Photocatalytic Redox Reactions with Metal Complex Catalysts DOI

S. Fukuzumi

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 327 - 343

Опубликована: Дек. 20, 2024

Metal-to-ligand charge-transfer (MLCT) and ligand-to-metal (LMCT) states are produced upon photoexcitation of metal complexes. The MLCT LMCT have strong reducing oxidizing capabilities, respectively, exhibiting photoredox catalysis in various photocatalytic redox reactions including water oxidation, CO2 reduction H2O2 production. By combining thermal catalysis, molecular functions photosynthesis been achieved by constructing models PSI PSII models, which combined to achieve the stoichiometry that is regioselective NAD+ NADH H2O.

Язык: Английский

Essential parts of hydrogen economy: Hydrogen production, storage, transportation and application DOI
Kashif Naseem, Fei Qin, Farrukh Khalid

и другие.

Renewable and Sustainable Energy Reviews, Год журнала: 2024, Номер 210, С. 115196 - 115196

Опубликована: Дек. 18, 2024

Язык: Английский

Процитировано

11

Part 1: Photocatalytic water splitting DOI
Mehrnaz Bahadori, Mahmood Tavakoli Hafshejani, Mahmoud Nasrollahzadeh

и другие.

Elsevier eBooks, Год журнала: 2025, Номер unknown, С. 95 - 124

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Engineering Long-Lived Charge Separation States Boosts Type-I ROS Generation for Efficient Cancer Therapy DOI

Zhongyan Hu,

Wenjing Liu, Jianyu Zhang

и другие.

Biomaterials, Год журнала: 2025, Номер 319, С. 123218 - 123218

Опубликована: Фев. 28, 2025

Язык: Английский

Процитировано

0

Designing biomimetic catalytic systems for CO2 reduction to formate using NAD(P)H DOI

Chan-Woo Park,

Chul Han Kwon,

Young Hyun Hong

и другие.

Inorganic Chemistry Frontiers, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review article focuses on current achievements and identifies future research directions by designing biomimetic catalytic systems for CO 2 reduction to formate using NAD(P)H.

Язык: Английский

Процитировано

0

Functional Molecular Models of Photosynthesis DOI Creative Commons
Shunichi Fukuzumi, Yong‐Min Lee, Wonwoo Nam

и другие.

iScience, Год журнала: 2024, Номер 27(9), С. 110694 - 110694

Опубликована: Авг. 8, 2024

This perspective focuses on functional models of photosynthesis to achieve molecular photocatalytic systems that mimic photosystems I and II (PSI PSII). A long-lived high-energy electron-transfer state 9-mesityl-10-methylacridinium ion (Acr

Язык: Английский

Процитировано

2

Photoredox catalysis of acridinium and quinolinium ion derivatives DOI
Shunichi Fukuzumi, Yong‐Min Lee, Wonwoo Nam

и другие.

Bulletin of the Korean Chemical Society, Год журнала: 2024, Номер unknown

Опубликована: Дек. 9, 2024

Abstract Photoredox catalysis has attracted increasing attention because of wide range synthetic transformations and solar energy conversion applications. Reviews on photoredox have so far focused predominantly the This review highlights how organic catalysts were developed they function as efficient photocatalysts in mechanistic point views. In particular, 9‐mesityl‐10‐methylactidinium (Acr + –Mes) been highlighted one best catalysts. Acr –Mes was originally a model compound photosynthetic reaction center to mimic long lifetime charge‐separated state which is converted chemical photosynthesis. The reason why acts most catalyst clarified terms one‐electron redox potentials lifetimes electron‐transfer • •+ ) produced upon photoexcitation different solvents. mesityl substituent at 9‐position moiety essential for discussed comparison with acridinium ions substituents R –R) including 10‐methylacridinium ion no (AcrH ). mechanisms are various reactions mimicking quinolinium its derivatives also that –Mes. Finally, immobilization form composite improve catalytic activity stability.

Язык: Английский

Процитировано

2

Developing biomimetics to produce value-added products DOI
Young Hyun Hong

Chem, Год журнала: 2024, Номер 10(6), С. 1620 - 1622

Опубликована: Май 30, 2024

Язык: Английский

Процитировано

1

Photocatalytic Redox Reactions with Metal Complex Catalysts DOI

S. Fukuzumi

Royal Society of Chemistry eBooks, Год журнала: 2024, Номер unknown, С. 327 - 343

Опубликована: Дек. 20, 2024

Metal-to-ligand charge-transfer (MLCT) and ligand-to-metal (LMCT) states are produced upon photoexcitation of metal complexes. The MLCT LMCT have strong reducing oxidizing capabilities, respectively, exhibiting photoredox catalysis in various photocatalytic redox reactions including water oxidation, CO2 reduction H2O2 production. By combining thermal catalysis, molecular functions photosynthesis been achieved by constructing models PSI PSII models, which combined to achieve the stoichiometry that is regioselective NAD+ NADH H2O.

Язык: Английский

Процитировано

0