Distal Heteroaryl Ipso‐Migration of Unactivated Alkenes via Cobalt/Photoredox‐Catalyzed Hydrogen/Deuterium Atom Transfer DOI

Masaaki Yamashita,

Akihiko Suzuki, Tatsuhiko Yoshino

и другие.

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Июнь 5, 2025

Abstract A structural isomerization of alkenyl alcohols via 1,4‐ or 1,5‐heteroaryl migration initiated by metal‐hydride hydrogen atom transfer (MHAT) under cobalt/photoredox dual catalysis is described. The remote method provided various heteroaryl‐containing ketones inaccessible through conventional MHAT 1,2‐migration pathways. was further applied to the synthesis deuterium‐labeled ketones.

Язык: Английский

A new reaction framework for allyl carboxylates DOI
Gaoyuan Zhao,

Arman Khosravi,

Sahil Sharma

и другие.

Trends in Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0
Distal Heteroaryl Ipso‐Migration of Unactivated Alkenes via Cobalt/Photoredox‐Catalyzed Hydrogen/Deuterium Atom Transfer DOI

Masaaki Yamashita,

Akihiko Suzuki, Tatsuhiko Yoshino

и другие.

Chemistry - An Asian Journal, Год журнала: 2025, Номер unknown

Опубликована: Июнь 5, 2025

Abstract A structural isomerization of alkenyl alcohols via 1,4‐ or 1,5‐heteroaryl migration initiated by metal‐hydride hydrogen atom transfer (MHAT) under cobalt/photoredox dual catalysis is described. The remote method provided various heteroaryl‐containing ketones inaccessible through conventional MHAT 1,2‐migration pathways. was further applied to the synthesis deuterium‐labeled ketones.

Язык: Английский

Процитировано

0