Distinct
types
of
luminescence
that
are
activated
by
various
stimuli
in
a
single
material
offer
exciting
developmental
opportunities
for
functional
materials.
A
versatile
sensing
platform
exhibits
photoluminescence
(PL),
persistent
(PersL),
and
mechanoluminescence
(ML)
is
introduced,
which
enables
the
sensitive
detection
temperature,
pressure,
force/stress.
The
developed
Sr
Chemistry - A European Journal,
Год журнала:
2024,
Номер
30(32)
Опубликована: Апрель 4, 2024
Abstract
Chiral
Metal‐Organic
Frameworks
(CMOFs)
are
a
rapidly
growing
field
reflecting
their
potential
as
selective
and
sensitive
chemical
sensors
for
chiral
analytes.
The
highly
tuneable
nature
of
CMOFs
enables
the
size,
shape,
non‐covalent
interactions
to
be
optimised
towards
specific
analytes
engender
strong
intermolecular
sensing
responses.
While
sensor
devices
have
been
explored
with
electrochemical
methods
including
differential
pulse
voltammetry
(DPV),
bipolar
chemiresistive
techniques,
using
spectroscopic
has
received
significantly
less
attention.
This
review
examines
synthesis
such
photoluminescence,
circular
dichroism,
solid‐state
nuclear
magnetic
resonance
view
incorporation
into
devices.
Future
directions
highlighted
generation
functional
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(46)
Опубликована: Июль 22, 2024
Thorium,
a
predominant
actinide
in
the
Earth's
crust,
presents
significant
environmental
and
health
risks
due
to
its
radioactive
nature.
These
are
particularly
pronounced
during
mining
processing
of
monazite
for
rare
earth
elements
(REEs),
which
contain
substantial
thorium
concentrations.
Current
instrumental
analysis
methods
thorium,
offer
high
accuracy
but
require
laborious
sample
preparations
expensive
instruments,
making
them
unsuitable
on-site
analysis.
Herein,
we
present
class
color-tunable
luminescent
lanthanide-based
metal-organic
frameworks
(Ln-MOFs)
as
fluorochromic
sensors
Th
Distinct
types
of
luminescence
that
are
activated
by
various
stimuli
in
a
single
material
offer
exciting
developmental
opportunities
for
functional
materials.
A
versatile
sensing
platform
exhibits
photoluminescence
(PL),
persistent
(PersL),
and
mechanoluminescence
(ML)
is
introduced,
which
enables
the
sensitive
detection
temperature,
pressure,
force/stress.
The
developed
Sr