Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

Chemical Reviews, Год журнала: 2011, Номер 111(3), С. 1315 - 1345

Опубликована: Март 9, 2011

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTCarboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and ScopeLutz Ackermann*View Author Information Institut für Organische und Biomolekulare Chemie, Georg-August-Universität, Tammannstrasse 2, 37077 Göttingen, Germany*Fax: (+49)551-39-6777. E-mail: [email protected]Cite this: Chem. Rev. 2011, 111, 3, 1315–1345Publication Date (Web):March 9, 2011Publication History Received2 December 2010Published online9 March 2011Published inissue 9 2011https://pubs.acs.org/doi/10.1021/cr100412jhttps://doi.org/10.1021/cr100412jreview-articleACS PublicationsCopyright © 2011 American Chemical SocietyRequest reuse permissionsArticle Views35746Altmetric-Citations3100LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Anions,Functionalization,Hydrocarbons,Metalation,Organic reactions Get e-Alerts

Язык: Английский

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Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

Chemical Reviews, Год журнала: 2012, Номер 112(11), С. 5879 - 5918

Опубликована: Авг. 31, 2012

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTRuthenium(II)-Catalyzed C–H Bond Activation and FunctionalizationPercia Beatrice Arockiam, Christian Bruneau*, Pierre H. Dixneuf*View Author Information Laboratoire Organométalliques, Matériaux et Catalyse, Institut Sciences Chimiques, UMR 6226 CNRS−Université de Rennes1, Campus Beaulieu, 35042 Rennes, France*E-mail: [email protected]; protected]Cite this: Chem. Rev. 2012, 112, 11, 5879–5918Publication Date (Web):August 31, 2012Publication History Received14 April 2012Published online31 August inissue 14 November 2012https://pubs.acs.org/doi/10.1021/cr300153jhttps://doi.org/10.1021/cr300153jreview-articleACS PublicationsCopyright © 2012 American Chemical SocietyRequest reuse permissionsArticle Views41440Altmetric-Citations2535LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Alcohols,Aromatic compounds,Catalysts,Hydrocarbons,Organic reactions Get e-Alerts

Язык: Английский

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Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis

Chemical Reviews, Год журнала: 2016, Номер 116(6), С. 3722 - 3811

Опубликована: Март 3, 2016

The applications of copper (Cu) and Cu-based nanoparticles, which are based on the earth-abundant inexpensive metal, have generated a great deal interest in recent years, especially field catalysis. possible modification chemical physical properties these nanoparticles using different synthetic strategies conditions and/or via postsynthetic treatments has been largely responsible for rapid growth nanomaterials their In addition, design development novel support multimetallic systems (e.g., alloys, etc.) also made significant contributions to field. this comprehensive review, we report approaches Cu (metallic copper, oxides, hybrid nanostructures) immobilized into or supported various materials (SiO2, magnetic materials, etc.), along with synthesis part discusses numerous preparative protocols whereas application sections describe utility as catalysts, including electrocatalysis, photocatalysis, gas-phase We believe critical appraisal will provide necessary background information further advance nanostructured

Язык: Английский

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Towards mild metal-catalyzed C–H bond activation

Chemical Society Reviews, Год журнала: 2011, Номер 40(9), С. 4740 - 4740

Опубликована: Янв. 1, 2011

Functionalizing traditionally inert carbon–hydrogen bonds represents a powerful transformation in organic synthesis, providing new entries to valuable structural motifs and improving the overall synthetic efficiency. C–H bond activation, however, often necessitates harsh reaction conditions that result functional group incompatibilities limited substrate scope. An understanding of mechanism rational design experimental have led significant improvement both selectivity applicability. This critical review summarizes discusses endeavours towards development mild activation methods wishes trigger more research this goal. In addition, we examine select examples complex natural product synthesis demonstrate utility functionalization (84 references).

Язык: Английский

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Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

Chemical Society Reviews, Год журнала: 2011, Номер 40(10), С. 5068 - 5068

Опубликована: Янв. 1, 2011

The direct functionalization of heterocyclic compounds has emerged as one the most important topics in field metal-catalyzed C–H bond activation due to fact that products are an synthetic motif organic synthesis, pharmaceutical industry, and materials science. This critical review covers recent progresses on regioselective dehydrogenative coupling reaction heteroarenes, including arylation, olefination, alkynylation, amination/amidation mainly utilizing transition metal catalysts (113 references).

Язык: Английский

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C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

Nature Chemistry, Год журнала: 2013, Номер 5(5), С. 369 - 375

Опубликована: Апрель 23, 2013

Язык: Английский

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C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

Chemical Society Reviews, Год журнала: 2012, Номер 41(9), С. 3651 - 3651

Опубликована: Янв. 1, 2012

Rhodium(III)-catalyzed direct functionalization of C-H bonds under oxidative conditions leading to C-C, C-N, and C-O bond formation is reviewed. Various arene substrates bearing nitrogen oxygen directing groups are covered in their coupling with unsaturated partners such as alkenes alkynes. The facile construction C-E (E = C, N, S, or O) makes Rh(III) catalysis an attractive step-economic approach value-added molecules from readily available starting materials. Comparisons contrasts between rhodium(III) palladium(II)-catalyzed made. remarkable diversity structures accessible demonstrated various recent examples, a proposed mechanism for each transformation being briefly summarized (critical review, 138 references).

Язык: Английский

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3d Transition Metals for C–H Activation

Chemical Reviews, Год журнала: 2018, Номер 119(4), С. 2192 - 2452

Опубликована: Ноя. 27, 2018

C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with notable applications to material crop protection, drug discovery, and pharmaceutical industries, among others. Despite major advances, the vast majority of these functionalizations required precious 4d or 5d transition metal catalysts. Given cost-effective sustainable nature earth-abundant first row metals, development less toxic, inexpensive 3d catalysts gained considerable recent momentum a significantly more environmentally-benign economically-attractive alternative. Herein, we provide comprehensive overview on until summer 2018.

Язык: Английский

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Catalytic Functionalization of C(sp²)H and C(sp³)H Bonds by Using Bidentate Directing Groups

Angewandte Chemie International Edition, Год журнала: 2013, Номер 52(45), С. 11726 - 11743

Опубликована: Сен. 17, 2013

C-H bonds are ubiquitous in organic compounds. It would, therefore, appear that direct functionalization of substrates by activation would eliminate the multiple steps and limitations associated with preparation functionalized starting materials. Regioselectivity is an important issue because molecules can contain a wide variety bonds. The use directing group largely overcome regiocontrol allowing catalyst to come into proximity targeted A functional groups have been evaluated for as transformation In 2005, Daugulis reported arylation unactivated C(sp(3))-H using 8-aminoquinoline picolinamide bidentate groups, Pd(OAc)2 catalyst. Encouraged these promising results, number transformations since developed systems based on groups. this Review, recent advances area discussed.

Язык: Английский

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Direct C−H Transformation via Iron Catalysis

Chemical Reviews, Год журнала: 2010, Номер 111(3), С. 1293 - 1314

Опубликована: Ноя. 4, 2010

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTDirect C−H Transformation via Iron CatalysisChang-Liang Sun, Bi-Jie Li, and Zhang-Jie Shi*View Author Information Beijing National Laboratory of Molecular Sciences (BNLMS), Key Bioorganic Chemistry Engineering Ministry Education, College PKU Green Centre State Natural Biomimetic Drugs, Peking University, 100871, China*E-mail: [email protected]. Phone/fax: (+86) 10-62760890.Cite this: Chem. Rev. 2011, 111, 3, 1293–1314Publication Date (Web):November 4, 2010Publication History Received30 June 2010Published online4 November inissue 9 March 2011https://pubs.acs.org/doi/10.1021/cr100198whttps://doi.org/10.1021/cr100198wreview-articleACS PublicationsCopyright © 2010 American Chemical SocietyRequest reuse permissionsArticle Views34344Altmetric-Citations1856LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Catalysts,Cross coupling reaction,Hydrocarbons,Iron,Oxidation Get e-Alerts

Язык: Английский

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