Nickel/Photoredox-Catalyzed Asymmetric Three-Component Cross-Coupling To Access Enantioenriched 1,1-Diaryl(heteroaryl)alkanes DOI

Xueying Gao,

Tingzhi Lin,

Yan‐En Wang

и другие.

Organic Letters, Год журнала: 2024, Номер 26(41), С. 8792 - 8797

Опубликована: Окт. 8, 2024

An enantioselective 1,2-dicarbofunctionalization of vinyl (hetero)arenes with alkyl bromides and aryl through nickel/photoredox catalysis is described. This three-component domino arylation could generate a diverse array enantioenriched 1,1-diaryl(heteroaryl)alkanes good to excellent yields (up 88%) high enantioselectivities 99%

Язык: Английский

Ni-catalyzed cross-electrophile alkyl-alkyl coupling reactions DOI Creative Commons

Li-Xu You,

Tian Lan,

Chunling Guo

и другие.

Science China Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 3, 2025

Язык: Английский

Процитировано

0
New reactivity of late 3d transition metal complexes in catalytic reactions of alkynes DOI
Shenghan Teng,

Peiyao Liang,

Jianrong Steve Zhou

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review summarizes seven types of new reactivities found in late 3d metal complexes and catalytic examples recent years.

Язык: Английский

Процитировано

0
Nickel-Catalyzed Reductive Arylalkylation of Alkenes: 5-Exo Cyclization vs. 6-Endo Cyclization vs. 1,2-Aryl Migration to 6-Endo Product DOI
Yuxin Du, Hongli Wu, Miao Yang

и другие.

Dalton Transactions, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

The DFT calculation explains the mechanism of forming 5- exo and 6- endo cyclization products in Ni-catalyzed reductive arylalkylation alkenes.

Язык: Английский

Процитировано

0
Bis(pinacolato)diboron‐Enabled Ni‐Catalyzed Reductive Arylation/Vinylation of Alkyl Electrophiles DOI Creative Commons
Deli Sun, Yuxin Gong,

Yu Wu

и другие.

Advanced Science, Год журнала: 2024, Номер 11(31)

Опубликована: Июнь 17, 2024

Abstract Herein, the use of economically and environmentally friendly bis(pinacolato)diboron (B 2 Pin ) is described as a non‐metallic reductant in mediating Ni‐catalyzed C(sp 3 )–C(sp reductive cross‐coupling alkyl electrophiles with aryl/vinyl halides. This method exhibits excellent suitability for heteroaryl halides halides/Katritzky salts. The present study compatible an situ halogenation alcohol method, allowing selective mono‐functionalization diols bio‐relevant alcohols (e.g., carbohydrates). B shows potential easy scalability without introducing additional metal impurities into products. It observed first time realm cross‐electrophile coupling chemistry that can sever to reduce Ni II 0 . mechanistic insight may inspire development new bond‐forming methodologies otherwise be difficult achieve reductant.

Язык: Английский

Процитировано

3
Nickel/Photoredox-Catalyzed Asymmetric Three-Component Cross-Coupling To Access Enantioenriched 1,1-Diaryl(heteroaryl)alkanes DOI

Xueying Gao,

Tingzhi Lin,

Yan‐En Wang

и другие.

Organic Letters, Год журнала: 2024, Номер 26(41), С. 8792 - 8797

Опубликована: Окт. 8, 2024

An enantioselective 1,2-dicarbofunctionalization of vinyl (hetero)arenes with alkyl bromides and aryl through nickel/photoredox catalysis is described. This three-component domino arylation could generate a diverse array enantioenriched 1,1-diaryl(heteroaryl)alkanes good to excellent yields (up 88%) high enantioselectivities 99%

Язык: Английский

Процитировано

3