Nano Energy, Год журнала: 2024, Номер 123, С. 109434 - 109434
Опубликована: Март 1, 2024
Язык: Английский
Advanced Functional Materials, Год журнала: 2022, Номер 33(7)
Опубликована: Дек. 5, 2022
Abstract Tuning the surface topography of solar evaporators is significance for boosting light absorption and enhancing solar‐to‐vapor efficiency. Herein, a novel strategy to manipulate graphene oxide (GO) via electrostatic assembly coupled with in situ polymerizations aniline reported. The GO fully hybridized polyaniline (PANI) nanocone arrays, manifesting periodic structures highly foldable configurations. Additionally, PANI arrays tune chemistry retard redispersion into water, thus enabling corresponding composite (PG) robust structural durability. Featuring these intriguing attributes, when applied as an evaporator pure PG delivers improved evaporation performance 1.42 kg m −2 h −1 high efficiency 96.6% under one sun illumination. Further investigations reveal that periodically conical over strengthen multiple reflections facilitate heat localization. Desalination test substantiates reliability practical freshwater production. numerical simulations optical microscopy observation exhibit topography‐strengthened vapor generation effect. This study sheds new on rational manipulation photothermal materials high‐efficiency evaporation.
Язык: Английский
Процитировано
80
Desalination, Год журнала: 2023, Номер 568, С. 116999 - 116999
Опубликована: Сен. 28, 2023
Язык: Английский
Процитировано
76
Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(23)
Опубликована: Март 16, 2023
Abstract Many living organisms have the superb structure‐editing capacity for better adaptation in dynamic environments over course of their life cycle. However, it's still challenging to replicate such natural into artificial hydrogel actuating systems enhancing environment‐interactive functions. Herein, we learn from metamorphosis development glowing octopus construct proof‐of‐concept fluorescent actuators with life‐like by developing a universal stepwise inside‐out growth strategy. These could perform origami‐like 3D shape deformation and also enable postnatal new structures adapt additional states different visual information delivery using environment keys (e.g., temperature, pH). This study opens previously unidentified‐avenues bio‐inspired actuators/robotics extends potential uses encryption.
Язык: Английский
Процитировано
72
ACS Applied Materials & Interfaces, Год журнала: 2022, Номер 14(45), С. 50966 - 50981
Опубликована: Ноя. 7, 2022
Solar photothermal-driven interfacial evaporation is a promising technology with great potential for wastewater purification and seawater desalination. However, intermittent solar illumination salt accumulation are still the major roadblocks of in practical applications. Herein, we developed novel system based on hierarchical MXene/polydopamine (PDA)/magnetic phase-change microcapsule composites (hereafter named "MXene/PDA@TiO2/Fe3O4@C22-HMC") integrated natural wood. The were fabricated by microencapsulating n-docosane as material (PCM) core TiO2/Fe3O4 composite shell then coating PDA layer, followed surface-attaching MXene nanosheets. obtained MXene/PDA@TiO2/Fe3O4@C22-HMC exhibits good optical absorption ability, high heat energy-storage capacity, hydrophilicity. This enables MXene/PDA@TiO2/Fe3O4@C22-HMC-based evaporator to gain water rate 2.09 kg m-2 h-1 under one-sun illumination. A combination microchannels wood tiny gap between microcapsules results rapid transportation within system, which effectively resists during evaporating process. As result, there was no crystal observed from surface 10 wt % NaCl solution three-sun 8 h. More importantly, introduction Fe3O4 nanoparticles into TiO2 endows magnetism, greatly enhancing reusability separability undertake multicycle washing processes long-term desalination use. latent release offers large amount energy continuous semi-cloudy day, increasing total production 1.17 compared conventional without PCM. study provides an effective utilization solar-driven systems
Язык: Английский
Процитировано
71
Advanced Functional Materials, Год журнала: 2023, Номер 33(19)
Опубликована: Март 12, 2023
Abstract Access to uranium resources is critical the sustainable development of nuclear energy. The ocean contains abundant resources, but marine biological pollution and low concentration make it a giant challenge extract from seawater. On foundation selective adsorption using high uranium‐affinity groups, realizing external‐field improved capture without extra energy consumption highly attractive. A solar thermal collector with 3D ion‐transport networks based on environmentally friendly biomass material reported, which antibacterial ligands photothermal graphene oxide. ability through an easy one‐step reaction fast mass transfer caused by conversion collaboratively improve original capacity hydrogel 46.7%, reaching 9.18 mg g −1 after contact natural seawater for 14 days. This study provides universal strategy design physical‐fields‐enhanced adsorbents.
Язык: Английский
Процитировано
67
Nature Water, Год журнала: 2024, Номер 2(2), С. 115 - 126
Опубликована: Фев. 21, 2024
Язык: Английский
Процитировано
66
Advanced Functional Materials, Год журнала: 2023, Номер 33(31)
Опубликована: Апрель 21, 2023
Abstract Solar‐driven vapor generation offers an affordable and sustainable approach to solve global freshwater scarcity. Creating interfacial solar evaporators capable of increasing water production rates matching human requirements is highly desirable but challenging due the slow transportation dynamics unavoidable oil‐fouling. Herein, a bio‐inspired lotus‐petiole‐mimetic microstructured graphene/poly(N‐acryloyl glycinamide) evaporator with integrated hydrophilic hydrophobic microregions developed. Through accurate control supramolecular interactions, optimized incorporating unique structural features wettability shows high light harvesting, enhanced activation, reduced energy demand for vaporization, enabling groundbreaking comprehensive performance along evaporation rate up 3.4 kg m −2 h −1 conversion efficiency ≈93% under one sun irradiation (1 kW ). Molecular simulations reveal that abundant hydrogen bonding sites polymeric networks can thermodynamically modulate escape behavior molecules. Notably, neither decrease in nor fouling on observed during prolonged purification process toward nano/submicrometer emulsions, oily brines, actual seawater, domestic wastewater. This study provides distinctive insights into behaviors at molecular level pioneers rational strategy design high‐yield freshwater‐generation systems wastewater containing complex contaminants.
Язык: Английский
Процитировано
55
Exploration, Год журнала: 2023, Номер 3(3)
Опубликована: Май 23, 2023
Covalent organic frameworks (COFs) stand for a class of emerging crystalline porous materials, which are ingeniously constructed with units through strong covalent bonds. Their excellent design capabilities, and uniform tunable pore structure make them potential materials various applications. With the continuous development synthesis technique nanoscience, COFs have been successfully combined variety functional to form COFs-based composites superior performance than individual components. This paper offers an overview different types reported so far, particular focus on applications composites. Moreover, challenges future prospects presented. We anticipate that review will provide some inspiration further
Язык: Английский
Процитировано
55
Nature Water, Год журнала: 2023, Номер 1(7), С. 587 - 601
Опубликована: Июль 20, 2023
Язык: Английский
Процитировано
53
Small, Год журнала: 2023, Номер 19(26)
Опубликована: Март 21, 2023
Abstract Techniques beyond crystal engineering are critical for manufacturing covalent organic frameworks (COFs) and to explore them advanced applications. However, COFs normally obtained as insoluble, unmeltable, thus nonprocessible microcrystalline powders. Therefore, it is a significant challenge implement into larger architectures structural control on different length scales. Herein, facile strategy presented prepare flexible COF nanofiber membranes by in‐situ growth of polyacrylonitrile (PAN) substrates via reversible polycondensation‐termination approach. The PAN@COF with vertically aligned nanoplates combine large functional surface efficient mass transport, making promising adsorbent, example, water purification. antibiotic pollutant ofloxacin (OFX) removed from superior absorption capacity ≈236 mg g −1 removal efficiency high 98%. here can be extended various Schiff base‐derived materials compositions, providing highly way construct COF‐based several
Язык: Английский
Процитировано
50