Abstract.
Export
of
dissolved
organic
carbon
(DOC)
from
riparian
zones
(RZs)
is
an
important,
but
poorly
understood
component
temperate
catchment
budgets.
This
paper
delineates
explicit
DOC
source
within
the
RZ
a
small
forested
in
central
Germany,
and
identifies
quantifies
their
dominant
export
mechanism
at
high
spatio-temporal
resolution.
Stream
water
samples
differing
hydrological
situations
were
compared
to
groundwater
surface
classified
chemically
(via
Fourier-transform
ion
cyclotron
resonance
mass
spectrometry)
spatially
via
small-scale
topographic
analysis
resolution
1
m.
Explicit
fluxes
resulting
then
simulated
by
physically-based,
fully-integrated
numerical
flow
model
(HydroGeoSphere).
Chemical
classification
revealed
two
distinct
pools
(DOCI
DOCII)
RZ.
The
comparison
stream
indicated
predominant
DOCI
during
wet
conditions
levels.
separated
mapped
using
threshold
value
high-resolution
topographical
wetness
index
(TWIHR).
Hydrological
modelling
that
runoff
with
TWIHR
values
dominated
overall
discharge
generation
therefore
export.
Although
corresponding
only
15
%
area
studied
RZ,
provided
total
1.5
times
load
remaining
85
associated
DOCII
pool.
Our
results
suggest
can
play
role
for
RZs
low
relief
should
be
considered
models.
We
propose
proxies
spatial
heterogeneity
(here:
TWIHR)
delineate
most
active
provide
meaningful
basis
improved
conceptualization
surficial
The Science of The Total Environment,
Год журнала:
2022,
Номер
849, С. 157398 - 157398
Опубликована: Июль 21, 2022
Dissolved
organic
carbon
(DOC)
in
surface
waters
is
an
important
component
of
the
boreal
landscape
budget
and
a
critical
variable
water
quality.
A
dominant
terrestrial
DOC
source
riparian
zone.
These
near
stream
areas
play
key
role
regulating
transport
between
land
aquatic
ecosystems.
The
groundwater
dynamics
at
this
interface
have
been
considered
major
controlling
for
export
to
streams.
This
study
focuses
on
levels
mean
travel
times
(MTT)
concentrations
and,
subsequently,
DOC.
done
by
comparing
them
as
explanatory
variables
capture
spatial
intra-annual
variability
We
used
physically
based
3D
hydrological
model,
Mike
SHE,
simulate
zones
14
sub-catchments
within
Krycklan
catchment
(Sweden).
model
concept
assumes
that
will
be
higher
moving
through
shallow
flow
paths.
In
can
linked
position
table
point
observation
or
time,
which
generally
shorter
has
travelled
more
conductive
soil
layers.
compared
results
with
both
observed
concentrations.
analysis
revealed
correlation
modelled
annual
averages
increased
from
r
=
0.08
0.87
using
MTT
instead
level.
also
better
captured
successfully
represented
seasonal
We,
therefore,
suggest
predictor
than
level
concentration
because
it
greater
variety
heterogeneities,
such
variation
properties,
size,
input
deep
sources.
Hydrology and earth system sciences,
Год журнала:
2023,
Номер
27(16), С. 3083 - 3114
Опубликована: Авг. 24, 2023
Abstract.
Stable
isotopes
(δ18O)
and
tritium
(3H)
are
frequently
used
as
tracers
in
environmental
sciences
to
estimate
age
distributions
of
water.
However,
it
has
previously
been
argued
that
seasonally
variable
tracers,
such
δ18O,
generally
systematically
fail
detect
the
tails
water
therefore
substantially
underestimate
ages
compared
radioactive
3H.
In
this
study
for
Neckar
River
basin
central
Europe
based
on
a
>20-year
record
hydrological,
δ18O
3H
data,
we
scrutinized
above
postulate
together
with
potential
role
spatial
aggregation
effects
exacerbating
underestimation
ages.
This
was
done
by
comparing
inferred
from
total
21
different
model
implementations,
including
time-invariant,
lumped-parameter
sine-wave
(SW)
convolution
integral
(CO)
models
well
StorAge
Selection
(SAS)-function
(P-SAS)
integrated
hydrological
combination
SAS
functions
(IM-SAS).
We
found
that,
indeed,
commonly
SW
CO
mean
transit
times
(MTTs)
∼
1–2
years
lower
than
those
obtained
same
models,
reaching
MTTs
∼10
years.
contrast,
several
implementations
P-SAS
IM-SAS
not
only
allowed
simultaneous
representations
storage
variations
streamflow
stream
signals,
but
these
were,
11–17
years,
also
much
higher
similar
3H,
which
suggested
11–13
Characterized
parameter
posterior
distributions,
particular
parameters
control
age,
individually
constrained
or
observations
exhibited
limited
differences
magnitudes
parts
temporal
variability
time
(TTDs)
response
changing
wetness
conditions.
suggests
both
lead
comparable
descriptions
how
is
routed
through
system.
These
findings
provide
evidence
us
reject
hypothesis
tracer
“cannot
see
older
about
4
years”
truncates
corresponding
leading
underestimations
Instead,
our
results
broad
equivalence
systems
characterized
at
least
15–20
The
question
degree
heterogeneity
can
further
adversely
affect
estimates
remains
unresolved
lumped
distributed
provided
inconclusive
results.
Overall,
demonstrates
reported
most
likely
result
use
other
per
se.
Rather,
largely
be
attributed
choices
approaches
complexity
considering
transient
conditions
next
aspects.
Given
additional
vulnerability
due
potentially
still
unknown
effects,
advocate
avoiding
type
if
possible
instead
adopting
SAS-based
time-variant
formulations
models.
Global Change Biology,
Год журнала:
2020,
Номер
26(10), С. 5899 - 5913
Опубликована: Июль 20, 2020
Abstract
The
magnitude
of
the
terrestrial
carbon
(C)
sink
may
be
overestimated
globally
due
to
difficulty
accounting
for
all
C
losses
across
heterogeneous
landscapes.
More
complete
assessments
net
landscape
balances
(NLCB)
are
needed
that
integrate
both
emissions
by
fire
and
transfer
aquatic
systems,
two
key
loss
pathways
C.
These
can
particularly
significant
in
wet–dry
tropics,
where
plays
a
fundamental
part
ecosystems
intense
rainfall
seasonal
flooding
result
considerable
export
(ΣF
aq
).
Here,
we
determined
NLCB
lowland
catchment
(~140
km
2
)
tropical
Australia
over
years
evaluating
productivity
(NEP),
fire‐related
ΣF
(comprising
downstream
transport
gaseous
evasion)
main
components,
is,
savanna
woodland
wetlands.
We
found
was
large
(NLCB
334
Mg
−2
year
−1
),
wetland
areas
contributed
84%
16%
this
sink,
respectively.
Annually,
(−56
(−28
reduced
NEP
13%
7%,
Savanna
burning
shifted
source
several
months
during
dry
season,
while
significantly
offset
wet
with
disproportionate
contribution
single
major
monsoonal
events—up
39%
annual
exported
one
event.
hypothesize
wetter
hotter
conditions
tropics
future
will
increase
emissions,
potentially
further
reducing
current
region.
long‐term
studies
upscale
first
estimate
less
productive,
yet
hydrologically
dynamic
regions
our
indicating
not
hold.
Frontiers in Earth Science,
Год журнала:
2020,
Номер
8
Опубликована: Ноя. 6, 2020
Tropical
regions
cover
approximately
36%
of
the
Earth's
landmass.
These
are
home
to
40%
world's
population,
which
is
projected
increase
over
50%
by
2030
under
a
remarkable
climate
variability
scenario
often
exacerbated
El
Niño
Southern
Oscillation
(ENSO)
and
other
teleconnections.
In
tropics,
ecohydrological
conditions
typically
influence
complex
land-ocean-atmosphere
interactions
that
produce
dynamic
cycling
mass
energy
reflected
in
clear
partition
water
fluxes.
Here,
we
present
review
seven
years
concerted
continuous
stable
isotope
monitoring
across
Costa
Rica,
including
key
insights
learned,
main
methodological
advances
limitations
(both
experimental
designs
data
analysis),
potential
gaps,
future
research
opportunities
with
humid
tropical
perspective.
The
uniqueness
geographic
location
Rica
within
mountainous
Central
America
Isthmus,
receiving
moisture
inputs
from
Caribbean
Sea
(windward)
Pacific
Ocean
(complex
leeward
topography),
experiencing
strong
ENSO
events,
poses
advantage
for
use
isotopic
variations
underpin
drivers
responses.
sequential
approach,
analyzed
transport,
rainfall
generation,
groundwater/surface
connectivity
Bayesian
rainfall-runoff
modeling.
overarching
goal
this
provide
robust
example
progressive
escalation
common
observations
more
modeling
outputs
applications
enhance
resource
management
tropics.
Global Change Biology,
Год журнала:
2021,
Номер
28(7), С. 2360 - 2380
Опубликована: Дек. 2, 2021
Despite
their
size
and
contribution
to
the
global
carbon
cycle,
we
have
limited
understanding
of
tropical
savannas
current
trajectory
with
climate
change
anthropogenic
pressures.
Here
examined
interannual
variability
externally
forced
long-term
changes
in
water
exchange
from
a
high
rainfall
savanna
site
seasonal
tropics
north
Australia.
We
used
an
18-year
flux
data
time
series
(2001-2019)
detect
trends
drivers
fluxes
water.
Significant
positive
gross
primary
productivity
(GPP,
15.4
g
C
m2
year-2
),
ecosystem
respiration
(Reco
,
8.0
net
(NEE,
7.4
)
use
efficiency
(WUE,
0.0077
kg
H2
O-1
year-1
were
computed.
There
was
weaker,
non-significant
trend
latent
energy
(LE,
0.34
W
m-2
).
Rainfall
nearby
increased
statistically
over
45-year
period
during
observation
period.
To
examine
dominant
GPP
WUE,
random
forest
approach
terrestrial
biosphere
model
conduct
attribution
experiment.
Radiant
driver
wet
season
fluxes,
whereas
soil
content
dominated
dry
fluxes.
The
suggested
that
[CO2
],
precipitation
Tair
accounting
for
90%
modelled
WUE.
Positive
largest
implying
tree
components
larger
contributor
than
grassy
understorey.
Fluxes
environmental
not
significant
season,
when
grasses
are
active.
is
potentially
still
recovering
cyclone
45
years
ago
regrowth
this
event
may
also
be
contributing
observed
sequestration,
highlighting
need
understand
sub-diurnal
decadal
scales.
Wiley Interdisciplinary Reviews Water,
Год журнала:
2025,
Номер
12(2)
Опубликована: Март 1, 2025
ABSTRACT
During
the
last
decade,
tracer‐aided
hydrological
models
(TAMs)
have
been
applied
in
numerous
studies
and
successfully
evolved
for
different
purposes.
Such
confirmed
value
of
tracer
data
modeling,
offering
insights
into
internal
storages,
water
sources,
flow
pathways,
mixing
processes,
ages,
which
cannot
be
derived
from
hydrometric
alone.
The
direct
coupling
tracers
flux
tracking
balance
can
reduce
model
uncertainty
through
increased
biogeochemical
process
knowledge.
More
specifically,
such
simultaneously
capture
celerity
responses
with
velocities
(and
age)
particles.
As
a
result
availability
high‐resolution
characterizing
functioning
across
Critical
Zone
entire
landscapes,
together
rapid
improvement
computing
capacity,
four
major
advances
reshaped
capability
TAMs,
we
review
this
paper:
(1)
enhanced
representation
spatial
heterogeneity,
(2)
more
explicit
conceptualization
ecohydrological
partitioning,
(3)
application
to
larger
catchment
scales,
(4)
incorporation
non‐conservative
coupled
quality
modeling.
However,
persistent
challenges
also
emerged,
particularly
relation
acquisition,
mismatches
between
information
content
scale
application,
uncertainties
structures,
as
well
adaptation
multi‐criteria
calibration.
In
review,
recent
remaining
TAMs
summarized
discussed
particular
focus
on
conservative
models.
Limnology and Oceanography,
Год журнала:
2023,
Номер
68(5), С. 1132 - 1146
Опубликована: Март 12, 2023
Abstract
Carbon
dioxide
(CO
2
)
can
be
either
imported
to
streams
through
groundwater
and
subsurface
inputs
of
soil‐respired
CO
or
produced
internally
stream
metabolism.
The
contribution
each
source
the
evasion
flux
from
is
not
well
quantified,
especially
in
tropics,
an
underrepresented
region
carbon
(C)
cycling
studies.
We
used
high‐frequency
measurements
dissolved
O
concentrations
estimate
potential
metabolism
a
tropical
lowland
headwater
stream.
found
that
was
heterotrophic
all
year
round,
with
net
ecosystem
productivity
(NEP)
values
ranging
0.84
4.06
g
C
m
−2
d
−1
(median
1.29
;
here
we
expressed
gross
primary
(GPP)
as
negative
respiration
(ER)
positive
flux).
Positive
NEP
were
result
relatively
low
stable
GPP
seasons,
compared
higher
more
variable
ER
favored
by
high
temperatures
organic
matter
availability,
particularly
during
wet
season.
due
turbulence
(median:
1.09
).
As
result,
daily
rates
exceeded
129%
(median;
120–175%
interquartile
range),
despite
strong
seasonal
changes
flow
regime
landscape
connectivity.
excess
likely
transported
downstream,
where
it
ultimately
emitted
atmosphere.
Our
results
highlight
overwhelming
importance
cycle
low‐energy,
oligotrophic
streams.