RSC Sustainability,
Год журнала:
2024,
Номер
2(5), С. 1487 - 1497
Опубликована: Янв. 1, 2024
This
work
compares
fossil-based
polymers
to
wood
derivatives
and
polylactic
acid
using
a
lifecycle
scenario
analysis.
The
aim
is
unravel
the
climate
neutrality
advantages
of
bio-based
like
derivatives.
ACS Sustainable Chemistry & Engineering,
Год журнала:
2024,
Номер
12(8), С. 2927 - 2961
Опубликована: Фев. 13, 2024
Polyesters
based
on
2,5-furandicarboxylic
acid
(2,5-FDCA)
have
attracted
attention
from
both
academia
and
industry
as
a
new
class
of
biobased
polymers
for
the
growing
era
plastics.
2,5-FDCA-based
polyesters
are
100%
renewable,
they
an
alternative
to
petroleum-based
or
terephthalic
(TPA)-based
polyesters.
Moreover,
scientists
plastics
experts
recognized
bioplastics
eco-friendly
solution
developing
cost-effective
renewable
The
growth
market
depends
sustainable
economy,
population
growth,
rapid
changes
in
different
polymers.
Although
variety
auxiliaries
been
practically
used
recent
years,
production
2,5-FDCA
monomers
by
oxidation
5-hydroxymethylfurfural
(HMF)
is
relatively
innovative
field
research.
This
review
focuses
properties
applications
packaging
coating
industries
producing
postconsumer
products.
manufacturability,
excellent
(thermal,
mechanical,
barrier)
features,
various
fields
available
homo-
copolyesters
discussed.
Biobased
pure
recently
progressed
with
exceptional
their
counterparts
In
particular,
mechanical
performance
homopolyesters
such
poly(ethylene
2,5-furandicarboxylate)
(PEF)
poly(propylene
(PPF)
has
highest
tensile
strength
(σb)
values
84.07
±
4.43
90
6
MPa,
respectively,
compared
other
homopolyesters.
On
hand,
neat
like
2,5-thiophenedicarboxylate)
(PETF)
poly(ethylene-co-1,4-cyclohexanedimethylene
(PECF)
had
maximum
97–98
59–75
copolyesters.
addition,
we
also
observed
Young's
modulus
(E)
PEF
(5248
328
MPa)
PPF
(2460
280
PETF
(3100–3300
PECF
(1740–2300
Furthermore,
elongation
at
break
(εb)
poly(decylene
furandicarboxylate)
(PDF)
(986
82%)
poly(butylene
(PBF)
(368
43%)
poly(pentylene
(PPeF)
(1050
200%)
poly(1,4-butanediol
(PBTF)
(900
84%)
Finally,
results
barrier
improvement
factor
(BIFp)
study
showed
that
PPeF
O2
(227
BIFp)
CO2
(979
Abstract
Fully
biodegradable
packaging
materials
are
demanded
to
resolve
the
issue
of
plastic
pollution.
However,
fresh
food
storage
performance
is
generally
much
lower
than
that
plastics
due
their
high
permeability,
microbial
friendliness,
and
limited
stretchability
transparency.
Here
a
material
reported
with
based
on
an
oil‐infused
bacterial
cellulose
(OBC)
porous
film.
The
oil
infusion
significantly
improved
cellulose's
food‐keeping
by
reducing
its
gas
increasing
transparency,
enabling
active
release
green
vapor‐phase
preservative
molecules,
while
maintaining
intrinsically
degradability.
Strawberries
stored
in
container
OBC
lid
at
23
°C
after
5
days
exhibited
moldy
rate
0%,
contrast
100%
those
poly(ethylene).
Enhanced
also
obtained
tomatoes,
pork,
shrimp.
film
naturally
degraded
being
buried
wet
soil
30
for
9
days,
identical
degradation
cellulose.
liquid
seal
strategy
broadly
applies
different
celluloses,
providing
general
option
developing
cellulose‐based
materials.
Ultrasonics Sonochemistry,
Год журнала:
2023,
Номер
99, С. 106581 - 106581
Опубликована: Сен. 3, 2023
Cellulose
nanocrystals
(CNCs)
are
typically
extracted
from
plants
and
present
a
range
of
opto-mechanical
properties
that
warrant
their
use
for
the
fabrication
sustainable
materials.
While
commercialization
is
ongoing,
extraction
at
large
scale
still
being
optimized.
Ultrasonication
well-established
routinely
used
technology
(re-)
dispersing
and/or
isolating
plant-based
CNCs
without
need
additional
reagents
or
chemical
processes.
Several
critical
ultrasonication
parameters,
such
as
time,
amplitude,
energy
input,
play
dominant
roles
in
reducing
particle
size
altering
morphology
CNCs.
Interestingly,
this
can
be
coupled
with
other
methods
to
generate
moderate
high
yields
Besides,
ultrasonics
treatment
also
has
significant
impact
on
dispersion
state
surface
chemistry
Accordingly,
ability
self-assemble
into
liquid
crystals
subsequent
superstructures
can,
example,
imbue
materials
finely
tuned
structural
colors.
This
article
gives
an
overview
primary
functions
arising
parameters
stabilizing
CNCs,
producing
combination
promising
methods,
highlighting
examples
where
design
photonic
using
nanocrystal-based
celluloses
substantially
impacted.