ACS Sensors,
Год журнала:
2024,
Номер
9(9), С. 4608 - 4616
Опубликована: Авг. 8, 2024
Efficient
and
reliable
technologies
for
the
on-site
detection
of
illicit
drugs
are
important
in
drug-facilitated
crime
investigations.
However,
development
such
is
challenging.
Based
on
synthetic
optimization,
introducing
a
boron
ester
functional
group
to
two
furanic
indicators
endows
stimulus-responsive
properties
synergistically.
The
ring-opening
reaction
presence
amine-containing
generated
well-known
donor-acceptor
Stenhouse
adducts,
accompanied
by
strong
color
changes.
A
small-size
lightweight
laminated
sensor
was
integrated
based
outstanding
ratiometric
variations
active
indicators.
prototype
platform
fabricated
equipped
with
circuit
control,
mini
pump,
signal
processing
system.
user-friendly
efficient
screening
drugs,
including
phenethylamines,
amphetamines,
cathinones,
tryptamines
liquid
states
were
conducted.
response
linear
concentration
range
2.1-10.6
μg·mL
Materials Advances,
Год журнала:
2024,
Номер
5(8), С. 3257 - 3280
Опубликована: Янв. 1, 2024
Herein,
we
report
the
synthesis
and
characterization
of
metal
complexes
Fe(
iii
),
Co(
ii
Cu(
)
with
SALPHEN
(
N
,
-bis(salicylimine)-
o
-phenyldiammine)
their
potential
application
as
sensitizers
in
dye-sensitized
solar
cells
(DSSCs).
Journal of the American Chemical Society,
Год журнала:
2024,
Номер
146(26), С. 17956 - 17963
Опубликована: Июнь 8, 2024
Conjugation
between
three-dimensional
(3D)
carboranes
and
the
attached
substituents
is
commonly
believed
to
be
very
weak.
In
this
paper,
we
report
that
reducing
1,12-bis(BMes2)-p-carborane
(B2pCab)
with
one
electron
gives
a
radical
anion
centrosymmetric
semiquinoidal
structure.
This
shows
extensive
delocalization
two
boron
centers
over
p-carborane
bridge
due
overlap
of
carborane
lowest
unoccupied
molecular
orbital
(LUMO)
BMes2
LUMO.
Unlike
dianions
other
C2B10H12
carboranes,
which
rearrange
nido-form,
two-electron
reduction
B2pCab
leads
rearrangement
into
basket-shaped
intermediate.
ACS Sensors,
Год журнала:
2024,
Номер
9(9), С. 4608 - 4616
Опубликована: Авг. 8, 2024
Efficient
and
reliable
technologies
for
the
on-site
detection
of
illicit
drugs
are
important
in
drug-facilitated
crime
investigations.
However,
development
such
is
challenging.
Based
on
synthetic
optimization,
introducing
a
boron
ester
functional
group
to
two
furanic
indicators
endows
stimulus-responsive
properties
synergistically.
The
ring-opening
reaction
presence
amine-containing
generated
well-known
donor-acceptor
Stenhouse
adducts,
accompanied
by
strong
color
changes.
A
small-size
lightweight
laminated
sensor
was
integrated
based
outstanding
ratiometric
variations
active
indicators.
prototype
platform
fabricated
equipped
with
circuit
control,
mini
pump,
signal
processing
system.
user-friendly
efficient
screening
drugs,
including
phenethylamines,
amphetamines,
cathinones,
tryptamines
liquid
states
were
conducted.
response
linear
concentration
range
2.1-10.6
μg·mL
