N‐Confused Porphyrin as a Highly Active Ligand Scaffold for Molecular Catalysts of CO2 Reduction DOI
Tong Zhou, Yuhan Wang,

Huihong Yuan

и другие.

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Abstract Key to CO 2 reduction transformation is the development of catalysts that efficiently activate inert molecules, enabling rapid reaction kinetics with minimal energy inputs. In this study, we introduce N‐confused porphyrin (NCP) as a highly active ligand scaffold for transition metal‐based in reactions. By breaking D 4h symmetry inherent conventional structures, NCP promotes enhanced electron delocalization around corresponding metal complex, improving catalytic efficiency. A comprehensive study demonstrates NCP‐based complexes (Fe, Co, and Ni) significantly outperform their parent metal‐porphyrin counterparts. These results provide new insights into design more effective reduction.

Язык: Английский

Effect of Axial Ligands on Photocatalytic CO2 Reduction of Zirconium-Based Porphyrins DOI

Chloe Yong,

Chi Song,

Guanhong Lu

и другие.

ACS Applied Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 2, 2025

Язык: Английский

Процитировано

1
Sulfur-induced electronic structure rearrangement at Ru sites for strengthening dry reforming of methane DOI

Zhende Li,

Jianfeng Lu, Jing Ding

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 160925 - 160925

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1
Enhancing photocatalytic CO2-to-CO conversion by iron complexes through 8-hydroxyquinoline ligand regulation DOI
Zhichao Xu, Xin Huang, Liyan Zhang

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 142039 - 142039

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Construction of PCN-222(Pt)/BiOCl heterojunction with built-in electric field drive charge separation for enhanced photocatalytic performance DOI
Lina Li, Gaopeng Liu, Jintao Dong

и другие.

Applied Surface Science, Год журнала: 2025, Номер unknown, С. 162978 - 162978

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0
Designed electron transport path via Fe–O–Ni atomic bond for high CO2 reduction DOI
Mengyang Xu,

Bingqing Chang,

Jinze Li

и другие.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Год журнала: 2025, Номер 71, С. 114 - 127

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0
The synergy between silver-cobalt dual-active sites on exfoliated carbon nitride for efficient CO2 photoreduction DOI
Chao Huang, Xuelian Yu, Jiangpeng Wang

и другие.

Journal of Alloys and Compounds, Год журнала: 2025, Номер 1027, С. 180595 - 180595

Опубликована: Апрель 23, 2025

Язык: Английский

Процитировано

0
N‐Confused Porphyrin as a Highly Active Ligand Scaffold for Molecular Catalysts of CO2 Reduction DOI
Tong Zhou, Yuhan Wang,

Huihong Yuan

и другие.

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Май 16, 2025

Abstract Key to CO 2 reduction transformation is the development of catalysts that efficiently activate inert molecules, enabling rapid reaction kinetics with minimal energy inputs. In this study, we introduce N‐confused porphyrin (NCP) as a highly active ligand scaffold for transition metal‐based in reactions. By breaking D 4h symmetry inherent conventional structures, NCP promotes enhanced electron delocalization around corresponding metal complex, improving catalytic efficiency. A comprehensive study demonstrates NCP‐based complexes (Fe, Co, and Ni) significantly outperform their parent metal‐porphyrin counterparts. These results provide new insights into design more effective reduction.

Язык: Английский

Процитировано

0