynes. These situ funtionalizable roles DG allowed extensive chemical manipulation initial product, especially diverse array heterocycles. In polar partners, Rh(III)-C(aryl) showed higher both an organometallic reagent nucleophilic aryl source. were accordingly activated virtue umpolung, ring strain, rearomatization. All possible integration compatibility Rh(III)-C into systems. date achieved under rhodium addition, means stoichiometric reactions, gained mechanistic insights interactions between Rh-C opened avenues future

Язык: Английский

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Electrochemical strategies for C–H functionalization and C–N bond formation

Chemical Society Reviews, Год журнала: 2018, Номер 47(15), С. 5786 - 5865

Опубликована: Янв. 1, 2018

This review provides an overview of the use electrochemistry as appealing platform for expediting carbon–hydrogen functionalization and carbon–nitrogen bond formation.

Язык: Английский

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