Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160541 - 160541
Опубликована: Фев. 1, 2025
Язык: Английский
ACS Nano, Год журнала: 2024, Номер 18(27), С. 17439 - 17468
Опубликована: Июнь 27, 2024
Lithium metal batteries (LMBs), with high energy densities, are strong contenders for the next generation of storage systems. Nevertheless, unregulated growth lithium dendrites and unstable solid electrolyte interphase (SEI) significantly hamper their cycling efficiency raise serious safety concerns, rendering LMBs unfeasible real-world implementation. Covalent organic frameworks (COFs) derivatives have emerged as multifunctional materials significant potential addressing inherent problems anode electrode metal. This stems from abundant metal-affine functional groups, internal channels, widely tunable architecture. The original COFs, derivatives, COF-based composites can effectively guide uniform deposition ions by enhancing conductivity, transport efficiency, mechanical strength, thereby mitigating issue dendrite growth. review provides a comprehensive analysis derived employed challenges posed in LMB. Additionally, we present prospects recommendations design engineering architectures that render feasible practical applications.
Язык: Английский
Процитировано
38
Langmuir, Год журнала: 2024, Номер 40(32), С. 16670 - 16689
Опубликована: Июнь 24, 2024
Waste polystyrene contributes considerably to environmental pollution due its persistent nature, prompting a widespread consensus on the urgent need for viable recycling solutions. Owing aromatic groups structure of polystyrene, hyper-cross-linked polymers can be synthesized through Friedel–Crafts cross-linking reaction using Lewis acids as catalysts. In addition, and carbonaceous counterparts used in several important applications, which helps their efficient recycling. This review systematically explores methods preparing multifunctional from waste applications sustainable We have comprehensively outlined various synthetic approaches these investigated physical chemical properties. These not only exhibit structural flexibility but also demonstrate diversity performance, making them suitable applications. Through systematic examination methods, we showcase cutting-edge positions materials field polymers. Additionally, provide in-depth insights into potential intentional recycling, highlighting contributions protection development. research provides valuable references fields science management, encouraging further exploration innovative utilization discarded polystyrene.
Язык: Английский
Процитировано
23
Journal of Molecular Structure, Год журнала: 2024, Номер 1321, С. 139945 - 139945
Опубликована: Сен. 7, 2024
Язык: Английский
Процитировано
14
Chemical Society Reviews, Год журнала: 2024, Номер 53(16), С. 8182 - 8201
Опубликована: Янв. 1, 2024
Covalent organic frameworks (COFs) have emerged as promising materials for ion conduction due to their highly tunable structures and excellent electrochemical stability. This review paper explores the mechanisms of in COFs, focusing on how these facilitate transport across ordered structures, which is crucial applications such solid electrolytes batteries fuel cells. We discuss design strategies employed enhance conductivity, including pore size optimization, functionalization with ionic groups, incorporation solvent molecules salts. Additionally, we examine various ion-conductive particularly energy storage conversion technologies, highlighting recent advancements future directions this field. aims provide a comprehensive overview current state research offering insights into potential COFs considering not only fundamental studies but also practical perspectives advanced devices.
Язык: Английский
Процитировано
12
Energy storage materials, Год журнала: 2024, Номер 67, С. 103295 - 103295
Опубликована: Фев. 24, 2024
Язык: Английский
Процитировано
11
Journal of the American Chemical Society, Год журнала: 2025, Номер unknown
Опубликована: Фев. 27, 2025
Covalent organic frameworks (COFs) have attracted broad interest because of their well-defined, customizable, highly stable, and porous structures. COFs shown significant potential for various practical applications, such as gas storage/purification, drug purification, water treatment, catalysis, battery applications. Scaling up is desirable to meet industrial application demands but hindered by the limitations synthesis methods high cost reactants. Recently, emerging green methods, mechanochemical flux synthesis, offered promising solutions these challenges (e.g., ton-scale production has been achieved companies recently). This Perspective provides an overview state art with respect discusses factors influencing large-scale COFs. Directions opportunities improving performance sustainability toward applications are also emphasized.
Язык: Английский
Процитировано
2
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161059 - 161059
Опубликована: Фев. 1, 2025
Язык: Английский
Процитировано
1
Chemical Science, Год журнала: 2025, Номер unknown
Опубликована: Янв. 1, 2025
Room-temperature synthesis bridges the gap between chemistry and practical application of COFs. This review provides an overview characterization technologies COF growth mechanisms recent room-temperature synthetic strategies.
Язык: Английский
Процитировано
1
CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2025, Номер 70, С. 142 - 206
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1
The Science of The Total Environment, Год журнала: 2024, Номер 939, С. 173478 - 173478
Опубликована: Май 28, 2024
Язык: Английский
Процитировано
8