Defect engineering of carbon-based electrocatalysts for the CO2 reduction reaction: A review DOI Open Access

Yankun Lu,

Baixue Cheng,

Haoyu Zhan

и другие.

New Carbon Materials, Год журнала: 2024, Номер 39(1), С. 17 - 41

Опубликована: Фев. 1, 2024

Язык: Английский

Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction DOI

Ziruo Zhou,

Wenyu Guo,

Tingyu Yang

и другие.

Chinese Journal of Structural Chemistry, Год журнала: 2024, Номер 43(3), С. 100245 - 100245

Опубликована: Фев. 5, 2024

Язык: Английский

Процитировано

74
Molecular Co-Catalyst Confined within a Metallacage for Enhanced Photocatalytic CO2 Reduction DOI
Dongdong Liu,

Huirong Ma,

Chao Zhu

и другие.

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(3), С. 2275 - 2285

Опубликована: Янв. 12, 2024

The construction of structurally well-defined supramolecular hosts to accommodate catalytically active species within a cavity is promising way address catalyst deactivation. resulting catalysts can significantly improve the utilization catalytic sites, thereby achieving highly efficient chemical conversion. In this study, Co-metalated phthalocyanine (

Язык: Английский

Процитировано

45
Regulating the Electronic Configuration of Ni Sites by Breaking Symmetry of Ni‐Porphyrin to Facilitate CO2 Photocatalytic Reduction DOI
Yuan‐Hui Zhong, Yang Wang,

Sheng‐Yi Zhao

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер 34(25)

Опубликована: Фев. 10, 2024

Abstract Adapting the coordination environment to influence electronic configuration of active sites represents an efficient approach for improving photocatalytic performance CO 2 reduction reaction (CO RR) but how execute it precisely remains challenging. Herein, heteroatom‐substitution in Ni‐porphyrin break symmetry Ni center is proposed be effective solution. Based on this, two symmetry‐breaking Ni‐porphyrins, namely Ni(Cl)ON 3 Por and Ni(Cl)SN , are designed successfully prepared. By theoretical calculation, found that efficiently regulates d orbital energy levels center. Furthermore, experimental findings jointly revealed Ni‐porphyrins facilitates generation highly reactive I species during catalytic process, effectively stabilizing reducing barrier formation key * COOH intermediate. As a result, gave production rates 24.7 38.8 mmol g −1 h as well selectivity toward 94.0% 96.4%, respectively, outperforming symmetric NiN 4 rate 6.6 82.8%). These offer microscopic insights into modulate activity by tuning rational design competent catalyst RR photocatalysis.

Язык: Английский

Процитировано

24
Artificial photosynthesis platform of 2D/2D MXene/crystalline covalent organic frameworks heterostructure for efficient photoenzymatic CO2 reduction DOI
Jiafu Qu, Tingyu Yang,

Pengye Zhang

и другие.

Applied Catalysis B Environment and Energy, Год журнала: 2024, Номер 348, С. 123827 - 123827

Опубликована: Апрель 24, 2024

Язык: Английский

Процитировано

21
Tailoring CuNi heteronuclear diatomic catalysts: Precision in structural design for exceptionally selective CO2 photoreduction to ethanol DOI

Entian Cui,

Yulian Lu, Jizhou Jiang

и другие.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2024, Номер 59, С. 126 - 136

Опубликована: Апрель 1, 2024

Язык: Английский

Процитировано

17
Halogen modified organic porous semiconductors in photocatalysis: mechanism, synthesis, and application DOI Creative Commons
Yue Yang, Liping Guo, Xuepeng Wang

и другие.

Advanced Powder Materials, Год журнала: 2024, Номер 3(2), С. 100178 - 100178

Опубликована: Янв. 23, 2024

Photocatalysis is considered as the promising energy conversion way to resolve issues of crisis and environmental pollution. As key point photocatalysis, photocatalyst determines final efficiency from solar, therefore, composition photoelectronic nature which deserve be valued. Halogen often affects immensely intrinsic electron configuration matrix because electrophilic property, thus its topic has attracted lots attention for photocatalytic application. In this review, halogen-contained organic porous semiconductors are discussed in detailed. Firstly, role halogens photocatalysis based on categorized. Then, introduce into their applications reviewed. At last, outlooks given at end paper. This review would bring new insights non-metal doping engineering improving performance semiconductors.

Язык: Английский

Процитировано

15
Achieving Almost 100% Selectivity in Photocatalytic CO2 Reduction to Methane via In‐Situ Atmosphere Regulation Strategy DOI

Wanyi Zhang,

Chaoyuan Deng, Wei Wang

и другие.

Advanced Materials, Год журнала: 2024, Номер 36(35)

Опубликована: Июль 14, 2024

Artificial photosynthesis, harnessing solar energy to convert CO

Язык: Английский

Процитировано

15
Mechanisms of noble metal-enhanced ferroelectric spontaneous polarized photocatalysis DOI
Mingliang Du, Wei Liu, Nian Liu

и другие.

Nano Energy, Год журнала: 2024, Номер 124, С. 109495 - 109495

Опубликована: Март 12, 2024

Язык: Английский

Процитировано

14
CQDs-interspersed floral CdS/NiAl-LDH heterojunction towards efficient photoreduction of CO2-to-CO DOI
Jia Li, Wentao Liu, Yang Li

и другие.

Journal of Alloys and Compounds, Год журнала: 2024, Номер 983, С. 173944 - 173944

Опубликована: Фев. 22, 2024

Язык: Английский

Процитировано

10
Pivotal Impact Factors in Photocatalytic Reduction of CO2 to Value‐Added C1 and C2 Products DOI

Yongqian Cui,

Abdelkader Labidi,

Xinxin Liang

и другие.

ChemSusChem, Год журнала: 2024, Номер unknown

Опубликована: Апрель 15, 2024

Over the past decades, CO

Язык: Английский

Процитировано

10