Synergistic Effects in the Electrochemical Carbon Dioxide Reduction Reaction for Multi‐Carbon Product Formation
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Апрель 1, 2025
Abstract
The
synergistic
effects
in
electrocatalysis
can
significantly
enhance
catalyst
performance
by
improving
catalytic
activity,
selectivity,
and
stability,
optimizing
reaction
mechanisms
electron
transfer
processes.
This
review
summarizes
recent
advancements
the
of
electrochemical
reduction
CO
2
(eCO
RR)
to
multi‐carbon
(C
2+
)
products.
Starting
with
fundamental
principles
eCO
RR
for
C
product
formation,
paper
outlines
producing
,
3
4
5
A
comprehensive
discussion
is
provided
on
critical
impact
structure–performance
relationship
production
Subsequently,
observed
are
classified
various
electrocatalysts
different
properties,
including
single/dual‐atom
catalysts,
multi‐centric
single‐atom
alloys,
metal‐organic
frameworks,
heterojunction
catalysts.
Finally,
challenges
achieving
selective
formation
through
discussed,
along
corresponding
strategies
overcome
obstacles.
Язык: Английский
Continuous-flow synthesis of special Au–Ag bimetallic nanoparticles and their application for SERS detection of thiram in cherry juice
Reaction Chemistry & Engineering,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
Special
Au–Ag
nanoparticles
are
controllably
synthesized
via
continuous
flow
and
used
as
substrates
for
SERS
detection
of
thiram
in
cherry
juice.
Язык: Английский
Research progress on the reaction mechanism, metal-based catalysts, and reactors for CO2 electroreduction to formic acid/formate
Journal of environmental chemical engineering,
Год журнала:
2025,
Номер
unknown, С. 116547 - 116547
Опубликована: Апрель 1, 2025
Язык: Английский
Tailoring ultra-small ZnO nanoparticles through cobalt doping to enhance photocatalytic CO2 reduction
RSC Advances,
Год журнала:
2025,
Номер
15(15), С. 11934 - 11941
Опубликована: Янв. 1, 2025
The
photocatalytic
reduction
of
CO
2
using
cobalt-doped
zinc
oxide
nanoparticles
(Co-ZnO
NPs)
achieves
a
yield
143.90
μmol
g
−1
h
,
which
is
15.73
times
higher
than
that
undoped
ZnO,
and
exhibits
excellent
stability.
Язык: Английский
Cell-free synthesis of high-order carbohydrates from low-carbon molecules
Science Bulletin,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 1, 2025
Язык: Английский
Edge‐Rich Graphene Nanomesh Thermally Self‐Exfoliated From Metal‐Organic Frameworks for Boosting CO2 Electroreduction
Advanced Functional Materials,
Год журнала:
2025,
Номер
unknown
Опубликована: Май 15, 2025
Abstract
Atomic‐level
metal
sites
at
the
edges
of
graphene‐like
carbon
supports
are
considered
more
active
for
CO
2
electrocatalysis
than
those
in‐plane.
However,
creating
high‐density
edge‐dominating
sites,
particularly
in
a
simple,
scalable,
and
self‐templated
fashion,
presents
significant
challenge.
Herein,
MOF‐mediated
self‐exfoliation
strategy
is
reported
to
preferentially
integrate
edge‐type
FeN
4
onto
ultrathin
edge‐rich
N‐doped
graphene
nanomesh
(e‐Fe‐NGM).
Theoretical
calculations,
finite
element
method
(FEM)
simulations,
together
with
series
situ
spectro‐electrochemical
experiments
corroborate
that
can
not
only
optimize
electronic
structure
catalysts,
facilitating
formation
*
COOH
desorption
CO,
but
also
effectively
induce
strong
local
electrostatic
field,
promoting
interfacial
H
O
supply
thereby
accelerating
protonation
process
.
Thus‐prepared
e‐Fe‐NGM
delivers
remarkable
Faraday
efficiency
(FE)
above
98%
over
an
ultra‐wide
potential
window
500
mV
high
turnover
frequency
6648
h
−1
,
much
superior
controlled
sample
dominant
plane‐type
sites.
Moreover,
this
self‐exfoliated,
non‐catalyzed
approach
readily
scalable
be
used
produce
large‐size
industrial
levels.
Язык: Английский