Zirconium-based metal−organic frameworks and their roles in electrocatalysis
Chemical Communications,
Год журнала:
2024,
Номер
60(64), С. 8360 - 8374
Опубликована: Янв. 1, 2024
Due
to
their
exceptional
chemical
stability
in
water
and
high
structural
tunability,
zirconium(IV)-based
MOFs
(Zr-MOFs)
have
been
considered
attractive
materials
the
broad
fields
of
electrocatalysis.
Numerous
studies
published
since
2015
attempted
utilise
Zr-MOFs
electrocatalysis,
with
porous
framework
serving
as
either
active
electrocatalyst
or
scaffold
surface
coating
further
enhance
performance
actual
electrocatalyst.
Herein,
roles
electrocatalytic
processes
are
discussed,
some
selected
examples
reporting
applications
various
reactions,
including
several
from
our
group,
overviewed.
Challenges,
limitations
opportunities
using
electrocatalysis
future
discussed.
Язык: Английский
Optimizing iodine adsorption in functionalized metal-organic frameworks via an unprecedented positional isomerism strategy
Chemical Engineering Journal,
Год журнала:
2024,
Номер
499, С. 156586 - 156586
Опубликована: Окт. 10, 2024
Язык: Английский
Pioneering radiation dosimetry and photothermal conversion in a photochromic and radiochromic thorium cluster
Science China Chemistry,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 7, 2025
Язык: Английский
Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials
Journal of the American Chemical Society,
Год журнала:
2024,
Номер
146(27), С. 18189 - 18204
Опубликована: Июнь 29, 2024
The
conceptual
framework
presented
in
this
Perspective
overviews
the
design
principles
of
innovative
thorium-based
materials
that
could
address
urgent
needs
medicinal,
nuclear
energy,
and
waste
remediation
sectors
from
lens
zirconium
uranium
analogs.
We
survey
intersections
Zr,
Th,
U
chemistry
with
a
focus
on
how
intrinsic
behavior
each
metal
translates
to
broader
material
properties,
including,
but
not
limited
to,
structural
topological
diversity,
preferential
metal–ligand
binding,
reactivity.
On
example
several
classes
materials,
including
organometallic
complexes,
polyoxometalates,
primary
Perspective,
metal–organic
frameworks
(MOFs),
govern
preparation
Zr-,
Th-,
U-compounds,
oxophilicity,
variation
oxidation
states,
stable
coordination
environments
have
been
considered.
Further,
we
highlight
impact
mentioned
variables
may
shift
throughout
progression
discrete
molecular
systems
extended
structures.
discuss
common
assumption
zirconium-organic
are
typically
considered
close
analog
congeners
areas
such
as
preparation.
Through
consideration
fundamental
principles,
shed
light
relationships
between
U-based
critical
analysis
their
distinct
properties
can
be
used
target
desired
performance.
As
result,
provide
detailed
understanding
Th-based
by
anchoring
two
well-studied
reference
points,
zirconium-
uranium-containing
Язык: Английский
Switching from Molecules to Functional Materials: Breakthroughs in Photochromism With MOFs
Advanced Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 7, 2024
Abstract
Photochromic
materials
with
properties
that
can
be
dynamically
tailored
as
a
function
of
external
stimuli
are
rapidly
expanding
field
driven
by
applications
in
areas
ranging
from
molecular
computing,
nanotechnology,
or
photopharmacology
to
programable
heterogeneous
catalysis.
Challenges
arise,
however,
when
translating
the
rapid,
solution‐like
response
stimuli‐responsive
moieties
solid‐state
due
intermolecular
interactions
imposed
through
close
packing
bulk
solids.
As
result,
integration
photochromic
compounds
into
synthetically
porous
matrices,
such
metal‐organic
frameworks
(MOFs),
has
come
forefront
an
emerging
strategy
for
material
development.
This
review
highlights
how
core
principles
reticular
chemistry
(on
example
MOFs)
play
critical
role
performance,
surpassing
limitations
previously
observed
solution
solid
state.
The
symbiotic
relationship
between
photoresponsive
and
focus
on
synthesis
creates
avenues
toward
tailorable
photoisomerization
kinetics,
directional
energy
charge
transfer,
switchable
gas
sorption,
synergistic
chromophore
communication
is
discussed.
not
only
focuses
recent
cutting‐edge
advancements
development,
but
also
novel,
vital‐to‐pursue
pathways
multifaceted
functional
realms
energy,
technology,
biomedicine.
Язык: Английский
Catalytically Active Site Mapping Realized through Energy Transfer Modeling
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
64(4)
Опубликована: Окт. 4, 2024
The
demands
of
a
sustainable
chemical
industry
are
driving
force
for
the
development
heterogeneous
catalytic
platforms
exhibiting
facile
catalyst
recovery,
recycling,
and
resilience
to
diverse
reaction
conditions.
Homogeneous-to-heterogeneous
transitions
can
be
realized
through
integration
efficient
homogeneous
catalysts
within
porous
matrices.
Herein,
we
offer
versatile
approach
understanding
how
guest
distribution
evolution
impact
performance
host-guest
by
implementing
resonance
energy
transfer
(RET)
concept
using
fluorescent
model
systems
mimicking
steric
constraints
targeted
catalysts.
Using
RET-based
methodology,
mapped
condition-dependent
(re)distribution
support
on
example
modular
matrices
such
as
metal-organic
frameworks
(MOFs).
Furthermore,
correlate
RET
results
performed
with
two
MOF-encapsulated
used
promote
CO2
hydrogenation
ring-closing
metathesis.
Guests
incorporated
aperture-opening
encapsulation,
redistribution
is
not
observed
under
practical
conditions,
showcasing
pathway
advance
recyclability
in
case
platforms.
These
studies
represent
first
generalizable
mapping
systems,
providing
foundation
predicting
tailoring
integrated
into
various
supports.
Язык: Английский