Origin of Reactivity Trends of an Elusive Metathesis Intermediate from NMR Chemical Shift Analysis of Surrogate Analogues

Journal of the American Chemical Society, Год журнала: 2024, Номер 146(29), С. 20168 - 20182

Опубликована: Июль 9, 2024

Olefin metathesis has become an efficient tool in synthetic organic chemistry to build carbon-carbon bonds, thanks the development of Grubbs- and Schrock-type catalysts. coordination, a key often rate-determining elementary step for d

Язык: Английский

Hydrazido complexes prepared by methylation of an anionic end-on bridging dinitrogen dititanium complex

Chemical Communications, Год журнала: 2024, Номер 60(58), С. 7459 - 7462

Опубликована: Янв. 1, 2024

Stepwise methylation of end-on bridging dinitrogen to a hydrazido ligand pentamethylhydrazinium salt is mediated by titanium complex.

Язык: Английский