Merging Consecutive PET Processes within a Metal–Organic Cage for Abiotic–Biotic Combined Photocatalytic Biomass Reforming DOI
Zhe Li,

Junkai Cai,

Lingxiao Wang

и другие.

ACS Catalysis, Год журнала: 2024, Номер 14(21), С. 16374 - 16382

Опубликована: Окт. 22, 2024

Combining abiotic photocatalytic modules with enzymatic conversion to reform biomass represents a compelling way for sustainable energy schemes but faces marked challenges on the electron and proton transport corresponding cofactor regeneration shuttling between biotic partners. Herein, we report consecutive photoinduced electron-transfer approach into fuels active H-source nitroarene reduction by grafting cage-dye-NADH (nicotinamide adenine dinucleotide) clathrate glucose dehydrogenase (GDH). Under light irradiation, acts as photoactive relay conduct two 1e– reactions consecutively 2e– oxidation of NADH NAD+, guaranteeing an orderly path related regeneration. When is positioned inside pocket GDH join NAD+-mediated synthesis, metal–organic artificial enzyme facilitates fast generation native within one working module. The combines photocatalysis dehydrogenation endow efficient feedstocks green H-source, innovating unique paradigm scheme that photons in turnover cycle. superiority allows direct hydrogenation fine chemicals enables tandem number reaching 15,000, providing distinguished avenue utilization solar conversion.

Язык: Английский

Enhanced Co‐adsorption of Alcohols and Amines for Visible Light Driven Oxidative Condensation Using Iron‐based MOF DOI
Kai Zhang, Yu Huang, Dongsheng Zhang

и другие.

Chemistry - A European Journal, Год журнала: 2024, Номер 30(43)

Опубликована: Май 28, 2024

Imines are essential intermediates in organic transformations, and is generally produced by dehydrogenative condensation of alcohols amines with the assist specialized catalysts additives. Heterogeneous photocatalysis provides a sustainable platform for such process without using toxic oxidants, yet functionalized photocatalyst optimized co-adsorption reactants needs to be developed promote stoichiometric oxidative under ambient conditions. Here, we show that benzyl alcohol aniline adsorb non-interferingly on Fe node linker sites MIL-53(Fe) metal frameworks (MOFs), respectively. The both barely influences reduction molecular oxygen generate radicals, resulting efficient formation benzaldehyde visible light. Additionally, weak adsorption water together surface acidity rapid depletion generated water, achieving an C-N bond creation wide range substrates.

Язык: Английский

Процитировано

1
A Host–Guest Platform for Highly Efficient, Quantitative, and Rapid Detection of Nitroreductase DOI Creative Commons
Wen Si, Yang Jiao, Xianchao Jia

и другие.

Chemosensors, Год журнала: 2024, Номер 12(8), С. 145 - 145

Опубликована: Июль 30, 2024

Nitroreductase (NTR) is an enzyme expressed at abnormally high level in solid tumors, which associated with the hypoxia tumors. The establishment of a high-performance and convenient fluorescent platform for fast monitoring NTR pivotal importance. Herein, novel host–guest complex was created by encapsulating substrate GP-NTR within metal–organic capsule Zn-MPB that included NADH mimic detection via responding to nitroreductase responsiveness good fluorescence imaging. Notably, double-substrate process streamlined single–substrate supramolecular method catalytic NTR, enabled reaction be independent cofactor supply shortened distance between active site NTR. increasing intensity Zn-MPB⊃GP-NTR exhibits linear relationship concentration shows response toward solution tens seconds. also displays sensitivity low limit 6.4 ng/mL. Cells vivo studies have confirmed could successfully applied imaging NTR-overexpressed tumor cells tumor-bearing animals. not only provides new avenue design optimization rapid quantitative activity, but offers tool early diagnosis hypoxia-related

Язык: Английский

Процитировано

1
A Pd4L2 cage containing Brønsted-base active sites for the one-pot photooxidation/Knoevenagel condensation reaction DOI Creative Commons
Yanfang Zhou, Dan‐Ni Yan,

Shao‐Jun Hu

и другие.

Dalton Transactions, Год журнала: 2023, Номер 52(23), С. 8135 - 8141

Опубликована: Янв. 1, 2023

Brønsted-base active sites on a Pd 4 L 2 cage facilitates enhanced catalytic efficiency, wide substrate scope and high turnover number (TON) for the one-pot photooxidation/Knoevenagel condensation reaction under mild conditions.

Язык: Английский

Процитировано

1
Merging Consecutive PET Processes within a Metal–Organic Cage for Abiotic–Biotic Combined Photocatalytic Biomass Reforming DOI
Zhe Li,

Junkai Cai,

Lingxiao Wang

и другие.

ACS Catalysis, Год журнала: 2024, Номер 14(21), С. 16374 - 16382

Опубликована: Окт. 22, 2024

Combining abiotic photocatalytic modules with enzymatic conversion to reform biomass represents a compelling way for sustainable energy schemes but faces marked challenges on the electron and proton transport corresponding cofactor regeneration shuttling between biotic partners. Herein, we report consecutive photoinduced electron-transfer approach into fuels active H-source nitroarene reduction by grafting cage-dye-NADH (nicotinamide adenine dinucleotide) clathrate glucose dehydrogenase (GDH). Under light irradiation, acts as photoactive relay conduct two 1e– reactions consecutively 2e– oxidation of NADH NAD+, guaranteeing an orderly path related regeneration. When is positioned inside pocket GDH join NAD+-mediated synthesis, metal–organic artificial enzyme facilitates fast generation native within one working module. The combines photocatalysis dehydrogenation endow efficient feedstocks green H-source, innovating unique paradigm scheme that photons in turnover cycle. superiority allows direct hydrogenation fine chemicals enables tandem number reaching 15,000, providing distinguished avenue utilization solar conversion.

Язык: Английский

Процитировано

0