Activating Metal–Organic Cages by Incorporating Functional M(ImPhen)3 Metalloligands: From Structural Design to Applications DOI
Yu‐Lin Lu, Yaping Wang,

Kai Wu

и другие.

Accounts of Chemical Research, Год журнала: 2024, Номер 57(22), С. 3277 - 3291

Опубликована: Окт. 9, 2024

ConspectusThe emulation of ingenious biofunctions has been a research focus for several decades. Metal-organic cages (MOCs), as type discrete supramolecular assembly with well-defined shapes and cavities, have aroused great interest in chemists to imitate natural protein or enzymes. However, genuinely achieve tailored functionalities reactivities enzymes, the design cage structures combining both confined microenvironment active site is prerequisite. Therefore, integration functionalized motifs into MOCs expected provide feasible approach construct biofunctional nanospaces, which not only allows modulation properties applications such molecular recognition, transport, catalysis but also creates unique microenvironments that promote enzymatic effects special selectivities, thereby providing versatile platform exceptional biomimetic functions beyond.In this Account, we specifically on our toward engineering confined-nanospaces via incorporation M(ImPhen)

Язык: Английский

Activating Metal–Organic Cages by Incorporating Functional M(ImPhen)3 Metalloligands: From Structural Design to Applications DOI
Yu‐Lin Lu, Yaping Wang,

Kai Wu

и другие.

Accounts of Chemical Research, Год журнала: 2024, Номер 57(22), С. 3277 - 3291

Опубликована: Окт. 9, 2024

ConspectusThe emulation of ingenious biofunctions has been a research focus for several decades. Metal-organic cages (MOCs), as type discrete supramolecular assembly with well-defined shapes and cavities, have aroused great interest in chemists to imitate natural protein or enzymes. However, genuinely achieve tailored functionalities reactivities enzymes, the design cage structures combining both confined microenvironment active site is prerequisite. Therefore, integration functionalized motifs into MOCs expected provide feasible approach construct biofunctional nanospaces, which not only allows modulation properties applications such molecular recognition, transport, catalysis but also creates unique microenvironments that promote enzymatic effects special selectivities, thereby providing versatile platform exceptional biomimetic functions beyond.In this Account, we specifically on our toward engineering confined-nanospaces via incorporation M(ImPhen)

Язык: Английский

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