Recent Strategies for the Synthesis of Ferrocene Derivatives and Their Applications to Electrochemistry DOI
Jung Min Joo, Soo Eun Park, Sohyeon Park

и другие.

Synthesis, Год журнала: 2025, Номер unknown

Опубликована: Май 5, 2025

Abstract Ferrocene, a highly redox-stable organometallic compound with distinctive sandwich-like structure, has significantly influenced the fields of electrochemistry, materials science, and medicinal chemistry. Modifying ferrocene core its side chains is crucial for fine-tuning redox properties, solubility, stability, thereby enhancing performance in various applications. This review discusses synthesis compounds potentially relevant to electrochemical applications, focusing on recent strategies nondirected C–H functionalization diverse reactions side-chain modifications. Advances activation ferrocenes have been facilitated by catalytic methods utilizing Pd, Ir, Au, In, Fe catalysts, as well through photoredox techniques. Furthermore, are modified via range mild transformations compatible core, including substitution annulation. These advancements synthesizing derivatives broadened their potential notably electron-transfer mediators, energy-storage systems, sensors. 1 Introduction 2 Nondirected Activation Ferrocene Its Derivatives 3 Side-Chain Modification 4 Applications Electrochemistry 5 Conclusion

Язык: Английский

Recent Strategies for the Synthesis of Ferrocene Derivatives and Their Applications to Electrochemistry DOI
Jung Min Joo, Soo Eun Park, Sohyeon Park

и другие.

Synthesis, Год журнала: 2025, Номер unknown

Опубликована: Май 5, 2025

Abstract Ferrocene, a highly redox-stable organometallic compound with distinctive sandwich-like structure, has significantly influenced the fields of electrochemistry, materials science, and medicinal chemistry. Modifying ferrocene core its side chains is crucial for fine-tuning redox properties, solubility, stability, thereby enhancing performance in various applications. This review discusses synthesis compounds potentially relevant to electrochemical applications, focusing on recent strategies nondirected C–H functionalization diverse reactions side-chain modifications. Advances activation ferrocenes have been facilitated by catalytic methods utilizing Pd, Ir, Au, In, Fe catalysts, as well through photoredox techniques. Furthermore, are modified via range mild transformations compatible core, including substitution annulation. These advancements synthesizing derivatives broadened their potential notably electron-transfer mediators, energy-storage systems, sensors. 1 Introduction 2 Nondirected Activation Ferrocene Its Derivatives 3 Side-Chain Modification 4 Applications Electrochemistry 5 Conclusion

Язык: Английский

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