Advanced Energy Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 9, 2024
Abstract
Manganese
(Mn)‐based
aqueous
zinc
ion
batteries
show
great
promise
for
large‐scale
energy
storage
due
to
their
high
capacity,
environmental
friendliness,
and
low
cost.
However,
they
suffer
from
the
severe
capacity
decay
associated
with
dissolution
of
Mn
cathode/electrolyte
interface.
In
this
study,
theoretical
modeling
inspires
that
amino
acid
molecule,
isoleucine
(Ile),
can
be
an
ideal
surface
coating
material
α‐MnO
2
stabilize
lattice
mitigate
dissolution,
thereby
enhancing
cycling
stability.
Furthermore,
coated
Ile
molecular
layers
accumulate
Zn
2+
ions
electrolyte
promote
those
ions’
transport
cathode
while
prohibiting
H
O
accessing
surface,
reducing
erosion.
The
compact
organic–inorganic
interface
is
experimentally
synthesized
utilizing
shows
homogeneous
distribution
on
well‐defined
Ile‐α‐MnO
nanorod
electrodes.
fabricated
zinc‐ion
battery
exhibits
a
specific
(332.8
mAh
g
−1
at
0.1
A
)
excellent
stability
(85%
after
2000
cycles
1
as
well
good
inhibition
toward
surpassing
most
reported
materials.
This
hybrid
design
provides
new,
simple
avenue
developing
high‐performance
low‐cost
Mn‐based
(AZIBs).
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(22)
Опубликована: Март 25, 2024
Abstract
Aqueous
zinc‐ion
batteries
(AZIBs)
are
considered
as
the
promising
candidates
for
large‐scale
energy
storage
because
of
their
high
safety,
low
cost
and
environmental
benignity.
The
applications
AZIBs
will
inevitably
result
in
a
large
amount
spent
AZIBs,
which
not
only
induce
waste
resources,
but
also
pose
risks.
Therefore,
sustainable
have
to
be
minimize
risk
pollution
maximize
utilization
compounds.
Herein,
this
minireview
focuses
on
sustainability
from
material
design
recycling
techniques.
structure
degradation
mechanism
discussed
guide
materials.
Subsequently,
component
materials
is
further
analysed
pre‐evaluate
behaviors
mentor
selection
more
materials,
including
active
cathodes,
Zn
anodes,
aqueous
electrolytes,
respectively.
According
features
corresponding
green
economic
approaches
proposed
realize
anodes
These
advanced
technologies
endow
with
efficiency
closed‐loop
control,
ensuring
that
devices.
This
review
offer
insight
into
potential
future
directions
AZIBs.
Chemical Society Reviews,
Год журнала:
2024,
Номер
53(10), С. 5291 - 5337
Опубликована: Янв. 1, 2024
Design
principles,
engineering
strategies,
challenges,
and
opportunities
of
gel
polymer
electrolytes
for
rechargeable
batteries
toward
wide-temperature
applications
are
thoroughly
reviewed.
Energy & Environmental Science,
Год журнала:
2024,
Номер
17(10), С. 3443 - 3453
Опубликована: Янв. 1, 2024
3-(Hydroxy(phenyl)phosphoryl)propanoic
acid
(HPA)
has
a
strong
coordination
ability
for
Zn
2+
/metal
anodes
which
not
only
form
sphere
micelles
that
promote
the
uniform
transmission
of
but
also
enhance
preferential
adsorption
on
anodes.
Advanced Materials,
Год журнала:
2024,
Номер
36(29)
Опубликована: Апрель 29, 2024
Abstract
The
advancement
of
aqueous
zinc‐ion
batteries
(AZIBs)
is
often
hampered
by
the
dendritic
zinc
growth
and
parasitic
side
reactions
between
anode
electrolyte,
especially
under
extreme
temperature
conditions.
This
study
unveils
performance
decay
mechanism
anodes
in
harsh
environments,
characterized
“dead
zinc”
at
low
temperatures
aggravated
hydrogen
evolution
adverse
by‐products
elevated
temperatures.
To
address
these
issues,
a
self‐adaptive
electrolyte
(TSAE),
founded
on
competitive
coordination
principle
co‐solvent
anions,
introduced.
exhibits
dynamic
solvation
capability,
engendering
an
inorganic‐rich
solid
interface
(SEI)
while
organic
alkyl
ether‐
carbonate‐containing
SEI
self‐adaptability
significantly
enhances
across
broad
range.
A
Zn//Zn
symmetrical
cell,
based
TSAE,
showcases
reversible
plating/stripping
exceeding
16
800
h
(>700
d)
room
1
mA
cm
−2
mAh
,
setting
record
lifespan.
Furthermore,
TSAE
enables
stable
operation
full
ultrawide
range
−35
to
75
°C.
work
illuminates
pathway
for
optimizing
AZIBs
fine‐tuning
interfacial
chemistry.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(21)
Опубликована: Март 27, 2024
Zn
metal
as
a
promising
anode
of
aqueous
batteries
faces
severe
challenges
from
dendrite
growth
and
side
reactions.
Here,
tetraphenylporphyrin
tetrasulfonic
acid
(TPPS)
is
explored
an
electrolyte
additive
for
advanced
anodes.
It
interesting
to
note
that
TPPS
spontaneously
assembles
into
unique
aggregates.
As
they
adsorb
on
the
anode,
aggregates
enhance
resistance
percolation
compared
single
molecules.
Meanwhile,
facilitates
anion
association
in
solvation
sheath
ACS Nano,
Год журнала:
2024,
Номер
18(4), С. 3752 - 3762
Опубликована: Янв. 17, 2024
The
performance
of
aqueous
zinc
metal
batteries
is
significantly
compromised
by
the
stability
solid
electrolyte
interphase
(SEI),
which
intimately
linked
to
structure
electrical
double
layer
(EDL)
between
anode
and
electrolyte.
Furthermore,
understanding
mechanical
behavior
SEI
crucial,
as
it
governs
its
response
stress
induced
volume
changes,
fracture,
or
deformation.
In
this
study,
we
introduce
l-glutamine
(Gln)
an
additive
regulate
adsorbed
environment
EDL
in
situ
produce
a
hybrid
consisting
ZnS
Gln-related
species.
results
nanoindentation
test
indicate
that
exhibits
low
modulus
hardness,
alongside
exceptional
shape
recovery
capability,
effectively
limits
side
reactions
enables
topological
adaptation
fluctuations
anodes
during
ion
plating/stripping,
thereby
enabling
Zn//Zn
symmetric
cells
exhibit
ultralong
cycle
life
4000
h
coin
high
cumulative
capacity
18,000
mA
pouch
cells.
More
importantly,
superiority
formulated
strategy
further
demonstrated
Zn//NH4V4O10
full
at
different
N/P
ratios
5.2,
4.9,
3.5,
2.4.
This
provides
promising
approach
for
future
interfacial
modulation
battery
chemistry.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(15)
Опубликована: Фев. 14, 2024
Abstract
Aqueous
zinc‐ion
batteries
(ZIBs)
are
promising
large‐scale
energy
storage
devices
because
of
their
low
cost
and
high
safety.
However,
owing
to
the
activity
H
2
O
molecules
in
electrolytes,
hydrogen
evolution
reaction
side
reactions
usually
take
place
on
Zn
anodes.
Herein,
additive‐free
PCA−Zn
electrolyte
with
capacity
suppressing
free
solvated
was
designed
by
selecting
cationophilic
solventophilic
anions.
In
such
electrolyte,
contact
ion‐pairs
solvent‐shared
were
achieved
even
at
concentration,
where
PCA
−
anions
coordinate
2+
bond
molecules.
Simultaneously,
also
induce
construction
H‐bonds
between
them.
Therefore,
is
effectively
restrained.
Furthermore,
since
possess
a
strong
affinity
metal
Zn,
they
can
adsorb
anode
surface
protect
from
direct
molecules,
inhibiting
occurrence
water‐triggered
reactions.
As
result,
plating/stripping
behavior
anodes
highly
reversible
coulombic
efficiency
reach
99.43
%
electrolyte.
To
illustrate
feasibility
Zn||PANI
full
assembled
based
exhibited
enhanced
cycling
performance.
