Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 159119 - 159119
Опубликована: Дек. 1, 2024
Язык: Английский
Nano Energy, Год журнала: 2025, Номер unknown, С. 110884 - 110884
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
1
Journal of the American Chemical Society, Год журнала: 2025, Номер unknown
Опубликована: Март 31, 2025
The solid electrolyte interphase (SEI) offers effective passivation on the anode for aqueous lithium-ion batteries (ALIBs). Conventional in ALIBs mainly relies LiF-contained SEI originating from anion reduction electrolyte. However, such formation is a competitive reaction negatively impacted by parasitic hydrogen evolution (HER), resulting high Li+ irreversible consumption and imperfect bare flaws. To address this issue, we propose preconstructing an artificial introducing multifunctional interface additive CsF to build superior ALIBs. first undergoes displacement with LiTFSI fresh form LiF situ of before cycles, avoiding extra consumption. Meanwhile, uncover that dissolving Cs+ can destroy bond network water lower activity strongly interact TFSI- cation-anion complex, facilitating proximity interface. based finally help achieve robust Such stabilizes electrolyte, significantly suppressing side HER allows obtain long life above 2000 cycles. ampere-hour-level (Ah-level) pouch cell achieves energy density 57 Wh/kg 176 Wh/L efficiency (∼94%).
Язык: Английский
Процитировано
1
Advanced Functional Materials, Год журнала: 2024, Номер unknown
Опубликована: Дек. 1, 2024
Abstract Rechargeable aqueous zinc batteries (AZBs) utilizing water‐borne electrolytes are intrinsically safe electrochemical devices that promising in next‐generation energy storage. Such application requires adaptivity to global climate, especially at grid‐scale, thus their stability of performance varying temperatures is critical. Many essential properties AZBs, i.e., ion transfer, redox kinetics, etc., largely governed by the because relatively limited stable phase temperature water. This limitation extremely vital cold regions since charging and discharging become more difficult sub‐zero range due water freezing. Despite development various electrolyte strategies recent years, comprehensive reviews focusing on this topic remain limited. research diverse reasons underneath failure AZBs extreme provides a thorough analysis possible resolutions from an perspective. It starts with challenges faced both high low concerning electrolytes. Different addressing these discussed, providing insights into under conditions. Finally, review concludes summary outlook design structure for all‐weather integrating innovative non‐aqueous battery systems.
Язык: Английский
Процитировано
6
Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161720 - 161720
Опубликована: Март 1, 2025
Язык: Английский
Процитировано
0
Journal of Energy Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
Chinese Chemical Letters, Год журнала: 2025, Номер unknown, С. 111185 - 111185
Опубликована: Апрель 1, 2025
Язык: Английский
Процитировано
0
Energy storage materials, Год журнала: 2025, Номер unknown, С. 104341 - 104341
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0
Advanced Functional Materials, Год журнала: 2025, Номер unknown
Опубликована: Апрель 18, 2025
Abstract Zinc–iodine batteries, grounded in halogen‐powered static conversion mechanisms, are experiencing significant development. However, clarity regarding their industrialization pathway remains elusive. This review delves into the energy storage mechanism of zinc–iodine encompassing not only conventional low‐valence transformation but also spotlighting emerging high‐valence mechanisms. Simultaneously, several optimization routes proposed from perspective battery industrialization, mainly covering direction cathode and anode materials, including efficient restraints iodine effect behavior, promotion reaction, effective design zinc anode. Furthermore, starting promoting practical application, path designing prototypes functionalized devices, focusing on device development, while improving relevant strategies for cost‐effective use explored. Additionally, considering future demand industry, discussion extends batteries to encompass extreme temperature conditions, derivative product designs, interdisciplinary integration. With a focus this work identifies key challenges field proposes comprehensive strategies, aiming provide guidance high‐performance, applications.
Язык: Английский
Процитировано
0
Advanced Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Май 29, 2025
Abstract Interhalogen chemistry, where distinct halogen species bond with each other, is a promising strategy to significantly enhance the performance of various battery systems. However, despite demonstrating unique electrochemical advantages and potential for advancing design, interhalogen technology often remains broadly categorized within electrochemistry without receiving specific focused attention. This review summarizes (hetero)interhalogen technologies employed in batteries, highlighting their effectiveness exploring further innovation. argued that this area warrants dedicated research broaden understanding accelerate development. Additionally, outlines key challenges associated current interhalogen‐based designs require careful consideration practical deployment.
Язык: Английский
Процитировано
0
Matter, Год журнала: 2024, Номер 8(3), С. 101932 - 101932
Опубликована: Дек. 17, 2024
Язык: Английский
Процитировано
1