Specific Photocatalytic C–C Coupling of Benzyl Alcohol to Deoxybenzoin or Benzoin by Precise Control of C_α–H Bond Activation or O–H Bond Activation by Adjusting the Adsorption Orientation of Hydrobenzoin Intermediates

ACS Catalysis, Год журнала: 2024, Номер 14(20), С. 15306 - 15324

Опубликована: Окт. 2, 2024

Benzyl alcohol (BA) is a major biomass derivative and can be further converted into deoxybenzoin (DOB) benzoin (BZ) as high-value products for industrial applications through photocatalytic C-C coupling reaction. The process contains two reaction steps, which are (1) the of BA to hydrobenzoin (HB) intermediates (2) either dehydration HB DOB or dehydrogenation BZ. We found that generation BZ mainly determined by activation C

Язык: Английский

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Visible-light or sunlight photoredox-catalyzed β-selective acylation of alkenes to access α, β-unsaturated ketones

Organic Chemistry Frontiers, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

A general method for accessing α,β-unsaturated ketones through visible-light or sunlight photoredox-catalyzed β-selective acylation of alkenes has been developed.

Язык: Английский

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Photoredox-Induced Dearomatization of 2-Alkenyl Aromatic Carboxylic Acids with Terminal Alkynes

ACS Catalysis, Год журнала: 2025, Номер unknown, С. 9672 - 9681

Опубликована: Май 23, 2025

Язык: Английский

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Visible light-driven excited-state copper-BINAP catalysis for accessing diverse chemical reactions

Chem Catalysis, Год журнала: 2024, Номер 4(11), С. 101184 - 101184

Опубликована: Ноя. 1, 2024

Язык: Английский

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